Vertical distribution and mobilization of arsenic in shallow alluvial aquifers of Chapai-Nawabganj district, Northwestern Bangladesh

Core sediments from two boreholes and groundwater from fifty four As-contaminated well waters were collected in the Chapai-Nawabganj area of northwestern Bangladesh for geochemical analysis. Groundwater arsenic concentrations in the uppermost aquifer (10 to 40 m of depth) range from 2.76?C315.15 mg/l (average 48.81 mg/l). Arsenic concentration in sediments ranges from 3.26?C10 mg/kg. Vertical distribution of arsenic in both groundwater and sediments shows that maximum As concentration (462 mg/l in groundwater and 10 mg/kg in sediments) occurs at a depth of 24 m. In January 2008, 2009 and 2010, maximum As concentration occurs at the same depth. Environmental scanning electron microscope (ESEM) with EDAX was used to investigate the presence of major and trace elements in the sediments. The dominant groundwater type is Ca-HCO₃ with high concentrations of As and Fe, but with low levels of NO₃ ^? and SO₃ ^?2. Statistical analysis clearly shows that As is closely associated with Fe (R² = 0.64) and Mn (R² = 0.91) in sediments while As is not correlated with Fe and Mn in groundwater samples. Comparatively low Fe and Mn concentrations in some groundwater, suggest that probably siderite and/or rhodochrosite precipitated as secondary mineral on the surface of the sediment particles. The correlations along with results of sequential leaching experiments suggest that reductive dissolution of FeOOH and MnOOH mediated by anaerobic bacteria represents mechanism for releasing arsenic into the groundwater.     

Holocene palaeohydrological changes in the northern Mediterranean borderlands as reflected by the lake-level record of Lake Ledro,northeastern Italy

A lake-level record of Lake Ledro (northern Italy) spans the entire Holocene with a chronology derived from 51 radiocarbon dates. It is based on a specific sedimentological approach that combines data from five sediment profiles sampled in distinct locations in the littoral zone. On a millennial scale, the lake-level record shows two successive periods from 11,700 to 4500 cal yr BP and from 4500 cal yr BP to the present, characterized by lower and higher average lake levels, respectively. In addition to key seasonal and inter-hemispherical changes in insolation, the major hydrological change around 4500 cal yr BP may be related to a non-linear response of the climate system to orbitally-driven gradual decrease in insolation. The Ledro record questions the notion of an accentuated summer rain regime in the northern Mediterranean borderlands during the boreal insolation maximum. Moreover, the Ledro record highlights that the Holocene was punctuated by successive centennial-scale highstands. Correlations with the Preboreal oscillation and the 8.2 ka event, and comparison with the atmospheric ¹⁴C residual record, suggest that short-lived lake-level fluctuations developed at Ledro in response to (1) final steps of the deglaciation in the North Atlantic area and (2) variations in solar activity.     

Three-dimensional numerical simulations of the Downie Slide to test the influence of shear surface geometry and heterogeneous shear zone stiffness

Massive slow-moving landslides often exhibit deformation patterns which vary spatially across the landslide mass and temporally with changing boundary conditions. Understanding the parameters controlling this behaviour, such as heterogeneous material properties, complex landslide geometry and the distribution of groundwater, is fundamental when making informed design and hazard management decisions. This paper demonstrates that significant improvements to the geomechanical analysis of massive landslides can be achieved through rigorous, three-dimensional numerical modelling. Simulations of the Downie Slide incorporate complex shear zone geometries, multiple water tables and spatial variation of shear zone stiffness parameters to adequately reproduce real slope behaviour observed through an ongoing site monitoring program. These three-dimensional models are not hindered by shortfalls typically associated with two-dimensional analysis, for example the ability to accommodate lateral migration of material, and they out-perform more simplified three-dimensional models where bowl-shaped shear geometries are incapable of reasonably reproducing observed deformation patterns.     

Climatic Influences on Autochthonous and Allochthonous Phytoplankton Blooms in a Subtropical Estuary, St. Lucie Estuary, Florida, USA

The St. Lucie Estuary, located on the southeast coast of Florida, provides an example of a subtropical ecosystem where seasonal changes in temperature are modest, but summer storms alter rainfall regimes and external inputs to the estuary from the watershed and Atlantic Ocean. The focus of this study was the response of the phytoplankton community to spatial and temporal shifts in salinity, nutrient concentration, watershed discharges, and water residence times, within the context of temporal patterns in rainfall. From a temporal perspective, both drought and flood conditions negatively impacted phytoplankton biomass potential. Prolonged drought periods were associated with reduced nutrient loads and phytoplankton inputs from the watershed and increased influence of water exchange with the Atlantic Ocean, all of which restrict biomass potential. Conversely, under flood conditions, nutrient loads were elevated, but high freshwater flushing rates in the estuary diminished water residence times and increase salinity variation, thereby restricting the buildup of phytoplankton biomass. An exception to the latter pattern was a large incursion of a cyanobacteria bloom from Lake Okeechobee via the St. Lucie Canal observed in the summer of 2005. From a spatial perspective, regional differences in water residence times, sources of watershed inputs, and the proximity to the Atlantic Ocean influenced the composition and biomass of the phytoplankton community. Long water residence times in the North Fork region of the St. Lucie Estuary provided an environment conducive to the development of blooms of autochthonous origin. Conversely, shorter residence times in the mid-estuary limit autochthonous increases in biomass, but allochthonous sources of biomass can result in bloom concentrations of phytoplankton.     

http://www.sciencedirect.com/science/article/pii/S1674987112000631

Charnockites sensu lato（charnockite-enderbite series） are lower crustal felsic rocks typically characterised by the presence of anhydrous minerals including orthopyroxene and garnet.They either represent dry（H₂O-poor） felsic magmas that are emplaced in the lower crust or granitic intrusions that have been dehydrated during a subsequent granulite facies metamorphic event.In the first case,postmagmatic high-temperature recrystallisation may result in widespread metamorphic granulite microstructures, superimposed or replacing the magmatic microstructures.Despite recrystallisation,magmatic remnants may still be found,notably in the form of melt-related microstructures such as melt inclusions. For both magmatic charnockites and dehydrated granites,subsequent fluid-mineral interaction at intergrain boundaries during retrogradation are documented by microstructures including K-feldspar microveins and myrmekites.They indicate that a large quantity of low-H₂O activity salt-rich brines,were present（together with CO₂ under immiscible conditions） in the lower crust.     

Evaluating roadside rockmasses for rockfall hazards using LiDAR data: optimizing data collection and processing protocols

Highways and railroads situated within rugged terrain are often subjected to the hazard of rockfalls. The task of assessing roadside rockmasses for potential hazards typically involves an on-site visual investigation of the rockmass by an engineer or geologist. At that time, numerous parameters associated with discontinuity orientations and spacing, block size (volume) and shape distributions, slope geometry, and ditch profile are either measured or estimated. Measurements are typically tallied according to a formal hazard rating system, and a hazard level is determined for the site. This methodology often involves direct exposure of the evaluating engineer to the hazard and can also create a potentially non-unique record of the assessed slope based on the skill, knowledge and background of the evaluating engineer. Light Detection and Ranging (LiDAR)–based technologies have the capability to produce spatially accurate, high-resolution digital models of physical objects, known as point clouds. Mobile terrestrial LiDAR equipment can collect, at traffic speed, roadside data along highways and rail lines, scanning continual distances of hundreds of kilometres per day. Through the use of mobile terrestrial LiDAR, in conjunction with airborne and static systems for problem areas, rockfall hazard analysis workflows can be modified and optimized to produce minimally biased, repeatable results. Traditional rockfall hazard analysis inputs include two distinct, but related sets of variables related to geological or geometric control. Geologically controlled inputs to hazard rating systems include kinematic stability (joint identification/orientation) and rock block shape and size distributions. Geometrically controlled inputs include outcrop shape and size, road, ditch and outcrop profile, road curvature and vehicle line of sight. Inputs from both categories can be extracted or calculated from LiDAR data, although there are some limitations and special sampling and processing considerations related to structural character of the rockmass, as detailed in this paper.     

日晕测量与日晕光度计外缘杂散光抑制试验

为配合大型太阳设备西部选址工作,研制了一架现代日晕光度计(Sky Brightness Monitor,SBM).前期实验对日晕光度计性能进行了测试,同时积累了云南部分址点的日晕数据.资料分析结果显示,轿子雪山正午前后的日晕水平最低可至日面中心强度百万分之几的量级(蓝波段).这表明该日晕光度计内部杂散光水平已达到了国际同类产品的标准.日晕光度计的内部杂散光源主要来自两部分:镜筒前端中性滤光片(ND4)固定套圈的边缘衍射(视场靠内区域)和镜筒内置光阑的边缘衍射(视场靠外区域).针对后者进行的变换光阑孔径大小试验结果证实,适当缩小光阑孔径可有效减小数据中视场靠外区域的衍射光干扰.     

Apodized Lyot coronagraph for SPHERE/VLT: II. Laboratory tests and performance

SPHERE (which stands for Spectro-Polarimetric High-contrast Exoplanet REsearch) is a second-generation Very Large Telescope (VLT) instrument dedicated to high-contrast direct imaging of exoplanets whose first-light is scheduled for 2011. Within this complex instrument one of the central components is the apodized Lyot coronagraph (ALC). The principal aim of this paper is to report the first laboratory experiment of the ALC designed for the SPHERE instrument. The performance and sensitivity of the optical configuration was first numerically studied with an end-to-end approach (see the results in paper I subtitled ??Detailed numerical study??). Made confident by the results, we then tested a prototype on an infrared coronagraphic bench. We measured the transmission profiles of the apodizer prototype and the coronagraphic performance of the apodized Lyot coronagraph in Y, J, and H bands. The coronagraph sensitivity to lateral and longitudinal misalignments of its three main components (apodizer, coronagraphic mask and Lyot stop) was finally studied in H band. We can conclude that the prototype meets the SPHERE technical requirements for coronagraphy.     

Shock experiments in support of the Lithopanspermia theory: The influence of host rock composition,temperature, and shock pressure on the survival rate of endolithic and epilithic microorganisms

Abstract– Shock recovery experiments were performed with an explosive set‐up in which three types of microorganisms embedded in various types of host rocks were exposed to strong shock waves with pressure pulse lengths of lower than 0.5 μs: spores of the bacterium Bacillus subtilis, Xanthoria elegans lichens, and cells of the cyanobacterium Chroococcidiopsis sp. 029. In these experiments, three fundamental parameters were systematically varied (1) shock pressures ranging from 5 to 50 GPa, (2) preshock ambient temperature of 293, 233 and 193 K, and (3) the type of host rock, including nonporous igneous rocks (gabbro and dunite as analogs for the Martian shergottites and chassignites, respectively), porous sandstone, rock salt (halite), and a clay‐rich mineral mixture as porous analogs for dry and water‐saturated Martian regolith. The results show that the three parameters have a strong influence on the survival rates of the microorganisms. The most favorable conditions for the impact ejection from Mars for microorganisms would be (1) low porosity host rocks, (2) pressures <10–20 GPa, and (3) low ambient temperature of target rocks during impact. All tested microorganisms were capable of surviving to a certain extent impact ejection in different geological materials under distinct conditions.     

Hypersaline fluids generated by high-grade metamorphism of evaporites: fluid inclusion study of uranium occurrences in the Western Zambian Copperbelt

In the Pan-African Lufilian belt (Western Zambian Copperbelt), uranium mineralizations, preferentially scattered in kyanite ± talc micaschists (metamorphosed evaporitic sediments) or concentrated along transposed quartz veins provide an opportunity to (1) understand the time/space relationship between the ore minerals and the deformation of the host rocks, (2) identify the different fluid events associated with specific stages of quartz deformation and (3) characterize the ore fluid geochemistry in terms of fluid origin and fluid/rock interactions. In the U occurrences studied in Lolwa and Mitukuluku (Domes region, Western Zambian Copperbelt), two mineralizing stages are described. The first generation of ore fluids (53–59 wt% CaCl₂, 13–15 wt% NaCl; N₂–H₂ in the gas phase of fluid inclusions) circulated during the high-temperature quartz recrystallization, at 500–700 °C. This temperature is in agreement with the P–T conditions recorded during the crustal thickening related to continental collision at ca. 530 Ma. LA-ICPMS analyses show the presence of uranium within this fluid, with a concentration mode around 20 ppm. The second generation of ore fluid (21–32 wt% NaCl, 19–21 wt% CaCl₂; CO₂–CO in the gas phase of fluid inclusions) percolated at lower temperature conditions, at the brittle–ductile transition, between 200 and 300 °C. This temperature could be related to the exhumation of the high-grade metamorphic rocks at ca. 500 Ma. The formation of H₂ and CO is interpreted as the result of radiolysis in the presence of dissolved uranium in the aqueous phase of these fluid inclusions. Finally, a late fluid (14–16 wt% NaCl_equiv) circulated in the brittle domain but seems unrelated to U (re-)mobilization event.