Relative influence of physical removal and biodegradation in the depuration of petroleum-contaminated seashore sediments

Two field experiments were conducted for a 21-month period to monitor the fate of an Arabian light crude oil spread on the surface of seashore sediments at low energy sites. The weathering of saturated and of aromatic hydrocarbons followed curvilinear decreasing curves, the saturates being eliminated more rapidly than the aromatics. The asphaltic fraction was more persistent and decreased only very slowly. On the basis of the results, a tentative semi-quantitative graphic model is proposed to evaluate the relative parts of physical removal and of biodegradation in the decontamination of oil-polluted seashore sediments. The model establishes interrelations between the residual concentration of total hydrocarbons (sum of saturates and aromatics), the age of the pollution and the biodegradation stage, defined by capillary gas-chromatography. The biodegradation stage was directly related to the residual level of the oil contamination in the sediments.     

Highly reducing conditions during Alpine metamorphism of the Malenco peridotite (Sondrio,northern Italy) indicated by mineral paragenesis and H2 in fluid inclusions

During regional metamorphism of the Malenco serpentinized peridotite (Sondrio, northern Italy), the mineral assemblage pentlandite-awaruite-magnetite-native copper-antigorite-brucite-olivine-diopside is formed. The opaque assemblage indicates very reduced fluids with fO₂ values 4 log units below QFM. Primary fluid inclusions were trapped in diopside overgrowth, contemporaneous with the opaque assemblage. These metamorphic fluids are saline aqueous solutions (about 10.4 mol% NaCl equivalent) and contain molecular H₂ of approximately 1 mol%, as shown by micro-Raman analysis and microthermometry. The fluids are interpreted to have been formed during deserpentinization at the olivine-in isograd under strong reducing conditions.     

Derivation of detrital rutile in the Yaoundé region from the Neoproterozoic Pan-African belt in southern Cameroon (Central Africa)

Rutile, as an important component in alluvial or eluvial heavy mineral deposits, is known in southern Cameroon. These deposits are underlain by the Neoproterozoic low- to high-grade Yaoundé Group. Geochemical, thermometric, fluid inclusion and Pb isotopic studies of the rutile from alluvial and eluvial concentrates and from medium-grade micaschist from the nearby Yaoundé region permit the following conclusions: (1) alluvial and eluvial rutile of the Yaoundé region are derived from the degradation of metapelites, metamafic rocks and pegmatites of the nearby Yaoundé Group; (2) rutile in the Yaoundé Group formed during the Pan-African metamorphism, or was inherited as detrital rutile from a 900 Ma source. The study also shows that the rutile can be used to trace the history of the Pan-African belt north of the Congo craton.     

Mechanisms of lateral and linear extension of gullies (dongas) in a subhumid grassland of South Africa

The formation of deep gullies (called ‘dongas’ locally) in rangeland in KwaZulu-Natal Province in South Africa is a natural phenomenon. These U-shaped, very wide gullies have considerable lateral expansion due to the episodic collapse of sidewalls. The dongas have developed in duplex soils such as Luvisols and Lixisols formed on Permian sedimentary rocks or unconsolidated Quaternary colluvium. This study combined morphological, mineralogical and chemical characterization with measurements of grain-size content, structural stability and the complete shrinkage curve to detect changes in soil properties of the different horizons located in the gully banks. The different soil horizons present clear and sharp differences in physical and mineralogical properties. The topsoil with complete grass cover is very resistant to soil detachment. However, the leached E horizon and the BC horizon have low structural stability. The soil profile down to and including the Bt horizon contains exclusively illite in the clay fraction, while the BC colluvial layer and the C horizon (mudstone) contain expandable interstratified illite–smectite. The Bt horizon has a high water content at saturation and high shrinkage, while the BC and C horizons have a high residual shrinkage and a very low water content at saturation. Because this type of gully expansion is not significantly linked to slope value or the stream power index (SPI) at the gully head, to land-use change, high rainfall intensities or the threshold of concentrated runoff being exceeded at the gully head, other causes were investigated. It was concluded that the heterogeneity between horizons with different mineralogical properties and structural stabilities, soil types and parent material, anisotropic water-saturation and shrink-swell properties are of major importance. This heterogeneity between different soil horizon morphologies and their physical properties can explain why the relationship between the critical slope and the drainage area for gully initiation showed a threshold for gullying much lower than that found elsewhere. © 2020 John Wiley & Sons, Ltd.     

Seasonal vegetation and management influence overland flow velocity and roughness in upland grasslands

There is considerable interest in how headwater management may influence downstream flood peaks in temperate humid regions. However, there is a dearth of data on flow velocities across headwater hillslopes and limited understanding of whether surface flow velocity is influenced by seasonal changes in roughness through vegetation cycles or management. A portable hillslope flume was used to investigate overland flow velocities for four common headwater grassland habitats in northern England: Low-density Grazing, Hay Meadow, Rank Grassland and Juncus effusus Rush pasture. Overland flow velocity was measured in replicate plots for each habitat, in response to three applied flow rates, with the experiments repeated during five different periods of the annual grassland cycle. Mean annual overland flow velocity was significantly lower for the Rank Grassland habitat (0.026 m/s) followed by Low-density Grazing and Rushes (0.032 and 0.029 m/s), then Hay Meadows (0.041 m/s), which had the greatest mean annual velocity (examples from 12 L/min flow rate). Applying our mean overland flow velocities to a theoretical 100 m hillslope suggests overland flow is delayed by >1 hr on Rank Grassland when compared to Hay Meadows in an 18 mm storm. Thus grassland management is important for slowing overland flow and delaying peak flows across upland headwaters. Surface roughness was also strongly controlled by annual cycles of vegetation growth, decay, grazing and cutting. Winter overland flow velocities were significantly higher than in summer, varying between 0.004 m/s (Rushes, November) and 0.034 m/s (Rushes, June); and velocities significantly increased after cutting varying between 0.006 m/s (Hay meadows, July) and 0.054 m/s (Hay meadows, September). These results show that seasonal vegetation change should be incorporated into flood modelling, as cycles of surface roughness in grasslands strongly modify overland flow, potentially having a large impact on downstream flood peak and timing. Our data also showed that Darcy-Weisbach roughness approximations greatly over-estimated measured flow velocities.     

Complex conductivity response to microbial growth and biofilm formation on phenanthrene spiked medium

Several laboratory studies have recently demonstrated the utility of geophysical methods for the investigation of microbial-induced changes over contaminated sites. However, it remains difficult to distinguish the effects due to the new physical properties imparted by microbial processes, to bacterial growth, or to the development of bacterial biofilm. We chose to study the influence of biofilm formation on geophysical response using complex conductivity measurements (0.1-1000 Hz) in phenanthrene-contaminated media. Biotic assays were conducted with two phenanthrene (PHE) degrading bacterial strains: Burkholderia sp (NAH1), which produced biofilm and Stenophomonas maltophilia (MATE10), which did not, and an abiotic control. Results showed that bacterial densities for NAH1 and MATE10 strains continuously increased at the same rate during the experiment. However, the complex conductivity signature showed noticeable differences between the two bacteria, with a phase shift of 50 mrad at 4 Hz for NAH1, which produced biofilm. Biofilm volume was quantified by Scanning Confocal Laser Microscopy (SCLM). Significant correlations were established between phase shift decrease and biofilm volume for NAH1 assays. Results suggest that complex conductivity measurements, specifically phase shift, can be a useful indicator of biofilm formation inside the overall signal of microbial activity on contaminated sites.     

Reduced removal of bacteriophage MS2 in during basin infiltration managed aquifer recharge as basin sand is exposed to infiltration water

Basin infiltration managed aquifer recharge (MAR) is a commonly used method for storing and treating surface water to be used as drinking water. This study examined how the removal of bacteriophage MS2 was affected by the relative age of the sand used for basin infiltration MAR at 4 °C using batch experiments (static and agitated) and column experiments. The sand and the water used in all experiments were characteristic of that used at a basin infiltration MAR scheme in Uppsala, Sweden. Experimental data was fit with numerical models describing the fate and transport of virus in soil—water systems. The “used” sand that had been subjected to intermittent infiltration over a period of 8 years had 15 times the amount of organic carbon than the “new” sand, which had yet to be used for infiltration. Results showed that attachment of MS2 to the new sand in batch experiments was relatively irreversible. Attachment to the used sand was reversible. Inactivation of MS2 was slowed when it was attached to the used sand. Results for the column experiments showed that the removal rate of MS2 was significantly lower in columns of used sand than in columns of new sand. Simulations indicated that MS2 would be entirely removed in the infiltration basins with new sand. Less than 3 log removals was estimated for basins with used sand. Reduced removal of MS2 by the used sand was deemed to be most likely due to organic coatings on the used sand. Results of this study give deeper insight into the mechanisms responsible for removing virus in infiltration basins and how those mechanisms will change as the sand in the basin is exposed to infiltration water.     

Analyse du transport solide en suspension dans le bassin versant de l'Oued El Hammam (Algérie du Nord)

Résumé

Dans les régions semi-arides et arides, caractérisées par des précipitations relativement faibles et souvent à caractère torrentiel, les facteurs climatiques jouent un rôle primordial dans l'érosion des sols à l'échelle des versants. La majeure partie de l'exportation des matériaux solides est effectuée par les cours d'eau lors des crues. La présente étude traite de l'évaluation et de la quantification du transport solide dans le bassin versant de l'Oued El Hammam, un sous-bassin important de la Macta caractérisé par une forte érosion hydrique. La sensibilité des roches à l'érosion, l'intensité des précipitations et les perturbations du régime d'écoulement font que le flux des matières en suspension (MES) transportées par l'Oued El Hammam atteint des valeurs très importantes. L'analyse du bilan qui règle le processus pluie–ruissellement–transport solide montre de bonnes relations, notamment entre la lame d'eau écoulée et la quantité de charge solide transportée. Nous présentons des modèles statistiques permettant de reproduire les flux de MES. Après calage et validation des modèles sur les chroniques mesurées, ils sont utilisés afin de reconstituer des chroniques de flux de MES non mesurées, à partir de données historiques de débit et de pluie. L'étude de la relation C–Q à l'échelle de la crue a été modélisée par une fonction puissance Y = aX^b ; une analyse statistique de la constante a et de l'exposant b a été menée afin d'expliquer le comportement de ces deux paramètres et de mieux comprendre l'aspect aussi bien pratique que théorique des processus.

Citation El Mahi, A., Meddi, M., et Bravard, J.-P., 2012. Analyse du transport solide en suspension dans le bassin versant de l'Oued El Hammam (Algérie du Nord). Hydrological Sciences Journal, 57 (8), 1642–1661.