U–Pb and Hf isotopic study of zircons from migmatised amphibolites in the Cathaysia Block: Implications for the early Paleozoic peak tectonothermal event in Southeastern China

Amphibolites occur in a number of localities in the Cathaysia Block, some of them have been migmatised and their protoliths represent basaltic magmas erupted in various tectonic settings. Four migmatised amphibolites were collected from Jiangxi and Fujian Provinces. Cathodo-luminescence images of zircons extracted from the representative amphibolites show unzoned or sector-zoned structure. LA-ICP-MS analysis indicates that most zircons have high Th/U ratios and yield U–Pb zircon ages of 446 ± 5, 435 ± 2, 434 ± 4 and 423 ± 2 Ma, respectively. Lu–Hf isotopic analysis on these zircons gives Hf model ages ranging from 900 to 1200 Ma. Based on lithological observations and previously published geochronological data, we interpret that these U–Pb ages record an important tectonothermal event that led to the migmatization. This early Paleozoic (Caledonian) tectonothermal event in the Southeastern China has a great tectonic implication for the evolutionary history of the Cathaysia Block.     

Modeling the 2D behavior of dry‐stone retaining walls by a fully discrete element method

The dry‐stone retaining walls (DSRW) have been tipped as a promising solution for sustainable development. However, before recently, their behavior is relatively obscure. In this study, discrete element method (DEM) approach was applied to simulate the plane strain failure of these walls. A commercial DEM package (PFC2D™) was used throughout this study. The authors used a fully discrete approach; thus, both the wall and the backfill were modeled as discrete elements. The methodology for obtaining the micromechanical parameters was discussed in detail; this includes the three mechanical sub‐systems of DSRWs: wall, backfill and interface. The models were loaded progressively until failure, and then the results were compared with the full‐scale experimental results where the walls were loaded, respectively, with hydrostatic load and backfill. Despite its complexity and its intensive calculation time, DEM model can then be used to validate a more simplified approach. Copyright © 2015 John Wiley & Sons, Ltd.     

Structural investigation of the synthetic CaAn(PO4)2 (An = Th and Np) cheralite-like phosphates

The crystallographic structures of the synthetic cheralite, CaTh(PO₄)₂, and its homolog CaNp(PO₄)₂ have been investigated by X-ray diffraction at room temperature. Rietveld analyses showed that both compounds crystallize in the monoclinic system and are isostructural to monazite LnPO₄ (Ln = La to Gd). The space group is P2₁/n (I.T. = 14) with Z = 2. The refined lattice parameters of CaTh(PO₄)₂ are a = 6.7085(8) Å, b = 6.9160(6) Å, c = 6.4152(6) Å, and β = 103.71(1)° with best fit parameters R _wp = 4.87%, R _p = 3.69% and R _B = 3.99%. For CaNp(PO₄)₂, we obtained a = 6.6509(5) Å, b = 6.8390(3) Å, c = 6.3537(8) Å, and β = 104.12(6)° and R _wp = 6.74%, R _p = 5.23%, and R _B = 6.05%. The results indicate significant distortions of bond length and angles of the PO₄ tetrahedra in CaTh(PO₄)₂ and to a lesser extent in CaNp(PO₄)₂. The structural distortions were confirmed by Raman spectroscopy of CaTh(PO₄)₂. A comparison with the isostructural compounds LnPO₄ (Ln = Ce and Sm) confirmed that the substitution of the large rare earth trivalent cations with Ca²⁺ and Th⁴⁺ introduces a distortion of the PO₄ tetrahedra.     

Time‐scale analysis in unsaturated porous media under external wave loads

Extreme waves caused by tsunamis and storm surges can lead to soil failures in the near‐shore region, which may have severe impact on coastal environments and communities. Multiphase flows in deformable porous media involve several coupled processes and multiple time scales, which are challenging for numerical simulations. The objective of this study is to investigate the roles of the various processes and their interactions in multiphase flows in unsaturated soils under external wave loading, via theoretical time‐scale analysis and numerical simulations. A coupled geomechanics–multiphase flow model based on conservation laws is used. Theoretical analysis based on coupled and decoupled models demonstrates that transient and steady‐state responses are governed by pore pressure diffusion and saturation front propagation, respectively, and that the two processes are essentially decoupled. Numerical simulations suggest that the compressibility of the pore fluids and the deformation of the soil skeleton are important when the transient responses of the media are of concern, while the steady‐state responses are not sensitive to these factors. The responses obtained from the fully coupled numerical simulations are explained by a simplified time‐scale analysis based on coupled and decoupled models. Copyright © 2010 John Wiley & Sons, Ltd.     

Fracture roughness and thermal exchange: A case study at Soultz-sous-Forêts

Heat exchange during laminar flow in an open fracture is studied numerically on the basis of the Stokes equation in the limit of hydrothermal lubrication. We examine the influence of fracture roughness on hydraulic permeability and heat flux through the fracture sides when a cold fluid is injected into a homogeneous hot host rock. Spatial temperature fluctuations inside the fluid are studied assuming the temperature of the rock to be constant and the fracture aperture to be self-affine. An application to the case study at the deep geothermal reservoir of Soultz-sous-Forêts, France, is presented. Finally, a thermal model based on sparse spatial information of the geometrical aperture is successfully proposed to reproduce the response of the fracture.     

Fluid composition and evolution in coesite-bearing rocks (Dora-Maira massif,Western Alps): implications for element recycling during subduction

Fluid inclusions and F, Cl concentration of hydrous minerals were analysed in the coesite-pyrope quartzite, the interlayered jadeite quartzite and their country-rock gneiss from the Dora-Maira massif using a combination of microthermometry, Raman spectrometry, synchrotron X-ray microfiuorescence and electron microprobe analysis. Three populations of fluid inclusions were recognized texturally and can be related to distinct metamorphic stages. A low-salinity aqueous fluid occurs in the retrogressed country gneiss and as late secondary inclusions in jadeite quartzite and chloritized pyrope. An earlier secondary population is found in matrix quartz of the jadeite- and pyro-pe-quartzites. This population can be related to the early decompression and so to incipient breakdown of garnet into phlogopite-bearing assemblages. The inclusion fluid is highly saline (up to 84 wt% equivalent NaCl) and contains Na, Ca, Fe, Cu and Zn as major cations. In pyrope quartzite, additional K was found in these brines, which locally coexist with CO₂-rich inclusions. The oldest fluid inclusions are preserved in kyanite grains included in fresh pyrope and in pyrope itself. In pyrope, all inclusions have decrepitated and contain magnesite, an Mg-phosphate, sheet-silicate(s), a chloride and an opaque phase, with no fluid preser ved. In contrast, the kyanite inclusions in pyrope preserve primary H₂O-CO₂ low-salinity fluid inclusions, probably owing to the low compressibility of the kyanite inclusions and host garnet. In spite of in-situ re-equilibration, these inclusions can be interpreted as relics of the dehydration fluid that attended pyrope growth. These correlations between textural and chemical fluid inclusion data and metamorphic stages are consistent with the fluid composition calculated from the halogen content of different generations of phlogopite and biotite. The preservation of different fluid compositions, both in time and space, is evidence for local control and possibly origin of the fluids, in agreement with isotopic data. These results, in particular the absence of CO₂ in the jadeite quartzite, are best interpreted in terms of a fluid-melt system evolution. With increasing metamorphism, partitioning of H₂O, Na, Ca, Fe and heavy metals into melt (jadeite quartzite) and Mg, Na/K, F, CO₂ and P(?) into a residual aqueous fluid can account for depletion in Na, Ca and Fe of the pyrope quartzite. During the retrograde path, a _{H 2 O} rose as melt crystallized, generating the two populations of hypersaline and water-rich fluids that were highly reactive to pyrope. The process of fluid-melt interaction envisioned here coupled with models of melt extraction in subduction zones provides an attractive opportunity for the instantaneous ( < 1 Ma) and selective transport of elements between a downgoing slab and the overlying mantle wedge.     

Investigating the swelling pressure of highly compacted bentonite/sand mixtures under constant-volume conditions

Acta Geotechnica - Compacted bentonite/sand mixtures are often considered as sealing/backfilling materials in deep geological disposal for radioactive waste. This study investigates the swelling...     

Vertical geochemical variations and arsenic mobilization in the shallow alluvial aquifers of the Chapai-Nawabganj District, northwestern Bangladesh: implication of siderite precipitation

Core sediments from three disturbed boreholes (JOR, GHAT, and RAJ) and two undisturbed boreholes (DW1 and DW2) were collected in the study area of the Chapai-Nawabganj district of northwestern Bangladesh for geochemical analyses. In the study area, groundwater samples from fourteen As-contained private wells and five nested piezometers at both the DW1 and DW2 boreholes were also collected and analyzed. The groundwater arsenic concentrations in the uppermost aquifer (10–40 m of depth) range from 3 to 315 μg/L (mean 47.73 ± 73.41 μg/L), while the arsenic content in sediments range from 2 to 14 mg/kg (mean 4.36 ± 3.34 mg/kg). An environmental scanning electron microscope (ESEM) with an energy dispersive X-ray spectrometer was used to investigate the presence of major and trace elements in the sediments. Groundwaters in the study area are generally the Ca–HCO₃ type with high concentrations of As, but low levels of Fe, Mn, NO₃ ^? and SO ₄ ^?2 . The concentrations of As, Fe, Mn decrease with depth in the groundwater, showing vertical geochemical variations in the study area. Statistical analysis clearly shows that As is closely associated with Fe and Mn in the sediments of the JOR core (r = 0.87, p < 0.05 for Fe and r = 0.78, p < 0.05 for Mn) and GHAT core (r = 0.95, p < 0.05 for Fe and r = 0.93, p < 0.05 for Mn), while As is not correlated with Fe and Mn in groundwater. The comparatively low Fe and Mn concentrations in some groundwater and the ESEM image revealed that siderite precipitated as a secondary mineral on the surface of the sediment particles. The correlations along with results of sequential extraction experiments indicated that reductive dissolution of FeOOH and MnOOH represents a mechanism for releasing arsenic into the groundwater.     

Seasonal changes in zooplanktonic alkaline phosphatase activity in Toulon Bay (France): the role of Cypris larvae

We studied zooplankton contribution to the total particulate phosphatase activity, the kinetics of this activity, the relation to the different taxonomic groups and the role of particle-bound bacteria. The activity of total particulate material collected from a liter of seawater was more elevated in May, June and August than during the rest of the year. These high activities resulted from a high contribution of the >90 microm fraction which account then for more than 60% of the total particulate activity. Two Michaelian processes with high and low V(max) were disclosed on this fraction. The high V(max) component was responsible for the high summer activities. During these periods, high densities of cirriped Cypris were found which were statistically correlated with this high V(max) component as with its specific activity. Moreover, the contribution of attached bacteria to these high activities was low. In return, this contribution was predominant during the periods of low activity. A simple method was developed to characterise this bacterial activity.