On the interpretation of inter-model spread in CMIP5 climate sensitivity estimates

This study diagnoses the climate sensitivity, radiative forcing and climate feedback estimates from eleven general circulation models participating in the Fifth Phase of the Coupled Model Intercomparison Project (CMIP5), and analyzes inter-model differences. This is done by taking into account the fact that the climate response to increased carbon dioxide (CO₂) is not necessarily only mediated by surface temperature changes, but can also result from fast land warming and tropospheric adjustments to the CO₂ radiative forcing. By considering tropospheric adjustments to CO₂ as part of the forcing rather than as feedbacks, and by using the radiative kernels approach, we decompose climate sensitivity estimates in terms of feedbacks and adjustments associated with water vapor, temperature lapse rate, surface albedo and clouds. Cloud adjustment to CO₂ is, with one exception, generally positive, and is associated with a reduced strength of the cloud feedback; the multi-model mean cloud feedback is about 33 % weaker. Non-cloud adjustments associated with temperature, water vapor and albedo seem, however, to be better understood as responses to land surface warming. Separating out the tropospheric adjustments does not significantly affect the spread in climate sensitivity estimates, which primarily results from differing climate feedbacks. About 70 % of the spread stems from the cloud feedback, which remains the major source of inter-model spread in climate sensitivity, with a large contribution from the tropics. Differences in tropical cloud feedbacks between low-sensitivity and high-sensitivity models occur over a large range of dynamical regimes, but primarily arise from the regimes associated with a predominance of shallow cumulus and stratocumulus clouds. The combined water vapor plus lapse rate feedback also contributes to the spread of climate sensitivity estimates, with inter-model differences arising primarily from the relative humidity responses throughout the troposphere. Finally, this study points to a substantial role of nonlinearities in the calculation of adjustments and feedbacks for the interpretation of inter-model spread in climate sensitivity estimates. We show that in climate model simulations with large forcing (e.g., 4 × CO₂), nonlinearities cannot be assumed minor nor neglected. Having said that, most results presented here are consistent with a number of previous feedback studies, despite the very different nature of the methodologies and all the uncertainties associated with them.     

LMDZ5B: the atmospheric component of the IPSL climate model with revisited parameterizations for clouds and convection

Based on a decade of research on cloud processes, a new version of the LMDZ atmospheric general circulation model has been developed that corresponds to a complete recasting of the parameterization of turbulence, convection and clouds. This LMDZ5B version includes a mass-flux representation of the thermal plumes or rolls of the convective boundary layer, coupled to a bi-Gaussian statistical cloud scheme, as well as a parameterization of the cold pools generated below cumulonimbus by re-evaporation of convective precipitation. The triggering and closure of deep convection are now controlled by lifting processes in the sub-cloud layer. An available lifting energy and lifting power are provided both by the thermal plumes and by the spread of cold pools. The individual parameterizations were carefully validated against the results of explicit high resolution simulations. Here we present the work done to go from those new concepts and developments to a full 3D atmospheric model, used in particular for climate change projections with the IPSL-CM5B coupled model. Based on a series of sensitivity experiments, we document the differences with the previous LMDZ5A version distinguishing the role of parameterization changes from that of model tuning. Improvements found previously in single-column simulations of case studies are confirmed in the 3D model: (1) the convective boundary layer and cumulus clouds are better represented and (2) the diurnal cycle of convective rainfall over continents is delayed by several hours, solving a longstanding problem in climate modeling. The variability of tropical rainfall is also larger in LMDZ5B at intraseasonal time-scales. Significant biases of the LMDZ5A model however remain, or are even sometimes amplified. The paper emphasizes the importance of parameterization improvements and model tuning in the frame of climate change studies as well as the new paradigm that represents the improvement of 3D climate models under the control of single-column case studies simulations.     

Analysis of the experimental compressibility of deep water marine sediments from the Gulf of Guinea

This study strives to analyze the compressibility of deep water marine sediments originating from the Gulf of Guinea. Our approach is multi-scaled and, on the macroscopic level, based on two equations which link the overburden effective stress with the liquidity index, the Biarez & Favre equation on the one hand, and the Burland equation on the other hand (after calculation of the ICL expression as a function of the I_L parameter). On the local level, the evolution of the microstructures is analysed and compared with GoG remoulded clay. Two additional observation techniques have been used, the scanning electron microscope and the mercury intrusion porosimetry.     

On the cratonization of the Arabian-Nubian Shield:Constraints from gneissic granitoids in south Eastern Desert,Egypt

The Shaitian granite complex(SGC) spans more than 80 Ma of crustal growth in the Arabian–Nubian Shield in southeast Egypt.It is a voluminous composite intrusion(60 km~2) comprising a host tonalite massif intruded by subordinate dyke-like masses of trondhjemite,granodiorite and monzogranite.The host tonalite,in turn,encloses several,fine-grained amphibolite enclaves.U-Pb zircon dating indicates a wide range of crystallization ages within the SGC(800 ± 18 Ma for tonalites;754 ± 3.9 Ma for trondhjemite;738 ± 3.8 Ma for granodiorite;and 717 ± 3.2 Ma for monzogranite),suggesting crystallization of independent magma pulses.The high positiveεNdi(+6–+8) indicate that the melting sources were dominated by juvenile material without any significant input from older crust.Application of zircon saturation geothermometry indicates increasing temperatures during the generation of melts from 745 ± 31 ℃ for tonalite to 810 ± 25 ℃ for trondhjemite;840 ± 10 ℃ for granodiorite;and 868 ± 10 ℃ for monzogranite.The pressure of partial melting is loosely constrained to be below the stability of residual garnet(10 kbar) as inferred from the almost flat HREE pattern((Gd/Lu)N= 0.9–1.1),but 3 kbar for the stability of residual amphibole as inferred from the significantly lower NbNand TaNcompared with LREENand the sub-chondrite Nb/Ta ratios exhibited by the granitic phases.The inverse relation between the generation temperatures and the ages estimates of the granitoid lithologies argue against a significant role of fractional crystallization.The major and trace element contents indicate the emplacement of the SGC within a subduction zone setting.It lacks distinctive features for melt derived from a subducted slab(e.g.high Sr/Y and high(La/Yb)Nratios),and the relatively low MgO and Ni contents in all granite phases within the SGC suggest melting within the lower crust of an island arc overlying a mantle wedge.Comparison with melts produced during melting experiments indicates an amphibolite of basaltic composition is the best candidate as source for the tonalite,trondhjemite and granodiorite magmas whereas the monzogranite magma is most consistent with fusion of a tonalite protolith.Given the overlapping Sm-Nd isotope ratios as well as several trace element ratios between monzogranite and tonalite samples,it is reasonable to suggest that the renewed basaltic underplating may have caused partial melting of tonalite and the emplacement of monzogranite melt within the SGC.The emplacement of potassic granite(monzogranite) melts subsequent to the emplacement of Na-rich granites(tonalitetrondhjemite-granodiorite) most likely suggests major crustal thickening prior arc collision and amalgamation into the over thickened proto-crust of the Arabian-Nubian shield.Eventually,after complete consolidation,the whole SGC was subjected to regional deformation,most probably during accretion to the Saharan Metacraton(arc–continent collisions) in the late Cryogenian-Ediacaran times(650–542 Ma).     

Photométries comparées des émissions de l'hydrogène et de l'hélium dans les régions externes des protubérances

Résumé La variation du rapport d'intensités H/D3 est étudiée dans les régions périphériques de deux protubérances d'éclat assez faibles et qui étaient suspendues au-dessus de la chromosphère. La partie supérieure des protubérances est relativement plus intense en D3, tandis qu'en dessous des protubérances le phénomène inverse s'observe. Il faut considérer que ces variations ne peuvent pas s'expliquer par des phénomènes de saturation, mais pourraient résulter du régime dynamique de la matière qui émet les radiations observées.     

Lithospheric mantle beneath the south-eastern Siberian craton: petrology of peridotite xenoliths in basalts from the Tokinsky Stanovik

We provide petrographic, major and trace element data for over 30 spinel peridotite xenoliths from the Tokinsky Stanovik (Tok) volcanic field on the Aldan shield to characterize the lithospheric mantle beneath the south-eastern margin of the Siberian craton, which formed in the Mesoproterozoic. High equilibration temperatures (870–1,010°C) of the xenoliths and the absence of garnet-bearing peridotites indicate a much thinner lithosphere than in the central craton. Most common among the xenoliths are clinopyroxene-poor lherzolites and harzburgites with Al₂O₃ and CaO contents nearly as low as in refractory xenoliths from kimberlite pipes (Mir, Udachnaya) in the central and northern Siberian craton. By contrast, the Tok peridotites have higher FeO, lower Mg-numbers and lower modal orthopyroxene and are apparently formed by shallow partial melting (3 GPa). Nearly all Tok xenoliths yield petrographic and chemical evidence for metasomatism: accessory phlogopite, amphibole, phosphates, feldspar and Ti-rich oxides, very high Na₂O (2–3.1%) in clinopyroxene, LREE enrichments in whole-rocks.Electronic Supplementary Material Supplementary material is available for this article at     

A conceptual hydrogeological model of ophiolite hard-rock aquifers in Oman based on a multiscale and a multidisciplinary approach

Ophiolites are found all over the world: from the Alps to the Himalayas, in Cuba, Papua-New Guinea, New Caledonia, Newfoundland, etc. They are composed of hard rocks—basalt, dolerite, gabbro and peridotite, which are formed at the mid-oceanic ridges, with specific ridge-related tectonic fracturing and intense hydrothermal alteration. Their geological and thus their hydrogeological properties differ from those of both granite or classical gabbro and classical basaltic lava. A conceptual hydrogeological model of these hard-rock aquifers was developed based on the convergent results of a multidisciplinary approach at several spatial scales, from rock-sample (centimetre) to catchment (kilometre), on well-preserved ophiolite rocks in Oman. In ophiolite rocks, groundwater circulation takes place mostly in the fissured near-surface horizon (50 m thick), and, to a lesser degree, in the tectonic fractures. Hydrograph analysis (Water Resour Res 34:233–240, 1977), interpretation of numerous pumping tests using both classical Theis and dual porosity models [Water Resour Res 32:2733–2745, 1996; Comput Geosci J (in press)], and mercury porosity and hydraulic conductivity lab-measurements support the aquifer parameter estimates. The hydraulic conductivity K of the fissured horizon is estimated at 10^–5 to 10^–6 m/s for gabbro and dolerite, and 10^–7 m/s for peridotite. The storage coefficient S of the peridotite aquifer is estimated at 10^–3 and appears to be controlled mainly by microcracks (20 to 100 m wide). Tectonic fractures in the ophiolite have similar hydrodynamic properties regardless of lithology (10^–1<T<10^–4 m²/s and 10^–1<S<10^–3) though the probability of obtaining productive wells is two to three times greater in gabbro and dolerite than in peridotite. Some of the tectonic fractures produce small hydrothermal, hyperalkaline springs in the peridotite. The water budget and hydrochemistry of the Oman ophiolite are characterized and support the conceptual hydrogeological model. Despite low annual rainfall, a relatively low hydraulic conductivity and a significant storage coefficient explain why most of the streams in peridotite are perennial.

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Résumé Les ophiolites se trouvent partout dans le monde : des Alpes à lHymalaya, à Cuba, Papouasie Nouvelle-Guinée, Nouvelle Calédonie, etc. Les ophiolites sont composées de roches dures basaltiques, de dolérites, gabbros et péridotites, qui sont formées aux rides mi-océaniques, avec, en relation avec les rides, une fracturation tectonique et une altération hydrothermale intense. Leurs propriétés géologiques et hydrogéologiques diffèrent de celles des granites ou des gabbros classiques ou des laves basaltiques classiques. Un modèle hydrogéologique conceptuel des aquifères de hard-rock a été développé sur les résultats convergents dune approche multidisciplinaire à différentes échelles spatiales, de léchantillon de roche de quelques centimètres à la taille du bassin versant en kilomètres, des ophiolites bien conservées dOman. Dans les roches ophiolitiques, la circulation des eaux souterraines est surtout localisée dans les fissures dun horizon de surface de plus dune cinquantaine de mètres et à un degré moindre dans les fractures tectoniques. Lanalyse des hydrographes (Water Resour Res 34:233–240, 1977), linterprétation des nombreux essais de pompage utilisant des modèles classiques de Theis et des modèles à double porosité (Water Resour Res 32:2733–2745, 1996; Comput Geosci J (Soumis), la porosité au mercure et la conductivité hydraulique calculée en laboratoire supportent lestimation des paramètres de laquifère. La conductivité hydraulique K de lhorizon fissuré est estimée entre 10^–5 et 10^–6 m/s pour les gabbros et les dolérites, et 10^–7 m/s pour les péridotites. Le coefficient demmagasinement S de laquifère de péridotite est estimé à 10^–3 et semble être contrôlé par les micro-fractures (20 à 100 m de largeur). Les fractures tectoniques dans les ophiolites possèdent des propriétés hydrodynamiques en regard de la lithologie (10-1<T<10-4 m²/s et 10-1/S/10-3) bien que la probabilité dobtenir des puits productifs est trois plus grand dans le grabbro et la dolérite que la péridétite. Quelques unes des fractures tectoniques produisent de petites sources hydrothermales hyperalcalines dans la péridotite. Le bilan hydrologique et hydrochimique de lophiolite dOman caractérise le modèle hydrogéologique conceptuel. Malgré des faibles précipitations annuelles, une relativement basse conductivité hydraulique et un coefficient demmagasinement significatif expliquent pourquoi la plus part des cours deau sur les péridotites ne sont jamais taris.

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Resumen Las rocas ofiolitas se encuentran en muchas partes del mundo desde los Alpes a los Himilaya, Newfoundland, Nueva Caledonia etc. Son rocas duras compuestas de basalto, dolerita, gabro y peridotita que son formadas por los cordones medio-oceánicos y por fracturación relacionada con los cordones tectónicos específicos y alteración hidrotermal intensa. La geología y los propiedades hidrogeológicas varian entre las de granito y gabro clásico y lava de basalto clásico. Se desarrolló un modelo conceptual de los acuíferos de las rocas duras Basado en los resultados convergentes de un enfoce multidisciplinario a varias escalas a partir de muestras de roca (centímetro) a cuenca kilómetro) enfocado en las rocas ofilíticas bien preservados en Oman. En las rocas ofiolíticas la circulación de agua ocurre principalmente en el horizonte de fisuras cercanas a la superficie (>50 m de espesor) y en un grado menos importante en fracturas tectónicas. Los estimados de los parámetros de estos acuíferos se basan en análisis de hidrógrafos (Water Resour Res 34:233–240, 1977), en la interpretación de pruebas de bombeo usando los modelos clásicos de Theis y de porosidad doble (Hamm y Bidaux 1996; Lods y Gouze, [en prensa]), y porosidad de mecurio y conductividad hidraúlica medida en el laboratorio. La conductividad hidraúlica K del horizonte fisurado se estima en 10E-5 a 10E-6 m-s para gabro y dolerita y 10E-7 para peridotita. El coeficiente de abastecimiento S del acuífero peridotita se estima en 10–3 y parece ser controlado principalmente por microfracturas (20 to 100 m de ancho). Las fracturas tectónicas en la ofiolita tienen propiedades hidrodinámicas similares independientes de la litología (10–1<T<10–4 m²/s and 10–1<S<10–3) pero la probabilidad de obtener pozos productivos es dos o tres veces mayor en gabro que en dolerita o peridotita. Algunas de las fracturas tectónicas producen pequeñas descargas de agua hidrotermal hiperalcalina en la peridotita. El presupuesto e hidroquímica de las ofilitas de Omán se caracteriza y apoya en el modelo conceptual hidrogeológico. La baja lluvia anual, una conductividad hidraúlica relativamente baja y un coeficiente de abastecimiento importante explican porqué la mejoría de los drenajes en peridotita es peremne.

     

Direct barite determination using SEM/EDS-ACC system: implication for constraining barium carriers and barite preservation in marine sediments

Barite (BaSO₄) in marine sediments is considered as a proxy of surface ocean productivity and is widely used for paleo-productivity reconstructions. However, direct barite determination is not achieved by currently used methods, which rely on the measurement of total barium by inductively coupled plasma–mass spectrometry (ICP-MS) and instrumental neutron activation analysis (INAA) and correction from the allogenic Ba contribution. We report here on a technique that directly counts individual barite crystals using a scanning electron microscope (SEM) coupled to an energy dispersive spectrometer (EDS) equipped with an automated particle counting and classification (ACC) system. We show that barite–Ba concentrations can be deduced from the abundance, shape and size distributions of barite crystals with current precision and sensitivity as high as ±5 wt.% (2σ confidence limit) and 10 ppm, respectively. This technique, coupled with ICP-MS and INAA techniques for total Ba measurements, was applied to sediment samples from the tropical North Atlantic and the Central North Pacific oceans. Results show that: (1) barite and detrital aluminosilicates are the two main carriers of Ba in the investigated sediments; (2) calculated Ba/Al ratios range from 0.005 to 0.008 with an average value around 0.0066, in close agreement with previously reported values; (3) barite might not be the major source for released barium out of sediments and we suggest instead adsorbed barium as a potential source.     

Comparison of β-dimethylsulfoniopropionate (DMSP) levels in two mediterranean ecosystems with different trophic levels

β-dimethylsulfoniopropionate (DMSP) and dimethylsulfide (DMS) concentrations were recorded from September 1999 to September 2000 in two geographically close ecosystems, differently affected by eutrophication: the Little Bay of Toulon and the Niel Bay (N.W. Mediterranean Sea, France). Little Bay had higher nutrient levels ([NO₃⁻]_max. = 30.3 μM; [PO₄³⁻]_max. = 0.46 μM) and higher chlorophyll a concentrations ([chl a]_mean = 2.4 μg/L) compared to Niel Bay ([NO₃⁻]_max. = 19.7 μM; [PO₄³⁻]_max. = 0.17 μM; [chl a]_mean = 0.4 μg/L). In the two sites, we measured dissolved (DMSP_d < 0.2 μm) and particulate DMSP (DMSP_p > 0.2 μm) concentrations. The DMSP_p was particularly analysed in the 0.2–5, 5–90 and > 90 μm fractions. In the eutrophicated Little Bay, DMSP_d concentrations showed a clear seasonality with high values from January to March (124–148 nM). The temporal profile of the DMSP_p concentrations was similar, peaking in February–March (38–59 nM). In the less eutrophic Niel Bay, DMSP_p concentrations were much lower (6–9 nM in March–April), whereas DMSP_d concentrations were relatively high (110–92 nM in February–March). DMS concentrations were elevated from the end of the winter to the spring in Little Bay, ranging from 3 nM in October to 134 nM in March. In the less eutrophic Niel Bay, lower DMS levels were observed, generally not exceeding 20 nM. Each particulate fraction (0.2–5; 5–90; > 90 μm) contained less DMSP in Niel Bay than in Little Bay. At both sites, the 5–90 μm fraction made up most of the DMSP_p. This 5–90 μm fraction consisted of microphytoplankton, principally Dinophyceae and Bacillariophyceae. The 5–90 μm biomass calculated from cell biovolumes, was more abundant in Little Bay where the bloom at the end of the winter (165 μg/L in March) occurred at the same time as the DMSP peaks. The estimated DMSP_p to biomass ratio for the 5–90 μm fraction was always higher in Little Bay than in Niel Bay. This suggests that the high DMSP levels recorded in Little Bay were not only due to a large Dinophyceae presence in this ecosystem. Indeed, the peak of DMSP_p to biomass ratio obtained from cell biovolumes (0.23 nmol/μg in March) was consistent with the proliferation of Alexandrium minutum. This Dinophyceae species may account for between 50% (2894 cells/L) and 63% (4914 cells/L) of the total phytoplankton abundance in the Little Bay of Toulon.