A Mössbauer and FTIR study of synthetic amphiboles along the magnesioriebeckite – ferri-clinoholmquistite join

A series of amphiboles along the magnesioriebeckite—Na₂Mg₃Fe³⁺ ₂Si₈O₂₂(OH)₂– ferri-clinoholmquistite—Li₂Mg₃Fe³⁺ ₂Si₈O₂₂(OH)2 - join, defined by the ^BLi^B Na_–1 exchange vector, were hydrothermally synthesized at 700°C, 0.4 GPa, NNO + 1 redox conditions. Powder XRD and SEM-EDAX showed a very high (> 90%) amphibole yield for all samples. X-ray patterns were indexed in the C2/m space group; refined cell-parameters show a linear decrease of a and as a function of chemistry. IR spectra in the OH-stretching region show four main and rather sharp bands; these are assigned to Mg and Fe²⁺ at M(1,3), and indicate that the obtained amphiboles depart from the nominal octahedral composition (^M1,3Mg₃). The IR spectra also show that there is an increasing filling-up of the A-site for increasing Na in the system (increasing solid-solution toward, arfvedsonite). Mössbauer spectra show four well-defined quadrupole doublets which are assigned to Fe³⁺ at M2 and to Fe²⁺ at M1, M3 and M4, respectively. The Fe³⁺/Fe²⁺ content derived from fitted peak areas show variable Fe³⁺ concentration along the series. Mössbauer spectra also show a distinct alteration of ⁵⁷Fe hyperfine parameters with changing Na–Li at M4. The most evident variation is observed for the quadrupole splitting of Fe³⁺ at M2, which increases by 50% from ferri-clinoholmquistite to magnesio-riebeckite; this suggest that the M2 octahedron in ferri-clinoholmquistite is much closer to the ideal geometry than the M2 octahedron in magnesio-riebeckite. Mössbauer spectra show also a well-defined increase in the Fe²⁺ quadrupole splitting of the M1 and M3 octahedra, which is attributed to the Na–Li distribution at the B-sites.     

The Multiscale TROPIcal CatchmentS critical zone observatory M-TROPICS dataset III: Hydro-geochemical monitoring of the Mule Hole catchment,south India

Despite the importance of tropical ecosystems for climate regulation, biodiversity, water and nutrient cycles, only a few Critical Zone Observatories (CZOs) are located in the tropics. Among these, most are in humid climates, while very few data exist for semi-arid and sub-humid climates, due to the difficulty of estimating hydro-geochemical balances in catchments with ephemeral streams. We contribute to fill this gap by presenting a meteorological and hydro-geochemical dataset acquired at the Mule Hole catchment (4.1 km²), a pristine dry deciduous forest located in a biosphere reserve in south India. The dataset consists of time series of variables related to (i) meteorology, including rainfall, air temperature, relative humidity, wind speed and direction, and global radiation, (ii) hydrology, including water level and discharge at the catchment outlet, (iii) hydrogeology, including manual (monthly) and/or automated (from 15 min to hourly) groundwater levels in nine piezometers and (iv) geochemistry, including suspended sediment content in the stream and chemical composition of rainfall (event based), groundwater (monthly sampling) and stream water (storm events, 15 min to hourly frequency with an automatic sampler). The time series extend from 2003 to 2019. Measurement errors are minimized by frequent calibration of sensors and quality checks, both in the field and in the laboratory. Despite these precautions, several data gaps exist, due to occasional access restriction to the site and instrument destruction by wildlife. Results show that large seasonal and interannual variations of climatic conditions were reflected in the large variations of stream flow and groundwater recharge, as well as in water chemical composition. Notably, they reveal a long-term evolution of groundwater storage, suggesting hydrogeological cycles on a decadal scale. This dataset, alone or in combination with other data, has already allowed to better understand water and element cycling in tropical dry forests, and the role of forest diversity on biogeochemical cycles. As tropical ecosystems are underrepresented by Critical Zone Observatories, we expect this data note to be valuable for the global scientific community.     

Report on the 4th International Meeting of the IUGS Lower Cretaceous Ammonite Working Group, the “Kilian Group” (Dijon, France, 30th August 2010)

The 4th Kilian Group meeting (Dijon, France, 30th August 2010) focused on the Aptian and Albian Stages. For the Aptian, a two-fold division of the stage was adopted for the Mediterranean area with a boundary between the Dufrenoyia furcata and Epicheloniceras martini Zones. The main changes to the zonal scheme concern the Lower Aptian with: the introduction of a Deshayesites luppovi Subzone in the upper part of the Deshayesites oglanlensis Zone; the replacement of Deshayesites weissi by Deshayesites forbesi as new index-species of the second interval zone; the introduction of a Roloboceras hambrovi Subzone in the upper part of the D. forbesi Zone; and the subdivision of the D. furcata Zone into the D. furcata and Dufrenoyia dufrenoyi Subzones. For the Albian, the upper part of the Douvilleiceras mammillatum Zone (Lower Albian) is now characterized by a Lyelliceras pseudolyelli Subzone. The main amendments concern the Upper Albian. The base of this substage is defined by the base of the Dipoloceras cristatum Zone. Above it, the Upper Albian zonal scheme comprises in stratigraphic order the Mortoniceras pricei, Mortoniceras inflatum, Mortoniceras fallax, Mortoniceras rostratum, Mortoniceras perinflatum and Arrhaphoceras briacensis Zones.     

The Pliensbachian ammonites of the Algarve Basin (Portugal) and their palaeobiogeographical significance for the “Iberia-Newfoundland” conjugate margins

A review of the Pliensbachian ammonite faunas of the Algarve Basin is given covering their taxonomy, stratigraphy and palaeobiogeography (palaeobiodiversity). This review is based on both an extensive revision of the previously collected and/or published material and on new finds precisely located within the ammonite succession. This new material allows us to clarify the variations within the most abundant species—a new species Reynesocoeloceras elmii nov. sp. is described—and to improve our understanding (palaeobiodiversity, palaeobiogeography and bio- or chrono-stratigraphy) of the two single known Pliensbachian fossiliferous assemblages in the Algarve Basin. The first of these assemblages is relatively diverse and is ascribed to the upper half of the Luridum Subchronozone. The second assemblage is less diversified and probably partly condensed. It is broadly attributed to the upper half of the Stokesi Subchronozone. Despite the newly collected ammonites and extensive prospecting, our knowledge of the Pliensbachian ammonite faunas of the Algarve remains fragmentary. Therefore, it is difficult to propose an incontrovertible extensive palaeobiogeographical interpretation for these faunas, but it seems that Tethyan (Mediterranean) affinities were of major importance whereas there were probably no NW European influences via the Lusitanian Basin.     

The Séchilienne (France) Landslide:a Non-typical Progressive Failure Implying Major Risks

The National Road RN 91 has been threatened for about twenty-five years by a huge landslide, located 25 km south-east to the town of Grenoble (France). If several million cubic meters of rock fall down, the debris will dam the valley. Then the failure of the dam by overtopping and rapid erosion might result in a catastrophic flood and dramatic consequences for human life, environment and economy throughout the valley. The paper presents the hazard assessment based on geological and hydrological surveys, including small scale hydraulic tests, as well as the risk evaluation that has been performed. The risk management relies first upon a high level monitoring and an emergency plan; various mitigation strategies have been considered.     

Comparisons of interplanetary type III storm footpoints with solar features

The trajectories of 38 type III storms in the interplanetary medium have been deduced from ISEE-3 radio observations and extrapolated back to the Sun to determine the Carrington coordinates of their footpoints. The analysis assumes radial motion of the solar wind, and the trajectories are projected radially back toward the surface for the last few solar radii. To identify the storm sources, the footpoints were compared to a variety of solar features: to the large-scale neutral line at the base of the current sheet, to active regions, to the small-scale neutral lines and Hα filaments which trace out active regions, and to coronal holes. Most of the footpoints were found to lie near active regions, in agreement with metric storm locations. There is a weak correlation with Hα filaments, no apparent association with the current sheet, and an anticorrelation with coronal holes. There is a small excess of storms in the leading half of magnetic sectors.     

Farside explorer: unique science from a mission to the farside of the moon

Farside Explorer is a proposed Cosmic Vision medium-size mission to the farside of the Moon consisting of two landers and an instrumented relay satellite. The farside of the Moon is a unique scientific platform in that it is shielded from terrestrial radio-frequency interference, it recorded the primary differentiation and evolution of the Moon, it can be continuously monitored from the Earth–Moon L2 Lagrange point, and there is a complete lack of reflected solar illumination from the Earth. Farside Explorer will exploit these properties and make the first radio-astronomy measurements from the most radio-quiet region of near-Earth space, determine the internal structure and thermal evolution of the Moon, from crust to core, and quantify impact hazards in near-Earth space by the measurement of flashes generated by impact events. The Farside Explorer flight system includes two identical solar-powered landers and a science/telecommunications relay satellite to be placed in a halo orbit about the Earth–Moon L2 Lagrange point. One lander would explore the largest and oldest recognized impact basin in the Solar System— the South Pole–Aitken basin—and the other would investigate the primordial highlands crust. Radio astronomy, geophysical, and geochemical instruments would be deployed on the surface, and the relay satellite would continuously monitor the surface for impact events.     

Brittle tectonics and major dextral strike-slip zone in the Buda karst (Budapest,Hungary)

Abstract

Three large (kilometric-scale) caves were studied in the Buda hills and the main directions of cave corridors, fault planes and mineralized veins were measured. Different stages of mineralizations are recognised: calcite scaleno- hedrons, baryte, silica, gypsum. New investigations of fluid inclusions in the baryte suggest a crystallization temperature of 50 °C and a freshwater fluid source. Microtectonic analysis allows the reconstruction of the successive tectonic events: (1) a NE-SW extensional phase at the Late Eocene-Early Oligocene limit (phase I), (2) a strike-slip phase with NW-SE compression and NE-SW extension during the Late Oligocene-Early Miocene (phase II), (3) a NW-SE transten- sional phase (phase III) and finally (4) a NE-SW extensional phase of Quaternary age (phase IV). The major phase is the strike-slip one, characterized by an important dextral strike- slip zone: the Ferenc-hegy zone. © Elsevier, Paris     

Evidence for solar forcing in variability of temperatures and pressures in Europe

Daily temperature and pressure series from 55 European meteorological stations covering the 20th century are analyzed. The overall temperature mean displays a sharp minimum near 1940 and a step-like jump near 1987. We evaluate the evolution of disturbances of these series using mean squared inter-annual variations and “lifetimes”. The decadal to secular evolutions of solar activity and temperature disturbances display similar signatures over the 20th century. Because of heterogeneity of the climate system response to solar forcing, regional and seasonal approaches are key to successful identification of these signatures. Most of the solar response is governed by the winter months, as best seen near the Atlantic Ocean. Intensities of disturbances vary by factors in excess of 2, underlining a role for the Sun as a significant forcing factor of European atmospheric variations. We speculate about the possible origin of these solar signatures. The last figure of the paper exemplifies its main results.