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101.
102.
Lotfi Mouni Lazhar Belkhiri Abdelkrim Bouzaza Jean-Claude Bollinger 《Arabian Journal of Geosciences》2017,10(4):77
The chemical associations of Cd, Cu, Pb, and Zn in four mine soil samples from the Amizour-Bejaia Pb/Zn mine (Algeria) have been investigated by a five-step sequential extraction procedure. Although Cd preferentially binds to carbonates, Cu, Pb, and Zn are mainly associated with the organic and reducible fractions. Batch adsorption experiments with either mono- or multi-metallic solutions are described with the Freundlich isotherm model. Whatever the nature of the soil sample, the sorption behavior for each given metal except Pb is very similar, indicating that the binding sites at the soil surface are progressively occupied by the metal from the solution. On each soil sample, the decreasing order of sorption can be established as Pb >> Cu > Cd > Zn. When the four metals are simultaneously applied to each soil sample, their specific behavior is strongly affected by their interactions and/or competition for the available surface sites: we generally observed isotherm curves with a slight maximum before the plateau at higher solution concentration. Although Cu is only slightly affected by the other metals, in the case of Pb, Cd, and Zn, the sorbed amounts strongly decreased. 相似文献
103.
Analytical data are reported for As, Bi, Sb, Se and Te in fifty five geological reference materials (RM). The method used is based on hydride generation inductively coupled plasma-mass spectrometry (HG-ICP-MS) following digestion of the samples in the mixed acid attack of HF-HClO4-HNO3-HCl. Analytes were separated from potential interferences by coprecipitation with La(OH)3. This scheme results in method detections limits of: 1 ng g?1 for Bi and Te; 6 ng g?1 for Sb and Se; and 10 ng g?1 for As. The average relative standard deviation (RSD) for three 0.5 g subsamples of each RM analysed by this method are: 3.7% for As in the range 0.35-187 μg g?1; 5.6% for Sb in the range 0.03-22 μg g?1; 6.8% for Bi in the range 0.002-48 μg g?1; 7.2% for Se in the range 6-3610 ng g?1; and 9.0% for Te in the range 2-445 ng g?1. 相似文献
104.
Several temperature–depth profiles recorded at Pipe Mine, 32 km southwest of Thompson, Manitoba, in central Canada, exhibit a marked departure from the equilibrium gradient. These profiles could be interpreted as indicating strong warming (up to 4.5 K) of the ground surface during the last 200 years. All the temperature profiles at Pipe Mine show perturbations stronger than at the others sites in the Thompson Nickel Belt. Temperature profiles recorded near the town of Thompson show a moderate warming (≈1–2 K) trend, while temperature profiles at Soab, 45 km southwest of Pipe Mine, indicate very moderate cooling (≈0.5 K). There was little human activity in this part of Manitoba before the development of the mining camp of Thompson in the late 1950s. Our study shows the variability of ground surface temperature histories at a very local scale (i.e. <1 km) with much stronger signals at some of the Pipe Mine drill holes than at others. These holes are located within 500 m of the highway and a power line built after 1955, at ≈3 km from the now abandoned open pit mine. The ground surface temperature history (GSTH) obtained by the inversion of Pipe Mine temperature profiles suggests that a recent (50 years) and strong (≈1–2 K) ground surface warming is superimposed on a 1–2 K warming trend that started 200 years ago, without any indication of a cold (little ice ages) episode before. The recent warming (40 years) at Pipe Mine is only a local effect and is likely to be related to the presence of the highway. Before 1960, the ground surface temperature history for Pipe is similar to other sites in the Thompson region. Ground surface temperature histories from other profiles within and near the city of Thompson seem less affected by environmental perturbations and their trends are parallel to that of the meteorological records in the Canadian Prairies. 相似文献
105.
Inverse and direct methods have been used to analyze a large number of borehole temperature logs in order to infer past climatic changes. Results indicate a warming of 1–2°C in eastern and central Canada during the past 150 years. A period of cooling between 500 and 200 years before present, corresponding to the time of the “Little Ice Age”, has also been identified in the same areas. A regional ground temperature history is estimated for eastern and central Canada from the simultaneous inversion of several temperature logs. The inferred temperature changes appear correlated with the concentration of atmospheric carbon dioxide as reported from a Greenland ice core, and agree with existing meteorological and dendrochronological records for the area. 相似文献
106.
Abstract— A large number of ordinary chondrites contains micron-sized particles of metal and/or troilite dispersed in their silicate grains. Such metallic phases are responsible for the so-called darkening of the silicate grains and might be either precipitates, which formed during reduction of the silicates, or inclusions injected as a melt during a shock event. We have investigated these tiny foreign phases by analytical transmission electron microscopy in three unweathered, metamorphosed ordinary chondrites (Saint Séverin, LL6, Tsarev, L6 and Kernouvé, H6). We also looked for remnant shock indices. Our TEM observations suggest the following sequence of events in the three meteorites. First, a number of relatively strong shock events occurred on the parent body/bodies producing an Fe-FeS melt that was injected into silicate grains along a dense network of open fractures. Most of these shock defects were subsequently erased by high-temperature (700–900 °C) thermal metamorphism. Some remnants of the shock events are the observed trails of tiny metal and/or sulfide inclusions that formed as a result of fracture healing. Chemical homogenization of the silicates and limited oxidation of the metallic blebs also occurred during this high-temperature annealing event, resulting in Ni-rich inclusions. This effect was especially pronounced in the L and LL-chondrites studied. During subsequent cooling of the body/bodies, inclusions of chromite and phosphate precipitated, nucleating preferentially on lattice defects (dislocations, subgrain boundaries) and on the metal and sulfide inclusions. A later shock event of moderate intensity, probably corresponding to the separation of the meteorite from its parent body, produced new shock features in the silicate grains of the Saint Séverin meteorite, including mechanical twins in diopside and straight free screw dislocations in olivine. 相似文献
107.
We have investigated by Transmission Electron Microscopy (TEM) the planar deformation features(PDF) in quartz from various sites where shock metamorphism has been detected optically: impact sites; the Vredefort complex (South Africa) and the K/T boundary at Raton Basin (Colorado). PDFs are straight narrow bands of glass or microtwins or huge densities of dislocations. Such contrasting microstructures must reflect different shock scenarios. In the Vredefort complex the post-shock thermal history has strongly overprinted the shock-induced defects. In the Raton Basin samples very tiny bubbles have precipitated on the dislocations, strongly suggesting a lengthy annealing at moderate pressure and temperature. This new information should be taken into account in any model of the origin of the K/T transition. In any case, observation of PDFs by optical microscopy alone is not sufficient to unambiguously conclude on their origin. 相似文献
108.
Information obtained from various parts of the two books on Montagne Pelée by Lacroix enables an estimate to be made of the size of l’Etang Sec summit crater, the volume of the 1902–1905 lava dome and its growth rate at various stages of development. During the week preceding the 8 May nuée ardente, dome growth was between 28 and 38 m3 s–1, leading to a volume of 17–23×106 m3 on the morning of the catastrophe. Considering that significant parts of the dome (~1/3?) were removed by the 8 and 20 May climactic eruptions, a high magmatic flux could have continued until at least 27 May, when the total remaining volume was estimated to 53×106 m3. After moderate activity in June–July (of order 10 m3 s–1), vigorous dome growth resumed dramatically, leading to the third climactic eruption of 30 August (a true calculation for this period being not feasible because of poor quality of the data). From November 1902 to July 1903 most of the effusive activity was concentrated in the great spine (erupted volume ~15×106 m3, magma flux 1.2 m3 s–1), which was eventually destroyed by collapse and minor nuées ardentes. The end of the eruption was characterized by a very low effusion rate, <1 m3 s–1 in average from August 1903 to October 1905. 相似文献
109.
Spectral analysis techniques have been applied to data sets of gravity and topography selected across fracture zones with large offset in the Equatorial and Central Atlantic Ocean and processed independently for each fracture zone. Three simple compensation models, two in local isostatic equilibrium (Airy I and II) and one in regional equilibrium (Plate model) have been tested. It is found that the free-air anomalies are primarily controlled by the topography and its isostatic response. For short wavelengths, admittance can be explained either by the effect of uncompensated sea floor topography with high density basement or by the effect of uncompensated sea floor topography with normal oceanic basement density but accompanied by a crust of constant thickness. For intermediate wavelengths, admittance for the Romanche fracture zone agrees best with a local isostatic model in which compensation is achieved by a less dense material in the upper mantle. No such evidence exists for the Vema and Chain fracture zones for which topography could just as well be regionally supported by an elastic plate 3 to 10 km thick. For longer wavelengths, the admittances computed for the three fracture zones are compatible with a thermal compensation of the topography. 相似文献
110.
Gilbert Mille Jan Yu Chen Henri Dou Edgar Azoulay Maryse Colin Jean-Claude Bertrand 《Marine environmental research》1985,17(1):65-80
Coastal Mediterranean sediments highly polluted by refinery effluents have been studied for their hydrocarbon content and bacterial activity. The study has taken into account both the distance from the refinery and depth of sampling. Very high hydrocarbon concentrations have been found (1–250 g/kg dry sediment). Micro-organisms in the sediments have a high bacterial activity and a good correlation exists between hydrocarbon concentrations and bacteria able to use these substrates as a carbon and energy source. 相似文献