Structure and stability of the former subglacial drainage system of the glacier De Tsanfleuron,Switzerland

A well-developed subglacial drainage system consisting of large cavities developed in the lee of bedrock steps connected together by a network of Nye channels is exposed on an area of recently deglaciated limestone bedrock in front of Glacier de Tsanfleuron, Switzerland. This system covers some 51 per cent of the bedrock surface area, and is believed to have transported the bulk of supraglacially-derived meltwaters through the glacier. Using the cavity hydraulics model of Kamb (1987), it is shown that the geometry of the system rendered it stable against collapse by meltback of channel roofs into a tunnel-dominated system. For likely combinations of glacier geometry and meltwater discharge, the steady state water pressure in this system would have been only a small fraction of that required for flotation, and for discharges of less than about 0·5–5 m³ s^?1 water would have flowed at atmospheric pressure. The system appears to have adjusted to varying discharges by a combination of varying water pressure and changing the total cross-sectional area of flow by altering the number of active channels connecting cavities. Glacier sliding velocity would have been independent of meltwater discharge for discharges at which water flowed at atmospheric pressure, but would have risen with increasing discharge for higher flows. Velocities on the order of 0·1 m d^?1 are predicted for a realistic range of discharges and effective pressures, and these are believed to be plausible. Episodes of enhanced sliding in glaciers with similar drainage systems could be triggered by a rise in meltwater discharge across the threshold between flows at atmospheric pressure and flow under pressure from the glacier.     

Biogeochemical aromatic markers in the sediments from mahakam delta (Indonesia)

Analysis of the tri-, tetraand pentaaromatic hydrocarbon fractions of several sediments (0–600 m) from the Mahakam Delta (Indonesia), indicate the predominance of polycyclic aromatic hydrocarbons (PAH) diagenetically related to triterpenoid natural precursors. High resolution Shpol'skii spectrofluorometry (HRS) proved to be a valuable analytical tool, in conjunction with high performance liquid chromatography (HPLC) and capillary gas chromatography coupled with mass spectrometry (CGC/MS), for the identification of individual components in Chromatographic fractions obtained after a high resolution reverse phase liquid chromatography.     

Organic geochemistry of Recent equatorial deltaic sediments

The organic matter of recent deltaic sediments cored in the Mahakam delta, East Kalimantan, has been studied before and after physical fractionation into sands >50 μm, silts 5–50 μm and clays <5 μm. Both the lipid and non-lipid components have been investigated.Weight, carbon and nitrogen fractionation budgets were used to define three types of samples, depending on coarse particle contributions to the total amount of organic matter: a = a first type with more than 50% of the O.M. in the coarse particles, high C/N ratios and O.M. content, b = an intermediary type with medium C/N ratios and O.M. content, each fraction having quite the same O.M. content, c = a third type with less than 5% of the whole O.M. in the sands and the lowest C/N ratios and O.M. content.Concerning the global organic characteristics of the fractions, a systematic increase of C/N ratios occurs when going from clays to sands; the finer the fraction is, the more nitrogenous the compounds are. This enrichment in nitrogen is related to a persistent high rate of hydrolysable material either for argillaceous organic matter-poor sediments or for the clay fractions of all types of samples. Conversely, the type (a) coarse sediments, in particular the sandy components were resistant to acid hydrolysis with burial.Concerning the geochemical markers signatures of granulometric fractions, the distribution patterns of n-alkanes and n-fatty acids are characterized by the predominance of high molecular weight compounds >C₂₂. Carbon preference index (CPI) values are higher in the sands and silts, reflecting their enrichment in continentally-derived vegetation debris. For type (c), the fractionation revealed markers of microbial activity within the clay fractions. For all types of samples, we observed an increase with burial of the n-alkane and n-fatty acid concentrations, particularly in the clay fractions, suggesting possibly a better preservation and/or affinity of lipids with the finest fractions.     

Oblique and near collision subduction, Sagami and Suruga Troughs —preliminary results of the French-Japanese 1984 Kaiko cruise, Leg 2

Leg 2 of the French-Japanese 1984 Kaiko cruise has surveyed the Suruga and the Sagami Troughs, which lie on both sides of the northwestward moving and colliding Izu-Bonin Ridge, the northernmost part of the Philippine Sea plate. The transition from the Nankai Trough to the Suruga Trough is characterized by northward decrease in width of the accretionary prism, in good agreement with the increasing obliquity between the through axis and the direction of the convergence, as the strike of the convergent boundary changes from ENE-NNE to south-north. South of the area, the southern margin of the Zenisu Ridge shows contractional deformations. This supports the interpretation made by the team of Leg 1 who studied the western extension of the area we studied, that it is an intra-oceanic thrusting of the ridge over the Shikoku Basin. In the Sagami Trough, where the relative motion is highly oblique to the plate boundary, active subduction is mostly confined in the east-west trending portions of the trough located south of the Boso Peninsula and along the lower Boso Canyon, near the TTT triple junction. In between, the present motion is mainly right-lateral along the northwest trending Boso escarpment. However, an inactive but recent (Pliocene to lower Pleistocene) accretionary prism exists south of the Boso escarpment, which suggests that the relative motion was more northerly than at present before about 1 Ma ago.     

Première datation UPb des orthogneiss œillés de la zone axiale de la Montagne noire (Sud du Massif central) : nouveaux témoins du magmatisme ordovicien dans la chaı̂ne Varisque

We present new U–Pb results on felsic Augen orthogneisses from the Axial Zone of the Montagne Noire (French Massif Central). The data indicate Ordovician ages, 456±3 and 450±6 Ma for two samples collected at ‘Pont-de-Larn’ and ‘Gorges d'Héric’, respectively. These ages are interpreted as the igneous emplacement age of the granitic protolith. To cite this article: F. Roger et al., C. R. Geoscience 336 (2004).     

Experimental study of arsenic speciation in vapor phase to 500°C: implications for As transport and fractionation in low-density crustal fluids and volcanic gases

The stoichiometry and stability of arsenic gaseous complexes were determined in the system As-H₂O ± NaCl ± HCl ± H₂S at temperatures up to 500°C and pressures up to 600 bar, from both measurements of As^(III) and As^(V) vapor-liquid and vapor-solid partitioning, and X-ray absorption fine structure (XAFS) spectroscopic study of As^(III)-bearing aqueous fluids. Vapor-aqueous solution partitioning for As^(III) was measured from 250 to 450°C at the saturated vapor pressure of the system (P_sat) with a special titanium reactor that allows in situ sampling of the vapor phase. The values of partition coefficients for arsenious acid (H₃AsO₃) between an aqueous solution (pure H₂O) and its saturated vapor (K = mAs_vapor /mAs_liquid) were found to be independent of As^(III) solution concentrations (up to ∼1 to 2 mol As/kg) and equal to 0.012 ± 0.003, 0.063 ± 0.023, and 0.145 ± 0.020 at 250, 300, and 350°C, respectively. These results are interpreted by the formation, in the vapor phase, of As(OH)₃(gas), similar to the aqueous As hydroxide complex dominant in the liquid phase. Arsenic chloride or sulfide gaseous complexes were found to be negligible in the presence of HCl or H₂S (up to ∼0.5 mol/kg of vapor). XAFS spectroscopic measurements carried out on As^(III)-H₂O (±NaCl) solutions up to 500°C demonstrate that the As(OH)₃ complex dominates As speciation both in dense H₂O-NaCl fluids and low-density supercritical vapor. Vapor-liquid partition coefficients for As^(III) measured in the H₂O-NaCl system up to 450°C are consistent with the As speciation derived from these spectroscopic measurements and can be described by a simple relationship as a function of the vapor-to-liquid density ratio and temperature. Arsenic^(III) partitioning between vapor and As-concentrated solutions (>2 mol As/kg) or As₂O₃ solid is consistent with the formation, in the vapor phase, of both As₄O₆ and As(OH)₃. Arsenic^(V) (arsenic acid, H₃AsO₄) vapor-liquid partitioning at 350°C for dilute aqueous solution was interpreted by the formation of AsO(OH)₃ in the vapor phase.The results obtained were combined with the corresponding properties for the aqueous As(III) hydroxide species to generate As(OH)₃(gas) thermodynamic parameters. Equilibrium calculations carried out by using these data indicate that As(OH)₃(gas) is by far the most dominant As complex in both volcanic gases and boiling hydrothermal systems. This species is likely to be responsible for the preferential partition of arsenic into the vapor phase as observed in fluid inclusions from high-temperature (400 to 700°C) Au-Cu (-Sn, -W) magmatic-hydrothermal ore deposits. The results of this study imply that hydrolysis and hydration could be also important for other metals and metalloids in the H₂O-vapor phase. These processes should be taken into account to accurately model element fractionation and chemical equilibria during magma degassing and fluid boiling.     

High Precision Hf-W Isotopic Measurements in Meteoritic Material Using Negative Thermal Ionisation Mass Spectrometry (NTIMS)

This paper presents a two-stage anion-exchange procedure for tungsten extraction, an improved mass spectrometric procedure for tungsten analysis and a simplified chemical separation and TIMS procedure for the determination of Hf concentrations. The chemical separation of tungsten is based on its complexing properties with HF and H₂O₂. The blank level for a sample size of 300 mg is about 80 pg for tungsten. The procedure is designed for the high sensitivity of negative thermal ionisation mass spectrometry (NTIMS) provided by the use of Mg oxide as an emitter on Ir filaments. Tungsten can be readily measured with a high precision in various meteoritical material and especially in small W-poor silicate fractions. Samples containing as little as a few ng g^-1 tungsten can be analysed reliably with this method.     

Geodynamic significance of the Raspas Metamorphic Complex (SW Ecuador): geochemical and isotopic constraints

The Raspas Metamorphic Complex of southwestern Ecuador is regarded as the southernmost remnant of oceanic and continental terranes accreted in the latest Jurassic–Early Cretaceous. It consists of variably metamorphosed rock types. (1) Mafic and ultramafic rocks metamorphosed under high-pressure (HP) conditions (eclogite facies) show oceanic plateau affinities with flat REE chondrite-normalized patterns, Nd_{150 Ma} ranging from +4.6 to 9.8 and initial Pb isotopic ratios intermediate between MORB and OIB. (2) Sedimentary rocks metamorphosed under eclogitic conditions exhibit LREE enriched patterns, strong negative Eu anomalies, Rb, Nb, U, Th, Pb enrichments, low Nd_{150 Ma} values (from −6.4 to −9.5), and high initial ⁸⁷Sr/⁸⁶Sr and ^206,207,208Pb/²⁰⁴Pb isotopic ratios suggesting they were originally sediments derived from the erosion of an old continental crust. (3) Epidote-bearing amphibolites show N-MORB affinities with LREE depleted patterns, LILE, Zr, Hf and Th depletion, high Nd_{150 Ma} (>+10) and low initial Pb isotopic ratios.The present-day well defined internal structure of the Raspas Metamorphic Complex seems to be inconsistent with the formerly proposed interpretation of a “tectonic mélange”. The association of oceanic plateau rocks and continent-derived sediments both metamorphosed in HP conditions suggests that the thin edge of the oceanic plateau first entered the subduction zone and dragged sediments downward of the accretionary wedge along the Wadatti–Benioff zone. Subsequently, when its thickest part arrived into the subduction zone, the oceanic plateau jammed the subduction processes, due to its high buoyancy.In Ecuador and Colombia, the latest Jurassic–Early Cretaceous suture involves HP oceanic plateau rocks and N-MORB rocks metamorphosed under lower grades, suggesting a composite or polyphase nature for the latest Jurassic–Early Cretaceous accretionary event.     

Simulation des changements climatiques au cours du XXIe siècle incluant l'ozone stratosphériqueSimulation of climate changes during the 21st century including stratospheric ozone

Two climate simulations of 150 years, performed with a coupled ocean/sea-ice/atmosphere model including stratospheric ozone, respectively with and without heterogeneous chemistry, simulate the tropospheric warming associated with an increase of the greenhouse effect of carbon dioxide and other trace gases since 1950 and their impact on sea–ice extent, as well as the stratospheric cooling and its impact on ozone concentration. The scenario with heterogeneous chemistry reproduces the formation of the ozone hole over the South Pole from the 1970s and its deepening until the present time, and shows that the ozone hole should progressively fill during the coming decades. To cite this article: J.-F. Royer et al., C. R. Geoscience 334 (2002) 147–154.     

“A Salute to the Bandido”: A Political Ecology of Voice Exploration into Peru’s Freedom of Voice Surrounding Hydrocarbon Development

This paper sets out to evaluate the freedom of voice for Peruvian stakeholders affected by hydrocarbon development. This occurs through the utilization of a political ecology of voice (PEV) theoretical framework based upon the theory of voice by Albert Hirschman and political ecology. PEV can be defined as the study of economic, political, social, and geographical factors over a specific time period and their impact upon the use of voice by stakeholders. Peru’s case study was focused on its main oil-producing Loreto Region and incorporated evaluation of hydrocarbon voice mechanisms (prior consultation and environmental impact assessments) supported by interview testimony of stakeholders and state officials. PEV analysis reveals a political environment which is dangerous, inflexible, and intolerant of Peruvian stakeholders voicing over hydrocarbon development. This is due to the state’s zealous pursuit of its “selva (rainforest) hydrocarbon and development vision” which severely undermines Peruvian stakeholder’s freedom of voice.