Premières datations de feux holocènes dans les Monts de Saint-Guilhem-le-Désert (Hérault,France), contribution à l'histoire de la forêt relique de Pinus nigra Arnold ssp Salzmanni (Dun.) Franco

The charcoal discovery in the soils and sediments of the relic forest of Pinus nigra ssp Salzmanni near Saint-Guilhem-le-Désert allows us to establish a chronology of Holocene fires. Their origin dates from the Middle Holocene, but they are especially significant after the construction of the medieval abbey during the 9th century. The original pine plantation was heterogeneous, with another pine, Pinus sylvestris, which has now been eradicated. Changes in the fire modes have been observed, recent human fires being generalized, which resulted in a significant regression of the forest cover, which was replaced by box-tree formations. To cite this article: J.-L. Vernet et al., C. R. Geoscience 337 (2005).     

Chemical weathering in the drainage basin of a tropical watershed (Nsimi-Zoetele site, Cameroon) : comparison between organic-poor and organic-rich waters

This study deals with the weathering processes operating at the scale of a small catchment (Nsimi-Zoetele, Cameroon) and is focused on the role of organic colloids on mineral weathering and transport of elements in natural waters. Samples of river, spring and groundwaters from Nsimi-Zoetele were filtered through membranes of decreasing pore size (0.22 μm, 0.025 μm, or: 300,000 Da, 5000 Da) to separate colloidal fractions from the truly dissolved one. Major and trace elements and dissolved organic carbon (DOC) were analysed in each fraction. Two kinds of waters can be distinguished in the catchment: clear and coloured waters. Clear waters exhibit low concentrations of major and trace elements and DOC. Elements are carried in these solutions in a true dissolved form except Al and rare earth elements (REEs). By contrast, the higher abundances of Al, Fe and trace elements in coloured waters are controlled by the colloidal fraction. Thermodynamic equilibrium calculations show that clear waters are in equilibrium with kaolinite and iron oxi-hydroxide which are major minerals in the weathered soil. For coloured waters, the aqueous speciation of Ca, Mg, Cu, Fe, Al, La and Th was calculated taking into account the complexes with humic acids. Speciation calculations for Cu, Fe, Al, La, Th show a strong complexation with humic acids, in good agreement with the results of the filtration experiments. By contrast, although filtration experiments show a strong control of major cations by organic matter (for example 75% for Ca), speciation calculations reveal that their complexes with humic ligands do not exceed a few percent of total dissolved elements. This discrepancy is explained as an artefact induced by the organic colloids and occurring during the filtration procedure. Finally, both filtration experiments and speciation calculations show that organic matter plays an important role in natural DOC-rich waters. Organic acids increase significantly the dissolution rates of silicates and oxi-hydroxides and thus the amounts of solutes and of complexed elements leaving the catchment.     

Geochemical morphology of the North Mid-Atlantic Ridge, 10°–24°N: Trace element-isotope complementarity

The new data presented here from a 10–24°N segment of the North Mid-Atlantic Ridge show that this segment is the most depleted of the 10–70°N ridge section. They also show the existence of: (1) a geochemical gradient from the 14°N anomaly to 17°10′N; (2) a very depleted mantle source (the lowest Sr isotopic ratios found so far in the North Atlantic); and (3) a geochemical limit located at about 17°10′N without any obvious relation with any structural feature. The 15°20′N fracture zone does not show any relationship with respect to this gradient. The basalts located north of 17°10′N have very homogeneous features, which allow their characteristics to be averaged (i.e., ⁸⁷Sr/⁸⁶Sr= 0.70238 ± 0.00004, (Nb/Zr)_N = 0.28 ± 0.1) and they are defined as normal mid-ocean ridge basalts. The basaltic glasses located south of 17°10′N present a wide spectrum of isotopic compositions and extended rare earth element patterns (from depleted to enriched). Despite this, they have a constant K/Nb of 233 ± 9 (1s_M, n = 18) whereas this ratio is 344 ± 29 north of 17°10′N. These observations illustrate the strong coherence of behaviour between K and Nb (Ta) during the petrogenic processes involved in the generation of these mid-ocean ridge basalts and also their fractionation during previous mantle processes. Possible interpretations of mixing processes are discussed and sources at the ridge segment scale are favoured. However, when looking in detail, local heterogeneities are still common and can even be traced back off-axis to 115 my.

Placed in the context of the North Atlantic Ridge from 10° to 70°N, the Sr isotopic ratios reveal the Azores superstructure (23–50°N), whereas the trace element ratios (La/Sm-Nb/Zr) trace the second-order structures (33–40°N, 42–48°N) superimposed on the superstructure. This study illustrates the complementarity of information given by certain well chosen trace element ratios on the one hand and by isotopic ratios on the other. Since there is evidence of decoupling between isotopic ratios and/or trace element ratios, it introduces the notion of complementary “chemical memory” as recorded by a given type of trace element ratio or a given type of isotopic ratio     

Diagenetic trends of a tertiary low-rank coal series

The Mahakam delta (Kalimantan, Indonesia) coals represent all the evolution stages between freshly-deposited plant/peat material, lignites and bituminous coals. The geochemical techniques used to study this coal series included elemental analysis, extraction of humic compounds, infrared spectroscopy and ¹³C nuclear magnetic resonance of the total coal.The main mechanisms of early maturation in this series are loss of oxygenated compounds, aromatisation and condensation of the organic matter. These changes, which have already been suggested for other coal series and partially reported for sedimentary organic matter, were confirmed and described in more detail for the Mahakam coal series.     

Modelling the Mixing Function to Constrain Coseismic Hydrochemical Effects: An Example from the French Pyrénées

Groundwater coseismic transient anomalies are evidenced and characterized by modelling the mixing function F characteristic of the groundwater dynamics in the Ogeu (western French Pyrénées) seismic context. Investigations of water-rock interactions at Ogeu indicate that these mineral waters from sedimentary environments result from the mixing of deep waters with evaporitic signature with surficial karstic waters. A 3-year hydrochemical monitoring of Ogeu springwater evidences that using arbitrary thresholds constituted by the mean ± 1 or 2σ, as often performed in such studies, is not a suitable approach to characterize transient anomalies. Instead, we have used a mixing function F calculated with chemical elements, which display a conservative behavior not controlled by the precipitation of a mineral phase. F is processed with seismic energy release (E_s) and effective rainfalls (R). Linear impulse responses of F to E_s and R have been calculated. Rapid responses (10 days) to rainwater inputs are evidenced, consisting in the recharge of the shallow karstic reservoir by fresh water. Complex impulse response of F to microseismic activity is also evidenced. It consists in a 2-phase hydrologic signal, with an inflow of saline water in the shallow reservoir with a response delay of 10 days, followed by an inflow of karstic water with a response delay of 70 days, the amount being higher than the saline inflow. Such a process probably results from changes in volumetric strain with subsequent microfracturation transient episodes allowing short inflow of deep salted water in the aquifer. This study demonstrates that groundwater systems in such environments are unstable systems that are highly sensitive to both rainfall inputs and microseismic activity. Impulse responses calculation of F to E_s is shown to be a powerful tool to identify transient anomalies. Similar processing is suggested to be potentially efficient to detect precursors of earthquakes when long time-series (5 years at least) are available in areas with high seismicity.     

Chronology of Upper Pleistocene sequences at Sidi Messaoud (wadi Noun, southwestern Morocco) based on C, optical and U-series dating

The Sidi Messaoud site provides a 40 m thick sedimentary infilling of great importance for the study of environmental changes and landscape evolution during the Upper Pleistocene in the Western Sahara. In this study, chronological results obtained by the ¹⁴C, U-series and optical dating techniques are compared. Each individual age, depositional environment and post-deposition history of the various samples are evaluated, in order to explain the methodological reasons for discordances and concordances. Stratigraphic and palaeoenvironmental implications for the last 120 ka history in southwestern Morocco are also inferred: the wadi Noun gorges had been incised before MIS 5, and later, during MIS 3, the valley has been filled in with a mean sedimentation rate of 1 m/ka.     

Deep-seated failure propagation in a fractured rock slope over 10,000 years: The La Clapière slope, the south-eastern French Alps

The “La Clapière” area (Tinée valley, Alpes Maritimes, France) is a typical large, complex, unstable rock slope affected by Deep Seated Gravitational Slope Deformations (DGSD) with tension cracks, scarps, and a 60 × 10⁶ m³ rock slide at the slope foot that is currently active. The slope surface displacements since 10 ka were estimated from ¹⁰Be ages of slope gravitational features and from morpho-structural analyses. It appears that tensile cracks with a strike perpendicular to the main orientation of the slope were first triggered by the gravitational reactivation of pre-existing tectonic faults in the slope. A progressive shearing of the cracks then occurred until the failure of a large rock mass at the foot of the slope. By comparing apertures, variations and changes in direction between cracks of different ages, three phases of slope surface displacement were identified: 1) an initial slow slope deformation, spreading from the foot to the top, characterized by an average displacement rate of 4 mm yr^− 1, from 10–5.6 ka BP; 2) an increase in the average displacement rate from 13 to 30 mm yr^− 1 from the foot to the middle of the slope, until 3.6 ka BP; and 3) development of a large failure at the foot of the slope with fast displacement rates exceeding 80 mm yr^− 1 for the last 50 years. The main finding of this study is that such a large fractured slope destabilization had a very slow displacement rate for thousands of years but was followed by a recent acceleration. The results obtained agree with several previous studies, indicating that in-situ monitoring of creep of a fractured rock slope may be useful for predicting the time and place of a rapid failure.     

H I observations of galaxies behind the Milky Way in the Puppis region

We report 21-cm H  i line observations of 161 galaxies located behind the Milky Way, in the Puppis region. The observations have been carried out with the Nançay radio telescope, resulting in 101 detections. Most of the galaxies observed appear in the ESO catalogue, and present apparent diameters larger than 1.6 arcmin. We show that the detection rate is strongly related to the apparent diameter; it is as high as 76 per cent for diameters larger than 1.6 arcmin. Half of the non-detections result, in fact, from an insufficient velocity coverage. Global parameters of the detected galaxies are computed, after a careful discussion of the correction for Galactic absorption. Our H  I data are then compared with those obtained by Kraan-Korteweg & Huchtmeier with the Effelsberg radio telescope for 20 galaxies observed in common: the agreement is excellent, implying respective uncertainties on recession velocities and on H  I fluxes lower than 10 km s⁻¹ and 2 Jy km s⁻¹ on average. Finally, we find that the detected galaxies follow well the correlation between the optical linear diameter and the H  I mass found by Haynes & Giovanelli. This result shows that our diameter corrections for Galactic absorption A_B are quite good, except for eight objects which are heavily obscured ( A_B 2.3), or have a very small diameter, lower than 0.5 arcmin.     

Plankton origin of particulate dimethylsulfoniopropionate in a Mediterranean oligotrophic coastal and shallow ecosystem

We report here dimethylsulfide (DMS) and dimethylsulfoniopropionate (DMSP) levels as a function of plankton communities and abiotic factors over a 12-month cycle in the Mediterranean oligotrophic coastal and shallow ecosystem of Niel Bay (N.W. Mediterranean Sea, France). Total particulate DMSP (DMSP_p) and DMS concentrations were highly seasonal, peaking during a spring (April) bloom at 8.9 nM and 73.9 nM, respectively. Significant positive correlations were found between total DMSP_p concentration and the abundance or biomass of the dinoflagellate Prorocentrum compressum (Spearman's rank correlation test: r = 0.704; p = 0.011). Similarly, DMS concentrations peaked during the development of blooms of P. compressum and Gymnodinium sp. There seemed to be a positive relationship between the chlorophyll a to pheopigment ratio and DMS concentrations, suggesting that DMS was released during phytoplankton growth. High DMS levels recorded in the shallow Niel Bay may also result from the activity of benthic macroalgae, and/or macrophytes such as Posidonia spp., or the resuspension of sulfur species accumulating in sediments. The fractionation of particulate DMSP into three size classes (>90 μm, 5–90 μm and 0.2–5 μm) revealed that 5–90 μm DMSP-containing particles made the greatest contribution to the total DMSP_p pool (annual mean contribution = 62%), with a maximal contribution in April (96%). This size class consisted mainly of dinoflagellates (annual mean contribution = 68%), with P. compressum and Gymnodinium sp. the predominant species, together accounting for up to 44% of the phytoplankton present. The positive correlation between DMSP concentration in the 5–90 μm size class and the abundance of P. compressum (Spearman's rank correlation test: r = 0.648; p = 0.023) suggests that this phytoplankton species would be the major DMSP producer in Niel Bay. The DMSP collected in the >90 μm fraction was principally associated with zooplankton organisms, dominated by copepods (nauplii and copepodites). DMSP_>90, not due to a specific zooplankton production, resulted from the phytoplankton cells ingested during grazing. The concomitant peaks of DMS concentration and zooplankton abundance suggest that zooplankton may play a role in releasing DMSP and/or DMS through sloppy feeding.