Parent stars of extrasolar planets – VIII. Chemical abundances for 18 elements in 31 stars

We present the results of detailed spectroscopic abundance analyses for 18 elements in 31 nearby stars with planets (SWPs). The resulting abundances are combined with other similar studies of nearby SWPs and compared to a sample of nearby stars without detected planets. We find some evidence for abundance differences between these two samples for Al, Si and Ti. Some of our results are in conflict with a recent study of SWPs in the SPOCS data base. We encourage continued study of the abundance patterns of SWPs to resolve these discrepancies.     

Practical versus absolute salinity measurements: New advances in high performance seawater salinity sensors

Optical salinity sensors described here measure directly the seawater refractive index and thus enable a measurement of the seawater density and composition variation. We detail the measurement dependence to environmental parameters (in particular temperature and pressure) compared to conductivity sensors, and demonstrate that it may be advantageous to directly measure refractive index rather than electrical conductivity and so obtain a more direct route to density and absolute salinity.     

Assessment of trace metals in droppings of Adélie penguins (Pygoscelis adeliae) from different locations of the Antarctic Peninsula area

In recent decades, polar regions of the planet have witnessed an increase in human presence. Antarctica is considered one of the most pristine regions of the world, but it could be affected by pollutio...     

Antimony speciation in saline hydrothermal fluids: A combined X-ray absorption fine structure spectroscopy and solubility study

Solubility of senarmontite (Sb₂O₃, cubic) in pure water and NaCl-HCl aqueous solutions, and local atomic structure around antimony in these fluids were characterized using in situ X-ray absorption fine structure (XAFS) spectroscopy at temperatures to 450 °C and pressures to 600 bars. These experiments were performed using a new X-ray cell which allows simultaneous measurement of the absolute concentration of the absorbing element in the fluid, and atomic environment around the absorber. Results show that aqueous Sb(III) speciation is dominated by the complex in pure water, mixed Sb-hydroxide-chloride complexes in acidic NaCl-HCl solutions (2 m NaCl-0.1 m HCl), and by Sb-chloride species in concentrated HCl solutions (3.5 m HCl). Interatomic Sb-O and Sb-Cl distances in these complexes range from 1.96 to 1.97 Å and from 2.37 to 2.47 Å, respectively. These structural data, together with senarmontite solubility determined from XAFS spectra, were complemented by batch-reactor measurements of senarmontite and stibnite (Sb₂S₃, rhombic) solubilities over a wide range of HCl and NaCl concentrations from 300 to 400 °C. Analysis of the whole dataset shows that Sb(III) speciation in high-temperature moderately acid (pH > 2-3) Cl-rich fluids is dominated by mixed hydroxy-chloride species like Sb(OH)₂Cl° and Sb(OH)₃Cl⁻, but other species containing two or three Cl atoms appear at higher acidities and moderate temperatures (?300 °C). Calculations using stability constants retrieved in this study indicate that mixed hydroxy-chloride complexes control antimony transport in saline high-temperature ore fluids at acidic conditions. Such species allow for a more effective Sb partitioning into the vapor phase during boiling and vapor-brine separation processes occurring in magmatic-hydrothermal systems. Antimony hydroxy-chloride complexes are however minor in the neutral low- to moderate-temperature solutions (?250-300 °C) typical of Sb deposits formation; the antimony speciation in these systems is dominated by Sb(OH)₃ and potentially Sb-sulfide species.     

Bioaccumulation of heavy metals and radionuclides from seawater by encased embryos of the spotted dogfish Scyliorhinus canicula

Encased embryos of spotted dogfish Scyliorhinus canicula absorbed six radio-isotopes (241Am, 109Cd, 57Co, 134Cs, 54Mn and 65Zn) directly from seawater during short-term experimental exposure, demonstrating the permeability of the egg-case to these contaminants. Embryo to water concentration factors (CFs) ranged from 0.14 for 134Cs to 7.4 for 65Zn. The 65Zn and 57Co CFs increased exponentially with embryo length, whereas the CF for 109Cd declined with length. Among different components of the encased embryo the egg case was the major repository (69-99%) of all six radio-isotopes that were distributed throughout its wall. Egg-case CFs were as high as 10(3) for 57Co and 65Zn, making it the major source of gamma radiation exposure to the embryo and potentially of radio-isotopes for continued absorption by the embryo, following the uptake phase of the experiment. The patterns of uptake by the egg-case approximated linearity for most isotopes and loss rates were isotope-specific; egg-case biokinetics were not greatly affected by the viability of the contained embryo. Within the embryo initial data on radio isotopic distribution show that the skin is their major site of uptake, as previously demonstrated for juveniles.     

High-precision CTE measurement of aluminum-alloys for cryogenic astronomical instrumentation

We are completing the construction of GIANO, a high resolution near-infrared cryogenic spectrograph for the Telescopio Nazionale Galileo (TNG). Most of the optics are made of aluminium and operate at cryogenic temperature. We evaluated the optical degradation due to mis-matches between the thermal expansion coefficients of the different aluminium parts of the instrument. We performed accurate measurements of the relative thermal expansion coefficients (CTE) of Al-6061 and Al-6082 over the 300–77 K temperatures range. We find that the two alloys have identical thermal expansion coefficient within a maximum (3σ) uncertainty of Δα/α?<?0.28%. Our results show that it is possible to overcome the problem of the alignment of a cryogenic instrument, manufacturing the curved optics, the optics’ holders and the optical bench with different metallic alloys with small CTE mismatch (Al-6061 and Al-6082). This conclusion has also been confirmed by the results of the optical tests with the instrument cooled in the laboratory, showing no significant image quality degradation.     

Evolution of density perturbations in double exponential quintessence models

In this work we investigate the evolution of matter (linear) density perturbations for quintessence models with a self-interaction potential that is a combination of exponentials. One of the models is based on the Einstein theory of gravity, while the other is based on the Brans-Dicke scalar tensor theory. We constrained the parameter space of the models by using the determinations of the growth rate of perturbations derived from data of the 2-degree Field Galaxy Redshift Survey.      

Glaciovolcanic landsystems and large-scale glaciotectonic deformation along the Brekknafjöll–Jarlhettur,Iceland

This paper documents the glaciovolcanic landsystem of the Brekknafjöll–Jarlhettur ridge in Central Iceland. Glaciolacustrine diamict is found beneath, and in association with, a complex assemblage of pillow lava, lava breccias and hyaloclastites. Three depositional environments are identified: glaciolacustrine fan, pillow lava dome, and hyaloclastite fan. These subaqueous environments occurred both simultaneously and at different times along the volcanic fissures which underlie the ridge and have given rise to a complex facies architecture. This facies architecture provides evidence that the ridge evolved in a time transgressive fashion during several episodes of volcanism, some of which may have been punctuated by periods of ice erosion. Associated with the ridge are large-diapiric folds in diamict and gravel which form by the loading and lateral displacement of saturated diamict beneath the developing volcanic pile. A depositional model is presented which emphasises the glaciolacustrine component and the time transgressive nature of the glaciovolcanic landsystem. Much of the eruption occurred in subglacial to englacial lakes or vaults, which were probably linked by water and sediment exchange. The initial subglacial vaults appear to have extended beyond the fissure limits and were infilled by glaciolacustrine diamicts, subaqueous outwash and the eruption of pillow lava. This was followed by the eruption of hyaloclastite sand and breccia forming an elongated fan.     

The density of North Atlantic and North Pacific deep waters

The densities of seventeen samples of seawater from GEOSECS stations 27 (North Atlantic) and 217 (North Pacific) have been measured with a vibrating flow densimeter at 25°C. The densities of the deep samples were found to be 5 ± 1.5and16 ± 3.6ppm greater, for the North Atlantic and North Pacific, respectively, than predicted by the equation of state of Millero, Gonzalez and Ward (1976) derived for seawaters of constant relative composition. The results are in good agreement with the density anomalies predicted by Brewer and Bradshaw (1975) on the basis of the observed increase of dissolved silica, alkalinity and total carbon dioxide in oceanic deep waters. The application of these corrections results in an agreement with the Millero, Gonzalez and Ward (1976) equation of state to ±4 ppm.     

Structural control of the distribution of trace elements between silicates and hydrothermal solutions

Over several years many partition coefficients have been measured between framework silicates, sheet silicates and hydrothermal solutions. Only trace alkaline cations are considered in the present work. It is well known that the difference between ionic radii of the trace cation and the major cation is replaces is not satisfactory for a good correlation with the partition coefficients P_X. A structural parameter δ_c is therefore defined, taking into consideration the adaptation of the trace cation to the cavity in which it occurs. This cavity may be the entire site of the major element, or a part of this site in the case of small cations, or a structural cavity located out of the alkali-ion site. The adaptation parameter δ_c is the difference between the ionic radius of the trace cation and the radius of that cavity. This paper shows that the partition coefficient P_X of the trace alkali-ion from the hydrothermal solution is an exponential function of the adaptation parameter δ_c, whatever the silicate may be.