Evolution of particle size and concentration in the Rhône river mixing zone: : influence of salt flocculation

The salt induced flocculation phenomenon is often proposed as a major mechanism influencing the deposition of the suspended matter near the mouth of major rivers. However, depending on the particular mixing conditions between fresh water and marine water and on suspended solids (SS) reactivity, salt induced aggregation may be a minor factor controlling fast deposition of SS. This work combines field studies and laboratory experiments in order to assess the importance of salt induced flocculation in the case of the saltwedge estuary of the Rhône river. Sampling of the mixing zone has been performed in contrasted hydrodynamic conditions from a low water discharge period (500 m³ s⁻¹) to a small flood event (2400 m³ s⁻¹) for particle counting and salinity measurements. Through laboratory experiments, it is shown that the Rhône river particulate matter has a poor average reactivity regarding salt induced flocculation. Considering the hydrodynamics of the estuary, we show that the evolution of the concentration of larger particles (>5 μm) can be explained by settling and dilution. In contrast, the smallest measured fraction (2–5 μm) shows a more complex behavior and settling processes alone cannot explain the observed particle concentrations during the field studies. Four hypotheses are discussed for explaining the 2–5 μm particle concentration evolutions.     

Amorce de la Sédimentation Synorogénique dans les PyrénéesVarisques. Données Chronologiques; Implications Paléogéographiques

Conodont associations and recent macrofaunal discoveries, allow us to date the beginning of detrital deposits going with the Variscan uplift in the Pyrenean marine basins during the Lower Carboniferous. Thus, the establishing of synorogenic conditions seems to have progressed from the East to the West; there appears the picture of a kind of north-Pyrenean axis already individualized in the wide Cantabrico-Pyrenean foreland.     

Tectonothermal chronology within a blueschist-eclogite complex, west-central Spitsbergen, Svalbard: Evidence from and Rb---Sr mineral ages

A high-pressure, relatively low-temperature metamorphic complex is exposed at Motalafjella, Spitsbergen. White mica concentrates from the complex record variably discordant age spectra in which apparent ages systematically increase throughout low-temperature portions of the analyses and define intermediate- and high-temperature plateaux. Phengitic concentrates record plateau ages of c. 470 Ma whereas paragonitic concentrates yield c. 460 Ma plateaux. These ages are interpreted to date diachronous cooling through different argon closure temperatures following the high-pressure metamorphism. The slight discordance displayed in low-temperature portions of the experiments is interpreted to reflect a partial rejuvenation of intracrystalline argon systems during an c. 400–425 Ma thermal overprint associated with late Caledonian tectonothermal activity. White mica concentrates and associated whole-rocks yield Rb---Sr mineral + whole-rock ages from 457 ± 11 Ma to 474 ± 11 Ma. These are interpreted to date post-metamorphic cooling through Sr blocking temperatures. Because similar ages are recorded by both K---Ar and Rb---Sr isotopic systems, relatively rapid post-metamorphic cooling is implied. This and relatively rapid depressurization during uplift indicate that the and Rb---Sr mineral ages likely closely date the peak metamorphism.The high pressure complex is unconformably overlain by variably cleaved, Upper Ordovician-Lower Silurian flysch which was deformed into regional recumbent folds prior to deposition of unconformably overlying Early Devonian molasse. Two penetratively cleaved slate samples display internally discordant whole-rock age spectra with ages increasing from c. 100 Ma to c. 470 Ma. The spectral discordance is interpreted to reflect the combined effects of: (1) a polymineralic character: (2) a detrital source similar in age to the Motalafjella complex; and (3) a partial, post-Paleozoic thermal rejuvenation of the detrital mica argon systems. No thermal overprint associated with Late Silurian cleavage formation appears to be recorded. This agrees with textural characteristics which suggest that the cleavage largely developed through pressure-solution assisted, grain-boundary sliding.     

Nouvelle hypothèse sur l'origine des formations géologiques de l'île de Timor (Sud-Est asiatique)

Similar lithological and tectonic features indicate that Timor and Sulawesi islands were part of the same continental block. Timor was in the southern part of Sulawesi, then separated during Late Miocene time during the opening of the South Banda Sea basin. At this time Timor evolved as a part of an Upper Miocene volcanic arc that collided the Australian plate at the end of the Lower Pliocene (3.5 Ma). To cite this article: M. Villeneuve et al., C. R. Geoscience 336 (2004).     

Petrography,Geochemistry and Physical Properties of a Continuous Extrusive Section from the Sarami Massif,Semail Ophiolite

As opposed to ocean crustal drilling that often yields a discontinuous core, ophiolites provide a unique opportunity to study continuous sections of oceanic basalts. In order to provide high frequency constraints on the construction of the upper oceanic crust, a continuous 280 m thick volcanic transect was sampled in the Semail ophiolite in Oman. The analyzed section is located in the Sarami Massif, in the central part of the ophiolite, and exposed along Wadi Shaffan. A multidisciplinary study was carried out after sampling in the field. Core measurements including porosity, grain density, compressional velocity, magnetic susceptibility and electrical resistivity for over 100 samples from this transect have been made. Geochemical analyses including major, trace and Rare Earth Elements were also performed on 23 selected samples from this transect. The Wadi Shaffan transect appears as composed of two main petrological and geochemical members providing the main lithostratigraphic signal. The boundary between the two sequences is marked by the presence of a massive flow unit equating to the most primitive lava and across which significant changes in mineralogy and texture are observed. The physical properties equally record significant changes. In all, the section is characterized by chemical compositions coherent with that of V1-Geotime volcanism and appears as built through two main sequences of volcanic activity. The magnetic susceptibility profile correlated to geochemical variations present the most detailed evolution allowing to individualize a succession of at least 4 volcanic phases. These phases are interpreted as magmatic cycles characterized by differentiation processes, allowing one to place high frequency constraints on the volcanic behavior of fast spreading ridges. Some of the physical properties also reflect this series of differentiation trends, as noticed in the past from downhole measurements recorded in the context of deep ocean drilling into the crust.     

ESR,U-series and paleomagnetic dating of Gigantopithecus fauna from Chuifeng Cave,Guangxi, southern China

Several Gigantopithecus faunas associated with taxonomically undetermined hominoid fossils and/or stone artifacts are known from southern China. These faunas are particularly important for the study of the evolution of humans and other mammals in Asia. However, the geochronology of the Gigantopithecus faunas remains uncertain. In order to solve this problem, a program of geochronological studies of Gigantopithecus faunas in Guangxi Province was recently initiated. Chuifeng Cave is the first studied site, which yielded 92 Gigantopithecus blacki teeth associated with numerous other mammalian fossils. We carried out combined ESR/U-series dating of fossil teeth and sediment paleomagnetic studies. Our ESR results suggest that the lower layers at this cave can be dated to 1.92 ± 0.14 Ma and the upper layers can be dated to older than 1.38 ± 0.17 Ma. Correlation of the recognized magnetozones to the geomagnetic polarity timescale was achieved by combining magnetostratigraphic, biostratigraphic and ESR data. The combined chronologies establish an Olduvai subchron (1.945–1.778 Ma) for the lowermost Chuifeng Cave sediments. We also analyzed the enamel δ¹³C values of the Gigantopithecus faunas. Our results show that southern China was dominated by C₃ plants during the early Pleistocene and that the Gigantopithecus faunas lived in a woodland-forest ecosystem.     

Sediment Yield During Late Glacial and Holocene periods in the Lac Chambon Watershed,Massif Central,France

A sediment budget for the Late Glacial and Holocene periods was calculated for the Lac Chambon watershed which is located in a formerly glaciated temperate crystalline mountain area. It appears that over 15 500 years: (1) 69 per cent of eroded particles have been displaced by gravity processes and then stored within the watershed, compared to 31 per cent that have been displaced by running water and evacuated outward; (2) the mean mechanical erosion due to gravity processes on the slopes amounted to 16·1 ±6 m and only developed on a quarter of the watershed surface, whereas the mean mechanical erosion due to running water amounted 1·24 ± 0·37 m and involved the whole watershed surface. The mean sediment yields due to gravity processes on slopes were 2300 ± 1360, 1770 ± 960 and 380 ± 100 m³ km⁻³ a⁻¹, respectively, for basalts, and basic and acidic trachyandesites. Values of sediment yield due to running water were 49±15, 120±36 and 79±24 m³ km⁻² a⁻¹, respectively, during the Bôlling–Allerôd, the Younger Dryas and the Pre-Boreal–Boreal periods. They were 56±17 and 166±50 m³ km⁻² a⁻¹ during the Sub-Atlantic period before and after 1360 a BP , respectively. These values reflect variations in the natural environment and the impact of human-induced deforestation. © 1997 by John Wiley & Sons, Ltd.     

Regolith mass balance inferred from combined mineralogical, geochemical and geophysical studies: Mule Hole gneissic watershed, South India

The aim of this study is to propose a method to assess the long-term chemical weathering mass balance for a regolith developed on a heterogeneous silicate substratum at the small experimental watershed scale by adopting a combined approach of geophysics, geochemistry and mineralogy. We initiated in 2003 a study of the steep climatic gradient and associated geomorphologic features of the edge of the rifted continental passive margin of the Karnataka Plateau, Peninsular India. In the transition sub-humid zone of this climatic gradient we have studied the pristine forested small watershed of Mule Hole (4.3 km²) mainly developed on gneissic substratum. Mineralogical, geochemical and geophysical investigations were carried out (i) in characteristic red soil profiles and (ii) in boreholes up to 60 m deep in order to take into account the effect of the weathering mantle roots. In addition, 12 Electrical Resistivity Tomography profiles (ERT), with an investigation depth of 30 m, were generated at the watershed scale to spatially characterize the information gathered in boreholes and soil profiles. The location of the ERT profiles is based on a previous electromagnetic survey, with an investigation depth of about 6 m. The soil cover thickness was inferred from the electromagnetic survey combined with a geological/pedological survey.Taking into account the parent rock heterogeneity, the degree of weathering of each of the regolith samples has been defined using both the mineralogical composition and the geochemical indices (Loss on Ignition, Weathering Index of Parker, Chemical Index of Alteration). Comparing these indices with electrical resistivity logs, it has been found that a value of 400 Ohm m delineates clearly the parent rocks and the weathered materials. Then the 12 inverted ERT profiles were constrained with this value after verifying the uncertainty due to the inversion procedure. Synthetic models based on the field data were used for this purpose. The estimated average regolith thickness at the watershed scale is 17.2 m, including 15.2 m of saprolite and 2 m of soil cover.Finally, using these estimations of the thicknesses, the long-term mass balance is calculated for the average gneiss-derived saprolite and red soil. In the saprolite, the open-system mass-transport function τ indicates that all the major elements except Ca are depleted. The chlorite and biotite crystals, the chief sources for Mg (95%), Fe (84%), Mn (86%) and K (57%, biotite only), are the first to undergo weathering and the oligoclase crystals are relatively intact within the saprolite with a loss of only 18%. The Ca accumulation can be attributed to the precipitation of CaCO₃ from the percolating solution due to the current and/or the paleoclimatic conditions. Overall, the most important losses occur for Si, Mg and Na with −286 × 10⁶ mol/ha (62% of the total mass loss), −67 × 10⁶ mol/ha (15% of the total mass loss) and −39 × 10⁶ mol/ha (9% of the total mass loss), respectively. Al, Fe and K account for 7%, 4% and 3% of the total mass loss, respectively. In the red soil profiles, the open-system mass-transport functions point out that all major elements except Mn are depleted. Most of the oligoclase crystals have broken down with a loss of 90%. The most important losses occur for Si, Na and Mg with −55 × 10⁶ mol/ha (47% of the total mass loss), −22 × 10⁶ mol/ha (19% of the total mass loss) and −16 × 10⁶ mol/ha (14% of the total mass loss), respectively. Ca, Al, K and Fe account for 8%, 6%, 4% and 2% of the total mass loss, respectively.Overall these findings confirm the immaturity of the saprolite at the watershed scale. The soil profiles are more evolved than saprolite but still contain primary minerals that can further undergo weathering and hence consume atmospheric CO₂.     

Effects of different crystal faces on the surface charge of colloidal goethite (α-FeOOH) particles: an experimental and modeling study

The surface charge of colloidal particles is usually determined by potentiometric titration. These acid-base titrations make it possible to measure the pH of point-of-zero charge (pzc) for oxide minerals. This macroscopic property is the most important parameter used in surface complexation modeling to reproduce experimental data. The pzc values of goethite reported in the literature vary between 7.0 and 9.5. Carbonate adsorption and/or surface morphology are thought to account for this wide range.We demonstrate a procedure for the removal of the carbonate ions that initially adsorb on goethite and strongly affect the titration curves and pzc determination. We also investigated the crystal-face-specific reactivity of two morphologically different goethites. The z-profiles obtained from atomic force microscopy (AFM) images showed that the goethite with the smallest specific surface area (S = 49 m²/g, denoted G49) exhibits 70% of the (001) face, whereas this value is only 30% for the goethite with largest specific surface area (S = 95 m²/g, denoted G95). This morphologic difference results in slightly different pzc values: 9.0 for G49 goethite and 9.1 for G95 geothite. These experimental pzc values have been correlated with multisite complexation calculations using both the full-site and the 1-pK approaches. We used the full-site approach to consider all of the configurations of hydrogen bond interactions with surface site. The resulting mean charges gave estimated pzc values of 8.9 and 9.2 for the (001) and (101) faces, respectively. Considering these theoretical pzc values for individual faces and the face distributions obtained from AFM analysis, the calculated pzc values are in full agreement with the experimental pzc values. However, this morphologic difference is more expressed in surface charge values than in the pzc values. Indeed, the surface charge of G49 goethite is much higher than that of G95 goethite, and the 1-pK calculations make it possible to fit the titration data satisfactorily.     

日本琵琶湖中微囊藻水华形成机理的再认识

Blooms of cyanobacteria are responsible for many problems in freshwater ecosystems. The massive growth of these microorganisms may limit the utilization of freshwater for human requirements since, apart from other problems, the production of toxic substances has been found to occur frequently during blooming periods. Ecologically, cyanobacterial blooms can modify dramatically the ecosystem through their low edibility within the food web and the huge primary production. Thus, saprobic processes are stimulated and the characteristics related to anaerobic conditions are also more extreme.Cyanobacterial blooms are many times explained as the consequence of the eutrophication of waterbodies. However, factors promoting bloom formation and ecological succession of cyanobacteria are not well understood yet.