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21.
Jean-François Chiffoleau Dominique Auger Emmanuelle Chartier Pierre Michel Isabelle Truquet André Ficht Jean-Louis Gonzalez Louis-Alexandre Romana 《Estuaries and Coasts》2001,24(6):1029-1040
Cadmium (Cd) is among the major contaminants in the Seine estuary. In the biota, the RNO (Réseau National d’Observation, the French Mussel-Watch) has shown that Cd concentrations in mussels living at the mouth of the estuary are related to changes in inputs to this area of phosphogypsum, a calcium sulphate that is a by-product of the phosphoric acid naturally enriched with Cd. In the water column, Cd concentrations at several key estuary sites show a very marked trend toward decreased contamination in the particles as well as in the dissolved phase. The behavior of Cd in the estuary has been studied between 1991 and 1998 in the framework of the scientific program Seine-Aval. This program has highlighted punctual Cd inputs in the estuarine water column. The partition of Cd between the dissolved and the particulate phase, previously described in various estuaries, is characterized by an intense phenomenon of solubilization in the mixing zone freshwater-seawater, but the colloidal Cd fraction remains low along the whole salinity gradient, about 5% to 10% of the apparent dissolved fraction. Although the decrease of inputs induced a fall of Cd concentrations in the water column, laboratory experiments show that the estuarine particles are far from being exhausted in Cd. Despite continuous efforts to reduce the urban and industrial inputs into the estuarine and coastal waters, the Seine estuary still remains very contaminated by Cd. 相似文献
22.
P. van Beek R. François M. Conte J.-L. Reyss M. Charette 《Geochimica et cosmochimica acta》2007,71(1):71-86
We measured 228Raex/226Raex and 226Raex/Baex ratios in suspended and sinking particles collected at the Oceanic Flux Program (OFP) time-series site in the western Sargasso Sea and compared them to seawater ratios to provide information on the origin and transport of barite (BaSO4) in the water column. The 228Raex/226Raex ratios of the suspended particles down to 2000 m are nearly identical to those of seawater at the same water depth. These ratios are much lower than expected if suspended barite was produced in surface waters and indicate that barite is produced throughout the mesopelagic layer. The 228Raex/226Raex activity ratios of sinking particles collected at 1500 and 3200 m varied mostly between 0.1 and 0.2, which is intermediate between the seawater ratio at these depths (<0.03) and the seawater ratios found in the upper 250 m (0.31-0.42). This suggests that excess Ba (i.e., Baex = Batotal − Balithogenic), considered to be mainly barite, present in the sinking flux is a mixture of crystals formed recently in the upper water column, formed several years earlier in the upper water column, or formed recently in deeper waters. We observe a sizeable temporal variability in the 228Raex/226Raex ratios of sinking particles, which indicates temporal variability in the relative proportion of barite crystals originating from surface (with a high 228Raex/226Raex ratio) and mesopelagic (with a low 228Raex/226Raex ratio) sources. However, we could not discern a clear pattern that would elucidate the factors that control this variability. The 226Ra/Ba ratios measured in seawater are consistent with the value reported from the GEOSECS expeditions (2.3 dpm μmol−1) below 500 m depth, but are significantly lower in the upper 500 m. High 226Raex/Baex ratios and elevated Sr concentrations in suspended particles from the upper water column suggest preferential uptake of 226Ra over Ba during formation of SrSO4 skeletons by acantharians, which must contribute to barite formation in shallow waters. Deeper in the water column the 226Raex/Baex ratios of suspended particles are lower than those of seawater. Since 228Raex/226Raex ratios demonstrate that suspended barite at these depths has been produced recently and in situ, their low 226Raex/Baex ratios indicate preferential uptake of Ba over Ra in barite formed in mesopelagic water. 相似文献
23.
Helene Valladas Norbert Mercier Laurence Froget Jean-Louis Joron Jean-Louis Reyss Panajotis Karkanas Eleni Panagopoulou Nina Kyparissi-Apostolika 《Quaternary Geochronology》2007,2(1-4):303-308
The lowest stratigraphic unit of Theopetra cave (Greece) contains a Middle Palaeolithic sequence radiocarbon dated to between 46 and 35 ka BP; at the limit of this dating method. The upper part of this sequence has yielded late Middle Palaeolithic lithic assemblages containing several early Upper Palaeolithic artifacts. To get more precise dates for the human occupation of the cave, burnt flint specimens from these Middle Palaeolithic layers were dated by thermoluminescence. The dates obtained are coherent and indicate that the first human occupation of the cave took place at the end of isotopic stage 6 or more probably at the beginning of stage 5, much earlier than previously proposed. In the light of this new evidence, it is reasonable to assume that: (a) Theopetra contains the oldest dated Middle Palaeolithic deposits of Greece and (b) that the assemblages first interpreted as “Transitional Middle/Upper Palaeolithic” industries may be the result of post-depositional mixing of cultural material. 相似文献
24.
We derive the electron density distribution in the ecliptic plane, from the corona to 1 AU, using observations from 13.8 MHz to a few kHz by the radio experiment WAVES aboard the spacecraft Wind. We concentrate on type III bursts whose trajectories intersect the spacecraft, as determined by the presence of burst-associated Langmuir waves, or by energetic electrons observed by the 3-D Plasma experiment. For these bursts we are able to determine the mode of emission, fundamental or harmonic, the electron density at 1 AU, the distance of emission regions along the spiral, and the time spent by the beams as they proceed from the low corona to 1 AU. For all of the bursts considered, the emission mode at burst onset was the fundamental; by contrast, in deriving many previous models, harmonic emission was assumed.By measuring the onset time of the burst at each frequency we are able to derive an electron density model all along the trajectory of the burst. Our density model, after normalizing the density at 1 AU to be ne(215 R0)=7.2 cm–3 (the average value at the minimum of solar activity when our measurements were made), is ne=3.3×105 r–2+4.1×106 r–4+8.0×107 r–6 cm–3, with r in units of R0. For other densities at 1 AU our result implies that the coefficients in the equation need to be multiplied by n
e
(1 AU)/7.2.We compare this with existing models and those derived from direct, in-situ measurements (normalized to the same density at 1 AU) and find that it agrees very well with in-situ measurements and poorly with radio models based on apparent source positions or assumptions of the emission mode. One implication of our results is that isolated type III bursts do not usually propagate in dense regions of the corona and solar wind, as it is still sometimes assumed. 相似文献
25.
Post-collision neogene volcanism of the Eastern Rif (Morocco): magmatic evolution through time 总被引:6,自引:0,他引:6
Samir El Bakkali Alain Gourgaud Jean-Louis Bourdier Herv Bellon Niyazi Gundogdu 《Lithos》1998,45(1-4):523-543
Neogene volcanism in the Eastern Rif (Morocco) comprises a series of calc-alkaline, potassic calc-alkaline, shoshonitic and alkaline volcanic rocks. According to new stratigraphical, along with new and previous chronological and geochemical data, the orogenic volcanism was successively (1) calc-alkaline (basaltic andesites and andesites: 13.1 to 12.5 Ma, rhyolites: 9.8 Ma), (2) K-calc-alkaline (basaltic andesitic to rhyolitic lavas and granodiorites: 9.0 to 6.6 Ma), and (3) shoshonitic (absarokites, shoshonites, latites, trachytes: 7.0 to 5.4 Ma). The later Pliocene volcanism was basaltic and alkaline (5.6 to 1.5 Ma). The calc-alkaline and K-calc-alkaline series exhibit lower K2O (0.7–5.3 wt.%), Nb (8–19 ppm) contents and higher 87Sr/86Sr (0.70773–0.71016) than the shoshonitic series (K2O: 2.4–7.2 wt.%, Nb: 21–38 ppm, 87Sr/86Sr: 0.70404–0.70778). Pliocene alkaline basalts have a sodic tendency (Na2O/K2O: 1.7–3.5), high Nb content (up to 52 ppm), and low 87Sr/86Sr ratio (0.70360–0.70413). The variations through time of K2O, Nb and Sr isotopic ratio reflect different mantle sources: (i) calc-alkaline, potassic calc-alkaline and shoshonitic series are derived from a mantle source modified by older subduction, (ii) alkaline basalts are derived mainly from an enriched mantle source. Through time, incompatible elements such as Nb increased while 87Sr/86Sr decreased, suggesting a decreasing influence of metasomatized mantle (inherited subduction). Such evolution is related to the post-collision regimes operating in this area, and could be linked to the succession of extensional, compressional and strike-slip fault tectonics. 相似文献
26.
Yuji Yokoyama Jean-Louis Reyss François Guichard 《Earth and Planetary Science Letters》1977,36(1):44-50
Production rates of22Na (T1/2 = 2.6years) from aluminium by the action of cosmic rays are measured at the Mont Blanc (altitude 4600 m), the Aiguille du Midi (3840 m), and the Col du Lautaret (2070 m). They are2.3 ± 0.5,1.8 ± 0.3,and0.77 ± 0.18 atoms min?1 kg?1, respectively, in good agreement with the calculated production rates, 2.4, 1.7 and 0.6 atoms min?1 kg?1, respectively, at the three stations.Production rates of24Na (T1/2 = 15hours) from aluminium and magnesium are also measured at the Aiguille du Midi; the observed rates of3.4 ± 0.4and6.0 ± 1.7 atoms min?1 kg?1, respectively, agree well with the theoretically expected rates of 3.7 and 5.6 atoms min?1 kg?1.The production rates of3H,7Be,10Be,14C,22Na,26Al,36Cl,37Ar,39Ar,53Mn,54Mn, and55Fe in terrestrial rocks by the action of cosmic rays are calculated in order to show the possibility of applying the measurements of these cosmogenic radionuclides to the earth science. 相似文献
27.
The evolution of the 27-day recurrence in the series of two solar indices (Wolf number WN and 10.7 cm radio flux F) and two geomagnetic indices (Dst and ζ, variance of the geomagnetic field recorded at a magnetic observatory) have been studied over the 1957 – 2007 time
span. Spectral energies contained in two period domains (25 – 27.3 and 27.3 – 31 days), designated as E
1 and E
2, have been computed. Whereas the evolution of E
1 is the same for the four indices, that of E
2 is essentially different for WN and F on the one hand, Dst and ζ on the other hand. Some general conclusions on the dynamics of the solar outer layers are inferred from these results.
First the solar activity, as measured by WN, and when averaged over a few years, evolves in the same way whatever the latitude.
Second, two families of coronal holes (CHs) are identified; the rapidly and the slowly rotating CHs evolve quite differently. 相似文献
28.
Antal?Embey-IsztinEmail author Gábor?Dobosi Jean-Louis?Bodinier Delphine?Bosch G.?A.?Jenner Simone?Pourtales Olivier?Bruguier 《Contributions to Mineralogy and Petrology》2014,168(3):1054
Peridotite xenoliths erupted by alkali basaltic volcanoes in the western Pannonian Basin can be divided into two fundamentally contrasting groups. Geochemical characteristics of the abundant protogranular, porphyroclastic and equigranular nodules suggest that these samples originate from an old consolidated and moderately depleted lithospheric mantle domain. In contrast, the geochemical features of the worldwide rare, but in the Pannonian Basin relatively abundant, poikilitic xenoliths attest to a more complex evolution. It has been argued that the origin of the peculiar texture and chemistry may be intimately linked to melt/rock reactions at successively decreasing liquid volumes in a porous melt flow system. The most likely site where such reactions can take place is the asthenosphere–lithosphere boundary. In this context, poikilitic xenoliths may provide petrological and geochemical evidence for reactions between magmatic liquids issued from the uprising asthenosphere and the solid mantle rocks of the lithosphere. These reactions are important agents of the thermal erosion of the lithosphere; thus, they could have considerably contributed to the thinning of the lithosphere in the Pannonian region. We suggest that in the Pannonian Basin, there could be a strong relation between the unusual abundance of poikilitic mantle xenoliths and the strongly eroded lithosphere. 相似文献
29.
Luc G. Bulot Jean-Louis Latil Alex Hairabian Arnaud Fournillon 《Proceedings of the Geologists' Association. Geologists' Association》2014
Nolaniceras nolani ( Seunes, 1887) has been widely quoted in the Upper Aptian literature over the years. Re-examination of the holotype of the species shows that it has always been misidentified and that this taxon is represented by a single specimen, the holotype, of uncertain age. As a consequence, its use as an index species for the Upper Aptian should be reconsidered and abandoned. 相似文献
30.
Nicolas Van Nieuwenhove Henning A. Bauch Frédérique Eynaud Evguenia Kandiano Elsa Cortijo Jean-Louis Turon 《Quaternary Science Reviews》2011,30(7-8):934-946
The Last Interglacial (Marine Isotopic Stage or MIS 5e) surface ocean heat flux from the Rockall Basin (NE Atlantic) towards the Arctic Ocean was reconstructed by analysing dinoflagellate cyst (dinocyst) assemblages in four sediment cores. Together with records of stable isotopes and ice-rafted detritus, the assemblage data reflect the northward retreat of ice(berg)-laden waters and the gradual development towards interglacial conditions at the transition from the Saalian deglaciation (Termination II) into MIS 5e. At the Rockall Basin, this onset of the Last Interglacial is soon followed by the appearance of the thermophilic dinocyst species Spiniferites mirabilis, with relative abundances higher than those observed at present in the area. North of the Iceland-Scotland Ridge, however, S. mirabilis only appears in significant numbers during late MIS 5e, between ~118 and 116.5 ka. Hence, fully marine Last Interglacial conditions with most intense Atlantic surface water influence occurred during late MIS 5e in the Nordic seas, and consequently also farther north in the Arctic Ocean, and at times when northern hemisphere summer insolation was already significantly decreased. The stratigraphic position of this Late Interglacial optimum is supported by planktic foraminifers and contrasts with the timing of the early Holocene climatic optimum in this area. We interpret the delayed northward expansion of Atlantic waters towards the polar latitudes as a result of the Saalian ice sheet deglaciation and its specific impact on the subsequent water mass evolution in this region. 相似文献