Long-term thermal evolution and effect of low power heating in an underground quarry

Vertical profiles of temperature have been monitored in the atmosphere of an underground quarry since June 2001. A long-term temperature increase of the order of 0.1 °C per year is observed. Three heating experiments with 100-W sources, performed to study plume dynamics, can also be used to investigate the effect of visits on this increase. Ten days after the 24-h heatings, the initial state is not restored. Artificial contributions to the observed long-term temperature trend, triggered by internal heat release, thus cannot be ruled out. This experiment defines strict criteria for the underground monitoring of global warming or the preservation of painted caves. To cite this article: C. Crouzeix et al., C. R. Geoscience 335 (2003).     

An integrated paleomagnetic study of Rio Grande de Santiago volcanic succession (trans-Mexican volcanic belt): revisited

We carried out an integrated paleomagnetic, rock-magnetic and paleointensity study of Miocene volcanic succession from the trans-Mexican volcanic belt (TMVB) north of Guadalajara. A total of 37 consecutive basaltic lava flows (326 oriented standard paleomagnetic cores) were collected at Lazo locality. Continuous susceptibility measurements with temperature and hysteresis experiments yield in most cases reasonably reversible curves with Curie points close to that of pseudo-single-domain magnetite. Two geomagnetic reversals were observed in the 300 m thick composite section. Paleosecular variation was lower than the one observed in general during Miocene. It appears that the volcanic units have been emplaced during a relatively short time span of about 1 Ma. The mean paleomagnetic directions obtained from this study do not differ significantly from that expected for the middle Miocene. The mean paleomagnetic direction calculated from all data is I=31.1°, D=354.6°, k=124 and ₉₅=2.1°, N=37. Seventy-two samples with apparently preserved primary magnetic mineralogy and without secondary magnetization, mostly belonging to reverse polarity chron were pre-selected for Thellier paleointensity determination. The flow-mean paleointensity values are ranging from 22.4±3.4 to 53.8±6.0 μT and the corresponding virtual dipole moments (VDMs) are ranging from (5.4±0.8) to (12.0±1.4)×10²² A m². This corresponds to mean value of (7.7±2.2)×10²² A m², which is close to present day geomagnetic field strength. Altogether, our data suggest the existence of relatively high geomagnetic field strength undergoing low fluctuations.     

Quantitative Zn speciation in a contaminated dredged sediment by μ-PIXE, μ-SXRF, EXAFS spectroscopy and principal component analysis

Dredging and disposal of sediments onto agricultural soils is a common practice in industrial and urban areas that can be hazardous to the environment when the sediments contain heavy metals. This chemical hazard can be assessed by evaluating the mobility and speciation of metals after sediment deposition. In this study, the speciation of Zn in the coarse (500 to 2000 μm) and fine (<2 μm) fractions of a contaminated sediment dredged from a ship canal in northern France and deposited on an agricultural soil was determined by physical analytical techniques on raw and chemically treated samples. Zn partitioning between coexisting mineral phases and its chemical associations were first determined by micro-particle-induced X-ray emission and micro-synchrotron-based X-ray radiation fluorescence. Zn-containing mineral species were then identified by X-ray diffraction and powder and polarized extended X-ray absorption fine structure spectroscopy (EXAFS). The number, nature, and proportion of Zn species were obtained by a coupled principal component analysis (PCA) and least squares fitting (LSF) procedure, applied herein for the first time to qualitatively (number and nature of species) and quantitatively (relative proportion of species) speciate a metal in a natural system.The coarse fraction consists of slag grains originating from nearby Zn smelters. In this fraction, Zn is primarily present as sphalerite (ZnS) and to a lesser extent as willemite (Zn₂SiO₄), Zn-containing ferric (oxyhydr)oxides, and zincite (ZnO). In the fine fraction, ZnS and Zn-containing Fe (oxyhydr)oxides are the major forms, and Zn-containing phyllosilicate is the minor species. Weathering of ZnS, Zn₂SiO₄, and ZnO under oxidizing conditions after the sediment disposal accounts for the uptake of Zn by Fe (oxyhydr)oxides and phyllosilicates. Two geochemical processes can explain the retention of Zn by secondary minerals: uptake on preexisting minerals and precipitation with dissolved Fe and Si. The second process likely occurs because dissolved Zn and Si are supersaturated with respect to Zn phyllosilicate. EXAFS spectroscopy, in combination with PCA and LSF, is shown to be a meaningful approach to quantitatively determining the speciation of trace elements in sediments and soils.     

Apport de la modélisation géophysique pour la compréhension de la structuration du pas de Calais

This study is based on an analysis of seismic, gravimetric and magnetic data to model the structure of the Dover Straits area. The Dover Straits are set in a transitional position within the Brabant para-autochthon, which lies between the Ardennes allochthon to the south and the Brabant Massif to the north. The seismic profiles show that this area is characterised by several superimposed Mesozoic basins, whose evolution has been controlled by the reactivation of Lower Palaeozoic faults. In common with the adjacent Weald–Wessex and southern North Sea basins, the Dover Straits area records a Jurassic extensional phase and a post-Cretaceous tectonic inversion. The geophysical modelling reveals the presence of a basement to these Mesozoic basins that exhibits Ordovician to Silurian structures, which cannot be detected on the seismic reflection profiles. In contrast to earlier interpretations, the modelling presented here suggests that the Brabant Massif continues southward beyond the Dover Straits and under the Brabant para-autochthon. Gravity data also provides evidence for the presence of granitic body at depth, in the vicinity of Km 27 on the seismic profile, which may have driven the uplift of the Silurian rocks in the area of the Straits. Similar granitic intrusions have been proposed to explain gravity anomalies along the Rhenohercynian Margin in Belgium, eastern and southern England. The geophysical modelling demonstrates the continuity of the basement and Mesozoic basin structures across the Dover Straits, suggesting a common geological evolution of the adjacent southern England–northern France regions. To cite this article: B. Minguely et al., C. R. Geoscience 337 (2005).     

Premières datations de feux holocènes dans les Monts de Saint-Guilhem-le-Désert (Hérault,France), contribution à l'histoire de la forêt relique de Pinus nigra Arnold ssp Salzmanni (Dun.) Franco

The charcoal discovery in the soils and sediments of the relic forest of Pinus nigra ssp Salzmanni near Saint-Guilhem-le-Désert allows us to establish a chronology of Holocene fires. Their origin dates from the Middle Holocene, but they are especially significant after the construction of the medieval abbey during the 9th century. The original pine plantation was heterogeneous, with another pine, Pinus sylvestris, which has now been eradicated. Changes in the fire modes have been observed, recent human fires being generalized, which resulted in a significant regression of the forest cover, which was replaced by box-tree formations. To cite this article: J.-L. Vernet et al., C. R. Geoscience 337 (2005).     

Chemical weathering in the drainage basin of a tropical watershed (Nsimi-Zoetele site, Cameroon) : comparison between organic-poor and organic-rich waters

This study deals with the weathering processes operating at the scale of a small catchment (Nsimi-Zoetele, Cameroon) and is focused on the role of organic colloids on mineral weathering and transport of elements in natural waters. Samples of river, spring and groundwaters from Nsimi-Zoetele were filtered through membranes of decreasing pore size (0.22 μm, 0.025 μm, or: 300,000 Da, 5000 Da) to separate colloidal fractions from the truly dissolved one. Major and trace elements and dissolved organic carbon (DOC) were analysed in each fraction. Two kinds of waters can be distinguished in the catchment: clear and coloured waters. Clear waters exhibit low concentrations of major and trace elements and DOC. Elements are carried in these solutions in a true dissolved form except Al and rare earth elements (REEs). By contrast, the higher abundances of Al, Fe and trace elements in coloured waters are controlled by the colloidal fraction. Thermodynamic equilibrium calculations show that clear waters are in equilibrium with kaolinite and iron oxi-hydroxide which are major minerals in the weathered soil. For coloured waters, the aqueous speciation of Ca, Mg, Cu, Fe, Al, La and Th was calculated taking into account the complexes with humic acids. Speciation calculations for Cu, Fe, Al, La, Th show a strong complexation with humic acids, in good agreement with the results of the filtration experiments. By contrast, although filtration experiments show a strong control of major cations by organic matter (for example 75% for Ca), speciation calculations reveal that their complexes with humic ligands do not exceed a few percent of total dissolved elements. This discrepancy is explained as an artefact induced by the organic colloids and occurring during the filtration procedure. Finally, both filtration experiments and speciation calculations show that organic matter plays an important role in natural DOC-rich waters. Organic acids increase significantly the dissolution rates of silicates and oxi-hydroxides and thus the amounts of solutes and of complexed elements leaving the catchment.     

Palaeosecular variation in Central Mexico over the last 30 000 years: the record from lavas

13 lava flows of known age (ages from ¹⁴C dating), which have been erupted in the last 30 000 years, have been studied to determine the palaeosecular variation of the geomagnetic field in Central Mexico. Samples were taken from two different monogenetic volcanic fields: the Michoacan-Guanajuato volcanic field (six sites) and the Chichinautzin Formation (seven sites), both part of the Transmexican Volcanic Belt. The lavas were studied in detail using rock magnetic methods (magnetic susceptibility at room temperature, low-temperature susceptibility behaviour, hysteresis loops, Curie temperatures), combined with reflected light microscopy, in order to deduce their magnetic mineralogy and the domain states of the magnetic minerals. The magnetic carriers are titanomagnetites, which show differing degrees of high-temperature deuteric oxidation, and seem to be predominantly pseudo-single domain (PSD), though in many cases are probably a mixture of domain states. Mean palaeomagnetic directions and palaeointensity values using Shaw and Thellier techniques were obtained using several specimens from each flow. Our data seem to indicate a sharp easterly swing in declination about 5000 years ago, which is also observed in lake sediments from Central Mexico. The calculated values of the virtual dipole moment (VDM) range from 3.1 to 14.9 × 10²² A m². Our data indicate that the virtual dipole moment seems to have increased gradually in magnitude over the last 30 kyr, with a peak at about 9000 years BP. These are features that have been observed in other parts of the globe and are probably caused by variations in the dipole part of the geomagnetic field.     

Geochemical morphology of the North Mid-Atlantic Ridge, 10°–24°N: Trace element-isotope complementarity

The new data presented here from a 10–24°N segment of the North Mid-Atlantic Ridge show that this segment is the most depleted of the 10–70°N ridge section. They also show the existence of: (1) a geochemical gradient from the 14°N anomaly to 17°10′N; (2) a very depleted mantle source (the lowest Sr isotopic ratios found so far in the North Atlantic); and (3) a geochemical limit located at about 17°10′N without any obvious relation with any structural feature. The 15°20′N fracture zone does not show any relationship with respect to this gradient. The basalts located north of 17°10′N have very homogeneous features, which allow their characteristics to be averaged (i.e., ⁸⁷Sr/⁸⁶Sr= 0.70238 ± 0.00004, (Nb/Zr)_N = 0.28 ± 0.1) and they are defined as normal mid-ocean ridge basalts. The basaltic glasses located south of 17°10′N present a wide spectrum of isotopic compositions and extended rare earth element patterns (from depleted to enriched). Despite this, they have a constant K/Nb of 233 ± 9 (1s_M, n = 18) whereas this ratio is 344 ± 29 north of 17°10′N. These observations illustrate the strong coherence of behaviour between K and Nb (Ta) during the petrogenic processes involved in the generation of these mid-ocean ridge basalts and also their fractionation during previous mantle processes. Possible interpretations of mixing processes are discussed and sources at the ridge segment scale are favoured. However, when looking in detail, local heterogeneities are still common and can even be traced back off-axis to 115 my.

Placed in the context of the North Atlantic Ridge from 10° to 70°N, the Sr isotopic ratios reveal the Azores superstructure (23–50°N), whereas the trace element ratios (La/Sm-Nb/Zr) trace the second-order structures (33–40°N, 42–48°N) superimposed on the superstructure. This study illustrates the complementarity of information given by certain well chosen trace element ratios on the one hand and by isotopic ratios on the other. Since there is evidence of decoupling between isotopic ratios and/or trace element ratios, it introduces the notion of complementary “chemical memory” as recorded by a given type of trace element ratio or a given type of isotopic ratio     

Study of the Santa Catarina aquifer system (Mexico Basin) using magnetotelluric soundings

A tensor magnetotelluric test survey was carried out in the region of Santa Catarina, located in the Chalco sub-basin of the Mexico Basin. The objective was to define the stratification at depth with an emphasis on the geometry of the main aquifer of that region which is partially known from DC resistivity soundings and drilling. High-quality magnetotelluric soundings could be recorded in the immediate vicinity of large urban zones because the sub-surface is very conductive. Interpretation shows that the solid bedrock is located at a depth of at least 800 m to the south and 1300 m to the north; it could, however, be much deeper. Using complementary DC resistivity sounding and well-logging data, three main layers have been defined overlying the bedrock. These layers are, from surface to bottom, an unsaturated zone of sand, volcanic ash and clay about 10 m thick, followed by a very conductive (1.5 ohm·m) 200 m thick layer of sand and ash with intercalated clay, saturated with highly mineralized water, and finally a zone with resistivity increasing gradually to 60 ohm·m. The investigated deep aquifer constitutes most of this third layer. It consists of a sequence of sand, gravel, pyroclastites and mainly fractured basalts. MT resistivity soundings and magnetic transfer functions also indicate that a shallow resistive structure is dipping, from the northwest, into the lacustrine deposits of the basin. This geologic feature is likely to be highly permeable fractured basaltic flows, which provide a channel by which water contaminated by the Santa Catarina landfill may leak into the basin.