Hyperspectral core logging for fire reconstruction studies

Lacustrine sediments contain a wide range of proxies that enable paleoenvironmental reconstructions. For instance, charcoal can be used to document past fire regime changes. In order to analyse high-temporal- and spatial-resolution records, however, it is necessary to develop fast, low-cost and high-stratigraphic-resolution methods. We developed a new paleo-fire proxy by studying a lacustrine core from the Esterel Massif, SE France, an area affected by two recent fire events, in AD 1987 and 2003. For this purpose, we searched for charcoal deposited and preserved in the lake sediments by combining a number of complementary methods, including: classic macrocharcoal tallying, scanning spectrophotometry, scanning hyperspectral imaging and high pressure liquid chromatography analyses. Macrocharcoal quantification is efficient, but time-consuming, and only provides intermediate-resolution data (cm scale). Spectrophotometry, used classically to quantify colour, is very fast, provides high-resolution data (4 mm) and is non-destructive (core preservation). Hyperspectral data have the same advantages as spectrophotometry, but offer higher spatial resolution (64-µm pixel size) and higher spectral resolution (6 nm) for core logging applications. The main result of this research is based on hyperspectral analysis at very high stratigraphic resolution using the I-band index. This index usually measures reflectance values at [660, 670 nm] corresponding to the trough in red reflectance produced by Chlorophyll a and its diagenetic products. This [660, 670 nm] reflectance trough, however, is also affected by the presence of altered organic matter and decreases with altered organic matter such as charcoal particles. Charcoal effect on the reflectance of Chlorophyll a and its diagenetic products is identified on first derivative spectra by a characteristic pattern around 675 nm, which is also in agreement with the Chlorophyll a concentrations measured by high-pressure liquid chromatography and charcoal particles. The I-band index is hence suitable for detecting burned organic matter, by quantifying the dilution of the chlorophyll signal by the charcoal signal. Thus, this adaptation of the I-band index can be applied in fire reconstruction studies.     

Analysis of the experimental compressibility of deep water marine sediments from the Gulf of Guinea

This study strives to analyze the compressibility of deep water marine sediments originating from the Gulf of Guinea. Our approach is multi-scaled and, on the macroscopic level, based on two equations which link the overburden effective stress with the liquidity index, the Biarez & Favre equation on the one hand, and the Burland equation on the other hand (after calculation of the ICL expression as a function of the I_L parameter). On the local level, the evolution of the microstructures is analysed and compared with GoG remoulded clay. Two additional observation techniques have been used, the scanning electron microscope and the mercury intrusion porosimetry.     

U–Pb zircon dating of post-obduction volcanic-arc granitoids and a granulite-facies xenolith from New Caledonia. Inference on Southwest Pacific geodynamic models

In New Caledonia, the occurrence of one of the World’s largest and best-exposed subduction/obduction complex is a key point for the understanding of the geodynamic evolution of the whole Southwest Pacific region. Within the ophiolite, pre-and post-obduction granitoids intrude the ultramafic allochthon and provide new time constraints for the understanding of obduction processes. At 27.4 Ma, a new East-dipping subduction generated the active margin magmatism along the western coast of the island (Saint-Louis massif). At 24.3 Ma, the eastward shift of the magma activity and slightly different geochemical features (Koum-Borindi massif) was either related to the older slab break-off; or alternatively, due to the eastward migration of the mantle wedge following the collision of the eastern margin of the Low Howe rise. Finally, the occurrence of a granulite-facies xenolith in the Koum-Borindi massif with comparable 24.5 Ma U–Pb zircon age and isotopic features (initial ε_Nd = 5.1) suggests that these evolved magmas were generated within the lithospheric mantle beneath a continental crust of normal thickness. Geochronological evidence for continuous convergence during the Oligocene infers an East-dipping Eocene-Oligocene subduction/obduction system to have existed in the Southwest Pacific from the d’Entrecasteaux zone to the North Island of New Zealand.     

A Mössbauer and FTIR study of synthetic amphiboles along the magnesioriebeckite – ferri-clinoholmquistite join

A series of amphiboles along the magnesioriebeckite—Na₂Mg₃Fe³⁺ ₂Si₈O₂₂(OH)₂– ferri-clinoholmquistite—Li₂Mg₃Fe³⁺ ₂Si₈O₂₂(OH)2 - join, defined by the ^BLi^B Na_–1 exchange vector, were hydrothermally synthesized at 700°C, 0.4 GPa, NNO + 1 redox conditions. Powder XRD and SEM-EDAX showed a very high (> 90%) amphibole yield for all samples. X-ray patterns were indexed in the C2/m space group; refined cell-parameters show a linear decrease of a and as a function of chemistry. IR spectra in the OH-stretching region show four main and rather sharp bands; these are assigned to Mg and Fe²⁺ at M(1,3), and indicate that the obtained amphiboles depart from the nominal octahedral composition (^M1,3Mg₃). The IR spectra also show that there is an increasing filling-up of the A-site for increasing Na in the system (increasing solid-solution toward, arfvedsonite). Mössbauer spectra show four well-defined quadrupole doublets which are assigned to Fe³⁺ at M2 and to Fe²⁺ at M1, M3 and M4, respectively. The Fe³⁺/Fe²⁺ content derived from fitted peak areas show variable Fe³⁺ concentration along the series. Mössbauer spectra also show a distinct alteration of ⁵⁷Fe hyperfine parameters with changing Na–Li at M4. The most evident variation is observed for the quadrupole splitting of Fe³⁺ at M2, which increases by 50% from ferri-clinoholmquistite to magnesio-riebeckite; this suggest that the M2 octahedron in ferri-clinoholmquistite is much closer to the ideal geometry than the M2 octahedron in magnesio-riebeckite. Mössbauer spectra show also a well-defined increase in the Fe²⁺ quadrupole splitting of the M1 and M3 octahedra, which is attributed to the Na–Li distribution at the B-sites.     

Influence of the South Atlantic convergence zone and SouthAtlantic Sea surface temperature on interannual summerrainfall variability in Southeastern South America

Summary  In subtropical Argentina, Paraguay and southern Brazil, precipitation is most abundant during summer but its interannual variability is large. At this time a zone of low-level convergence, upper-level divergence, and intense convection is developed to the north of this area. This feature is known as the South Atlantic convergence zone (SACZ) and seems to be related to the interannual variability of summer rainfall to its south. The aim of this work is to document this relationship. Reduced (increased) precipitation in southern Brazil, most of Uruguay and northeastern Argentina is associated with a strong (weak) SACZ and a northward (southward) displacement of it, while increased (reduced) rainfall occurs further south in subtropical Argentina. Also, warm (cold) SST in the region 20° S–40° S and west of 30° W is likely accompanied by a southward (northward) shift of the SACZ. Aside of this relation with the SACZ that affect on the precipitation field of Southeastern South America, the proximate Atlantic Ocean SST seems to force the precipitation over this region by other mechanisms as well. The result of this additional SST forcing is to enhance the signal of the SACZ in northeastern Argentina, Uruguay and southern Brazil and to oppose the SACZ effect in southern subtropical Argentina. Received July 24, 1999 Revised July 5, 2000     

The 2005 eruption of Ilamatepec (Santa Ana) volcano,El Salvador

We report the stratigraphic sequence of the 2005 eruption of Ilamatepec volcano together with sedimentological and chemical analyses of its products.Structural and textural characteristics of the deposits indicate that the eruption was driven by a small-volume rhyolitic intrusion at shallow levels, which resulted first in the collapse of the existing hydrothermally altered fan of previous deposits inside the crater lake, driving phreatic explosions with launching of blocks on ballistic trajectories; later the magma interacted with lake waters producing several hydromagmatic pyroclastic density currents (PDCs). These flows were energetic enough to knock down pine trees up to distances of 1.8 km from the crater in the E-NE sector of the volcano. Finally, ejection of ballistic blocks that landed on previously emplaced, wet pyroclastic density current deposits, caused the generation of a lahar that flowed down the steep eastern flank toward the El Jabillal gully. Subsequent lahars occurred as a result of intense rain caused by hurricane Stan.Radiocarbon ages on paleosols and charcoal fragments, separating previous volcanogenic sequences, indicate that similar eruptions have occurred more frequently in the past centuries, than previously thought.The new data confirms that Ilamatepec volcano is one of the most active volcanoes in El Salvador. Nevertheless, more detailed studies of the eruptive sequence of Ilamatepec volcano are mandatory to establish future eruptive patterns.     

The Multiscale TROPIcal CatchmentS critical zone observatory M-TROPICS dataset III: Hydro-geochemical monitoring of the Mule Hole catchment,south India

Despite the importance of tropical ecosystems for climate regulation, biodiversity, water and nutrient cycles, only a few Critical Zone Observatories (CZOs) are located in the tropics. Among these, most are in humid climates, while very few data exist for semi-arid and sub-humid climates, due to the difficulty of estimating hydro-geochemical balances in catchments with ephemeral streams. We contribute to fill this gap by presenting a meteorological and hydro-geochemical dataset acquired at the Mule Hole catchment (4.1 km²), a pristine dry deciduous forest located in a biosphere reserve in south India. The dataset consists of time series of variables related to (i) meteorology, including rainfall, air temperature, relative humidity, wind speed and direction, and global radiation, (ii) hydrology, including water level and discharge at the catchment outlet, (iii) hydrogeology, including manual (monthly) and/or automated (from 15 min to hourly) groundwater levels in nine piezometers and (iv) geochemistry, including suspended sediment content in the stream and chemical composition of rainfall (event based), groundwater (monthly sampling) and stream water (storm events, 15 min to hourly frequency with an automatic sampler). The time series extend from 2003 to 2019. Measurement errors are minimized by frequent calibration of sensors and quality checks, both in the field and in the laboratory. Despite these precautions, several data gaps exist, due to occasional access restriction to the site and instrument destruction by wildlife. Results show that large seasonal and interannual variations of climatic conditions were reflected in the large variations of stream flow and groundwater recharge, as well as in water chemical composition. Notably, they reveal a long-term evolution of groundwater storage, suggesting hydrogeological cycles on a decadal scale. This dataset, alone or in combination with other data, has already allowed to better understand water and element cycling in tropical dry forests, and the role of forest diversity on biogeochemical cycles. As tropical ecosystems are underrepresented by Critical Zone Observatories, we expect this data note to be valuable for the global scientific community.     

运用生物地理学理论与遥感影像寻找本·拉登

本·拉登到底在哪里？这是我们这个时代最重要的政治问题之一。在这篇文章中,我们依据反映生物分布和灭绝规律的生物地理学理论(距离衰减理论、岛屿生物地理理论、本·拉登个人数据),结合遥感数据(陆地卫星 ETM+、航天雷达地形测图、QuickBird),从全球、区域、局部三个空间尺度分析并最终指出本·拉登当前最可能的所在地。这是第一次运用科学手段来确定本·拉登居所。该方法具有可重复性：一旦美国情报部门提供新的信息,便可通过该方法重新定位本·拉登当前最有可能的藏身场所。