Chronology of Upper Pleistocene sequences at Sidi Messaoud (wadi Noun, southwestern Morocco) based on C, optical and U-series dating

The Sidi Messaoud site provides a 40 m thick sedimentary infilling of great importance for the study of environmental changes and landscape evolution during the Upper Pleistocene in the Western Sahara. In this study, chronological results obtained by the ¹⁴C, U-series and optical dating techniques are compared. Each individual age, depositional environment and post-deposition history of the various samples are evaluated, in order to explain the methodological reasons for discordances and concordances. Stratigraphic and palaeoenvironmental implications for the last 120 ka history in southwestern Morocco are also inferred: the wadi Noun gorges had been incised before MIS 5, and later, during MIS 3, the valley has been filled in with a mean sedimentation rate of 1 m/ka.     

Deep-seated failure propagation in a fractured rock slope over 10,000 years: The La Clapière slope, the south-eastern French Alps

The “La Clapière” area (Tinée valley, Alpes Maritimes, France) is a typical large, complex, unstable rock slope affected by Deep Seated Gravitational Slope Deformations (DGSD) with tension cracks, scarps, and a 60 × 10⁶ m³ rock slide at the slope foot that is currently active. The slope surface displacements since 10 ka were estimated from ¹⁰Be ages of slope gravitational features and from morpho-structural analyses. It appears that tensile cracks with a strike perpendicular to the main orientation of the slope were first triggered by the gravitational reactivation of pre-existing tectonic faults in the slope. A progressive shearing of the cracks then occurred until the failure of a large rock mass at the foot of the slope. By comparing apertures, variations and changes in direction between cracks of different ages, three phases of slope surface displacement were identified: 1) an initial slow slope deformation, spreading from the foot to the top, characterized by an average displacement rate of 4 mm yr^− 1, from 10–5.6 ka BP; 2) an increase in the average displacement rate from 13 to 30 mm yr^− 1 from the foot to the middle of the slope, until 3.6 ka BP; and 3) development of a large failure at the foot of the slope with fast displacement rates exceeding 80 mm yr^− 1 for the last 50 years. The main finding of this study is that such a large fractured slope destabilization had a very slow displacement rate for thousands of years but was followed by a recent acceleration. The results obtained agree with several previous studies, indicating that in-situ monitoring of creep of a fractured rock slope may be useful for predicting the time and place of a rapid failure.     

H I observations of galaxies behind the Milky Way in the Puppis region

We report 21-cm H  i line observations of 161 galaxies located behind the Milky Way, in the Puppis region. The observations have been carried out with the Nançay radio telescope, resulting in 101 detections. Most of the galaxies observed appear in the ESO catalogue, and present apparent diameters larger than 1.6 arcmin. We show that the detection rate is strongly related to the apparent diameter; it is as high as 76 per cent for diameters larger than 1.6 arcmin. Half of the non-detections result, in fact, from an insufficient velocity coverage. Global parameters of the detected galaxies are computed, after a careful discussion of the correction for Galactic absorption. Our H  I data are then compared with those obtained by Kraan-Korteweg & Huchtmeier with the Effelsberg radio telescope for 20 galaxies observed in common: the agreement is excellent, implying respective uncertainties on recession velocities and on H  I fluxes lower than 10 km s⁻¹ and 2 Jy km s⁻¹ on average. Finally, we find that the detected galaxies follow well the correlation between the optical linear diameter and the H  I mass found by Haynes & Giovanelli. This result shows that our diameter corrections for Galactic absorption A_B are quite good, except for eight objects which are heavily obscured ( A_B 2.3), or have a very small diameter, lower than 0.5 arcmin.     

Causes and impacts of changes in the Arctic freshwater budget during the twentieth and twenty-first centuries in an AOGCM

The fourth version of the atmosphere-ocean general circulation (AOGCM) model developed at the Institut Pierre-Simon Laplace (IPSL-CM4) is used to investigate the mechanisms influencing the Arctic freshwater balance in response to anthropogenic greenhouse gas forcing. The freshwater influence on the interannual variability of deep winter oceanic convection in the Nordic Seas is also studied on the basis of correlation and regression analyses of detrended variables. The model shows that the Fram Strait outflow, which is an important source of freshwater for the northern North Atlantic, experiences a rapid and strong transition from a weak state toward a relatively strong state during 1990–2010. The authors propose that this climate shift is triggered by the retreat of sea ice in the Barents Sea during the late twentieth century. This sea ice reduction initiates a positive feedback in the atmosphere-sea ice-ocean system that alters both the atmospheric and oceanic circulations in the Greenland-Iceland-Norwegian (GIN)-Barents Seas sector. Around year 2080, the model predicts a second transition threshold beyond which the Fram Strait outflow is restored toward its original weak value. The long-term freshening of the GIN Seas is invoked to explain this rapid transition. It is further found that the mechanism of interannual changes in deep mixing differ fundamentally between the twentieth and twenty-first centuries. This difference is caused by the dominant influence of freshwater over the twenty-first century. In the GIN Seas, the interannual changes in the liquid freshwater export out of the Arctic Ocean through Fram Strait combined with the interannual changes in the liquid freshwater import from the North Atlantic are shown to have a major influence in driving the interannual variability of the deep convection during the twenty-first century. South of Iceland, the other region of deep water renewal in the model, changes in freshwater import from the North Atlantic constitute the dominant forcing of deep convection on interannual time scales over the twenty-first century.     

Plankton origin of particulate dimethylsulfoniopropionate in a Mediterranean oligotrophic coastal and shallow ecosystem

We report here dimethylsulfide (DMS) and dimethylsulfoniopropionate (DMSP) levels as a function of plankton communities and abiotic factors over a 12-month cycle in the Mediterranean oligotrophic coastal and shallow ecosystem of Niel Bay (N.W. Mediterranean Sea, France). Total particulate DMSP (DMSP_p) and DMS concentrations were highly seasonal, peaking during a spring (April) bloom at 8.9 nM and 73.9 nM, respectively. Significant positive correlations were found between total DMSP_p concentration and the abundance or biomass of the dinoflagellate Prorocentrum compressum (Spearman's rank correlation test: r = 0.704; p = 0.011). Similarly, DMS concentrations peaked during the development of blooms of P. compressum and Gymnodinium sp. There seemed to be a positive relationship between the chlorophyll a to pheopigment ratio and DMS concentrations, suggesting that DMS was released during phytoplankton growth. High DMS levels recorded in the shallow Niel Bay may also result from the activity of benthic macroalgae, and/or macrophytes such as Posidonia spp., or the resuspension of sulfur species accumulating in sediments. The fractionation of particulate DMSP into three size classes (>90 μm, 5–90 μm and 0.2–5 μm) revealed that 5–90 μm DMSP-containing particles made the greatest contribution to the total DMSP_p pool (annual mean contribution = 62%), with a maximal contribution in April (96%). This size class consisted mainly of dinoflagellates (annual mean contribution = 68%), with P. compressum and Gymnodinium sp. the predominant species, together accounting for up to 44% of the phytoplankton present. The positive correlation between DMSP concentration in the 5–90 μm size class and the abundance of P. compressum (Spearman's rank correlation test: r = 0.648; p = 0.023) suggests that this phytoplankton species would be the major DMSP producer in Niel Bay. The DMSP collected in the >90 μm fraction was principally associated with zooplankton organisms, dominated by copepods (nauplii and copepodites). DMSP_>90, not due to a specific zooplankton production, resulted from the phytoplankton cells ingested during grazing. The concomitant peaks of DMS concentration and zooplankton abundance suggest that zooplankton may play a role in releasing DMSP and/or DMS through sloppy feeding.     

Seasonal dynamics of trophic relationships among co-occurring suspension-feeders in two shellfish culture dominated ecosystems

The temporal dynamics of carbon and nitrogen isotope values of co-occurring suspension-feeders in two shellfish culture areas (Normandy, France) were investigated over two years to evaluate the inter-specific trophic partitioning and relative contributions of organic matter sources to benthic suspension-feeders' diet. Oysters (Crassostrea gigas), mussels (Mytilus edulis), cockles (Cerastoderma edule), slipper limpets (Crepidula fornicata), and sand-mason worms (Lanice conchilega) were sampled in an estuarine environment (Baie des Veys, east Cotentin, Normandy), while oysters, mussels, slipper limpets, and honeycomb worms (Sabellaria alveolata) were sampled in an open-marine environment (Lingreville-sur-mer, west Cotentin, Normandy). Whatever the sampling period, the bivalves, C. gigas and M. edulis, exhibited the lowest values of δ¹³C and δ¹⁵N compared with the other species. Feeding relationships among suspension-feeders in both C. gigas culture areas exhibited temporal variations due to the marine/estuarine influence and seasonal changes in food supply. In the open-marine ecosystem, the contribution of phytoplankton remained the most important for all species except S. alveolata, while in the estuarine ecosystem, microphytobenthos and/or macroalgae detritus contributed a larger extent to the organisms' diets. During phytoplankton bloom periods (e.g. May and July) suspension-feeders, except for S. alveolata, relied strongly on phytoplankton; however, the majority of suspension-feeders exhibited different opportunistic behaviour in winter when phytoplankton biomass might be a limiting factor. We hypothesized that differences in particle capture and selection by the suspension-feeders influenced their isotopic values. Feeding ecology of suspension-feeders partly explained why competition was limited and why ecosystems can often support unexpectedly large numbers of suspension-feeders. We also showed that understanding ecosystem characteristics of the organic matter sources is of primary importance to determine the extent to which members of the suspension-feeding guild potentially compete for food.     

Thermo-mechanical behavior of energy piles in high plasticity clays

Energy piles make use of constant and moderate ground temperature for efficient thermal control of buildings. However, this use introduces new engineering challenges because the changes of temperature in the foundation pile and ground induce additional deformations and forces in the foundation element and coupled thermo-hydro-mechanical phenomena in the soil. Several published full-scale tests investigated this aspect of energy piles and showed thermally induced deformation and forces in the foundation element. In parallel, significant progress has been made in the understanding of thermal properties of soils and on the effect of cyclic thermal load on ground and foundation behavior. However, the effect of temperature on the creep rate of energy piles has received practically no attention in the past. This paper reports the experimental results of an in situ tension thermo-mechanical test on an energy pile performed in a very stiff high plasticity clay. During the in situ test, the pile was subjected to thermal loading by circulating hot water in fitted pipes, simulating a thermal load in a cooling-dominated climate, at different levels of mechanical loading. The axial strain and temperature in the pile, and the load–displacement of the pile were monitored during the tension test at different locations along the center of the pile and at the pile head, respectively. The data showed that as the temperature increases, the observed creep rate of the energy pile in this high plasticity clay also increases, which will lead to additional time-dependent displacement of the foundation over the life time of the structure. It was also found that the use of geothermal piles causes practically insignificant thermally induced deformation and loads in the pile itself.     

Lithospheric mantle beneath the south-eastern Siberian craton: petrology of peridotite xenoliths in basalts from the Tokinsky Stanovik

We provide petrographic, major and trace element data for over 30 spinel peridotite xenoliths from the Tokinsky Stanovik (Tok) volcanic field on the Aldan shield to characterize the lithospheric mantle beneath the south-eastern margin of the Siberian craton, which formed in the Mesoproterozoic. High equilibration temperatures (870–1,010°C) of the xenoliths and the absence of garnet-bearing peridotites indicate a much thinner lithosphere than in the central craton. Most common among the xenoliths are clinopyroxene-poor lherzolites and harzburgites with Al₂O₃ and CaO contents nearly as low as in refractory xenoliths from kimberlite pipes (Mir, Udachnaya) in the central and northern Siberian craton. By contrast, the Tok peridotites have higher FeO, lower Mg-numbers and lower modal orthopyroxene and are apparently formed by shallow partial melting (3 GPa). Nearly all Tok xenoliths yield petrographic and chemical evidence for metasomatism: accessory phlogopite, amphibole, phosphates, feldspar and Ti-rich oxides, very high Na₂O (2–3.1%) in clinopyroxene, LREE enrichments in whole-rocks.Electronic Supplementary Material Supplementary material is available for this article at     

Chemical weathering in the drainage basin of a tropical watershed (Nsimi-Zoetele site, Cameroon) : comparison between organic-poor and organic-rich waters

This study deals with the weathering processes operating at the scale of a small catchment (Nsimi-Zoetele, Cameroon) and is focused on the role of organic colloids on mineral weathering and transport of elements in natural waters. Samples of river, spring and groundwaters from Nsimi-Zoetele were filtered through membranes of decreasing pore size (0.22 μm, 0.025 μm, or: 300,000 Da, 5000 Da) to separate colloidal fractions from the truly dissolved one. Major and trace elements and dissolved organic carbon (DOC) were analysed in each fraction. Two kinds of waters can be distinguished in the catchment: clear and coloured waters. Clear waters exhibit low concentrations of major and trace elements and DOC. Elements are carried in these solutions in a true dissolved form except Al and rare earth elements (REEs). By contrast, the higher abundances of Al, Fe and trace elements in coloured waters are controlled by the colloidal fraction. Thermodynamic equilibrium calculations show that clear waters are in equilibrium with kaolinite and iron oxi-hydroxide which are major minerals in the weathered soil. For coloured waters, the aqueous speciation of Ca, Mg, Cu, Fe, Al, La and Th was calculated taking into account the complexes with humic acids. Speciation calculations for Cu, Fe, Al, La, Th show a strong complexation with humic acids, in good agreement with the results of the filtration experiments. By contrast, although filtration experiments show a strong control of major cations by organic matter (for example 75% for Ca), speciation calculations reveal that their complexes with humic ligands do not exceed a few percent of total dissolved elements. This discrepancy is explained as an artefact induced by the organic colloids and occurring during the filtration procedure. Finally, both filtration experiments and speciation calculations show that organic matter plays an important role in natural DOC-rich waters. Organic acids increase significantly the dissolution rates of silicates and oxi-hydroxides and thus the amounts of solutes and of complexed elements leaving the catchment.