Micro- to nano-scale characterization of martite from a banded iron formation in India and a lateritic soil in Brazil

The pseudomorphic transformation of magnetite into hematite (martitization) is widespread in geological environments, but the process and mechanism of this transformation is still not fully understood. Micro- and nano-scale techniques—scanning electron microscopy, focused ion bean transmission electron microscopy, and Raman spectroscopy—were used in combination with X-ray diffraction, Curie balance and magnetic hysteresis analyses, as well as Mössbauer spectroscopy on martite samples from a banded iron formation (2.9 Ga, Dharwar Craton, India), and from lateritic soils, which have developed on siliciclastic and volcanic rocks previously affected by metamorphic fluids (Minas Gerais, Brazil). Octahedral crystals from both samples are composed of hematite with minor patches of magnetite, but show different structures. The Indian crystals show trellis of subhedral magnetite hosting maghemite in sharp contact with interstitial hematite crystals, which suggests exsolution along parting planes. Grain boundary migrations within the hematite point to dynamic crystallization during deformation. Dislocations and fluid inclusions in hematite reflect its precipitation related to a hydrothermal event. In the Brazilian martite, dislocations are observed and maghemite occurs as Insel structures and nano-twin sets. The latter, typical for the hematite, are a transformation product from maghemite into hematite. For both samples, a deformation-induced hydrothermally driven transformation from magnetite via maghemite to hematite is proposed. The transformation from magnetite into maghemite comprises intermediate non-stoichiometric magnetite steps related to a redox process. This study shows that martite found in supergene environment may result from earlier hypogene processes.     

Probability-based damage assessment for reinforced concrete bridge columns considering the corrosive and seismic hazards in Taiwan

In this paper, we consider the time at which earthquake events occur when analyzing seismic structural damage to a deteriorating RC bridge within a specified period. Because the uncertainty exists in the occurrence time of earthquake events, Monte Carlo simulation is applied. The proposed procedure for evaluating the exceedance probability, which corresponds to a specified limit state, is then applied to a case study of RC bridges in Taiwan to demonstrate its applicability. This study selects three typical RC bridges located in the Taipei Basin, Taiwan, to analyze exceedance probabilities of specified damage states during various specified periods and then discusses the cumulative damage effect on the exceedance probabilities of specified damage states. Additionally, for the chloride-induced deteriorating bridges at various distances to the sea in Suao, Taiwan, the effects of the deterioration and seismic structural damage on the exceedance probabilities of specified damage states are demonstrated and discussed. The proposed assessment procedure can help engineers understand whether the deterioration would accelerate the declining seismic performance of bridges and shorten their serviceability-related and safety-related service lives, as well as provide reference for repairing RC bridges and retrofitting their seismic performance.     

A review of multiple natural hazards and risks in Germany

Although Germany is not among the most hazard-prone regions of the world, it does experience various natural hazards that have caused considerable economic and human losses in the past. Moreover, risk due to natural hazards is expected to increase in several regions of Germany if efficient risk management is not able to accommodate global changes. The most important natural hazards, in terms of past human and economic damage they caused, are storms, floods, extreme temperatures and earthquakes. They all show a pronounced spatial and temporal variability. In the present article, a review of these natural hazards, associated risks and their management in Germany is provided. This review reveals that event and risk analyses, as well as risk management, predominantly focus on one single hazard, generally not considering the cascading and conjoint effects in a full multi-hazard and risks approach. However, risk management would need integrated multi-risk analyses to identify, understand, quantify and compare different natural hazards and their impacts, as well as their interactions.     

Brazil's Amazon forest in mitigating global warming: unresolved controversies

Brazil's Amazon rainforest provides an important environmental service with its storage of carbon, thereby reducing global warming. A growing number of projects and proposals intend to reward carbon storage services. Reducing emissions from deforestation and forest degradation is currently a key issue for negotiations on an international agreement that is to take effect in 2013. Various issues require decisions that will have substantial impacts on both the effectiveness of mitigation and the scale of Amazonia's potential role. These decisions include the effects that money generated from payments can have, the spatial scale of mitigation (e.g. projects or countries and sub-national political units), whether to have voluntary or mandatory markets, and whether these reductions will generate carbon credits to offset emissions elsewhere. It is argued that national-level programmes, combined with a national target under the United Nations Framework Convention on Climate Change, are the best solution for Brazil in terms of both capturing international funding and stimulating the major cuts in global emissions that are needed to minimize climate risk to the Amazon rainforest. The high likelihood of passing a tipping point for maintaining the Amazon rainforest implies the need for urgency in altering current negotiating positions.     

Seasonal Rainfall Forecasts for the Yangtze River Basin in the Extreme Summer of 2020※

Seasonal forecasts for Yangtze River basin rainfall in June, May–June–July (MJJ), and June–July–August (JJA) 2020 are presented, based on the Met Office GloSea5 system. The three-month forecasts are based on dynamical predictions of an East Asian Summer Monsoon (EASM) index, which is transformed into regional-mean rainfall through linear regression. The June rainfall forecasts for the middle/lower Yangtze River basin are based on linear regression of precipitation. The forecasts verify well in terms of giving strong, consistent predictions of above-average rainfall at lead times of at least three months. However, the Yangtze region was subject to exceptionally heavy rainfall throughout the summer period, leading to observed values that lie outside the 95％ prediction intervals of the three-month forecasts. The forecasts presented here are consistent with other studies of the 2020 EASM rainfall, whereby the enhanced mei-yu front in early summer is skillfully forecast, but the impact of midlatitude drivers enhancing the rainfall in later summer is not captured. This case study demonstrates both the utility of probabilistic seasonal forecasts for the Yangtze region and the potential limitations in anticipating complex extreme events driven by a combination of coincident factors.     

Coastal margin evolution and postulated “basin‐shipyard” area at ancient Locri‐Epizephiri,Calabria, Italy

Environmental settings on the Ionian coastal plain and inner shelf seaward of Locri‐Epizephiri in Calabria, Italy, differed markedly before, during, and following settlement by the Greeks. Sediment core analyses and geophysical surveys in this study support recent archaeological findings and the hypothesis that the margin may once have served as a harbor and/or shipyard. The subsurface Holocene stratigraphy records that (1) the shoreline advanced to a maximum landward position before Greek settlement, then regressed offshore to what is now the inner shelf before once again migrating landward. These marked coastal shifts were triggered primarily by land uplift and probable subsidence offshore along this structurally active Calabrian Arc segment. Associated with this are: (2) a sediment fining‐upward sequence in Greek–Roman time that indicates only partial protection of the coastal area, and (3) possible presence of subsurface structures seaward of the city wall in a sector now positioned ∼200 m offshore. © 2010 Wiley Periodicals, Inc.     

Geophysical response of slackwater and sandy terrace deposits near Savanna, Northwestern Illinois

Low-permeability clayey and silty river terrace deposits are an important component in protecting underlying aquifers from contamination by agrochemicals and other contaminants. Such deposits also record deglaciation dynamics, meltwater drainage and local climatic variations. In this study, conducted over Mississippi River terraces near Savanna, Illinois, clayey slackwater terrace deposits and sandy terrace deposits are examined using resistivity soundings, ground-penetrating radar (GPR) profiles and direct-push conductivity logs. The clayey terrace deposits are characterized by low resistivity (10–35 ohm-m) and slow GPR wave velocity (0.07 m/ns), whereas non-clayey terrace deposits exhibit much higher resistivity (169–1,762 ohm-m) and faster GPR wave velocities (0.15 m/ns). Sandy and clayey terrace deposits may thus be differentiated and mapped on the basis of their geophysical response. Models based on resistivity soundings provide reasonably accurate estimates of the thickness of clayey slackwater deposits, but fail to reveal thin sands embedded in the clayey deposits. In some cases, the full thickness of the slackwater deposits was also not revealed. GPR profiles, however, imaged these embedded shallow sands and possibly imaged deeper sands below the base of the slackwater deposits, giving more accurate estimates of thickness. GPR also accurately resolved the thickness and character of sandy terrace deposits. Direct-push conductivity logs provide both accurate estimates of the thickness of clayey slackwater terrace deposits and a means of identifying thin embedded sands. In summary, resistivity soundings image these deposits at the lowest resolution with one-dimensional models, whereas GPR provides much higher resolution showing detailed layering within the upper several meters. Direct-push conductivity logs provide the highest resolution, but are invasive and only reveal stratigraphy at one location.     

A mineralogical and geochemical study of polymict eucrite discovered in Sahara of southwest Algeria

NWA2268 is a polymict eucrite discovered in the Sahara, at southwest Algeria, close to the region of Tindouf. This meteorite weighs 65 g and presents a thin black fusion crust. The rock is fine- to medium-grained breccia and contains mineral fragments of plagioclases, pyroxenes, spinel, olivine and silica. The rock contains some basaltic fragments with sub-ophitic or cumulative textures, constituted by plagioclases and exsolved pigeonite. Pyroxferroite grains are present and locally destabilised in an association of hedenbergite, fayalite and silica. It also presents unequilibrated eucritic clast with heterogeneous pyroxenes and plagioclases compositions. Pyroxenes in the all of the other clasts have equilibrated composition, with exolved pigeonites with augite lamellaes. This polymict eucrite contains also partially devitrified glass that represents impact melts linked to impact event. None recrystallization of this glass confirms a lack of post-brecciation metamorphism. Diogenitic fragments are less abundant than 10 %. The oxygen isotopic composition of NWA2268 is Δ¹⁷O (?0.43). This meteorite is interpreted as belonging to the HED group attributed to the 4-Vesta asteroid.