Report on the 2007 Recertification of the Certified Reference Materials GAS (Serpentinite) and OShBO (Alkaline Granite)

A report is presented on the recertification of two certified reference materials (CRMs) initially prepared and certified by the Central Geological Laboratory of Mongolia (CGL), namely serpentinite GAS and alkaline granite OShBO. Subsequent work done in collaboration with the International Association of Geoanalysts (IAG) followed the International Organisation for Standardisation (ISO) guidelines for certification (ISO Guide 35, 2006) more closely than had been possible originally. The certification protocol followed was that of the International Association of Geoanalysts (IAG). The recertification added to the number of elements that were certified for OShBO (from 21 to 30), but not for GAS (decreased from 15 to 12) because of the greater analytical difficulties posed by that sample matrix in meeting the more stringent metrological requirements for recertification. Further, the uncertainties for these values were established in accordance with the Guide to Measurement Uncertainty ; individual contributions of heterogeneity and bias are reported as appropriate for each of the certified constituents. Traceability of the certified values was demonstrated to the greatest possible extent, based on concurrent analyses of the matrix-matched existing CRMs, SW and GM, by all participating laboratories. The materials are now available from the CGL for use by laboratories in controlling data quality when analysing materials of similar matrices.     

Occurrence of gorgosterol in diatoms of the genus Delphineis

The presence of the C₃₀ sterol gorgosterol (22,23-methylene-23,24-dimethylcholest-5-en-3ß-ol) and its analogues in some marine and freshwater environments is generally associated with invertebrate animals or dinoflagellates since there have been no reports of them in other microalgal classes. Here we show that two unialgal cultures of different species of the marine diatom Delphineis contain gorgosterol in addition to sterols more commonly found in diatoms. Our findings suggest that some reports of gorgosterol in seawater and marine sediments may well have an origin, at least in part, from diatoms.     

Chemical complexity in galaxies

ALMA will be able to detect a broad spectrum of molecular lines in galaxies. Current observations indicate that the molecular line emission from galaxies is remarkably variable, even on kpc scales. Imaging spectroscopy at resolutions of an arcsecond or better will reduce the chemical complexity by allowing regions of physical conditions to be defined and classified.     

Comment on “Comparison of the composition of the Tempel 1 ejecta to the dust in Comet C/Hale-Bopp 1995 O1 and YSO HD 100546” by C.M. Lisse, K.E. Kraemer, J.A. Nuth III, A. Li, D. Joswiak [2007. Icarus 187, 69-86]

Lisse et al. [Lisse, C.M., Kraemer, K.E., Nuth III, J.A., Li, A., Joswiak, D., 2007. Icarus 187, 69-86] recently presented a new analysis of an ISO spectrum of Comet C/1995 O1 (Hale-Bopp), from which they claimed the identification of many new dust species. Among them are PAHs, which were not found in our first analysis of the ISO spectra. We present here a re-examination of the ISO observations of Comet Hale-Bopp. From the absence of PAHs features in the 5.25-8.5 μm region, we infer that PAHs are at least twice less abundant than derived by Lisse et al. The carbonate feature at 7.00 μm is marginally present, but lower by a factor 2 to 3 than predicted by the model of Lisse et al.     

Joint altimetric and in-situ data assimilation using the GRACE mean dynamic topography: a 1993–1998 hindcast experiment in the Tropical Pacific Ocean

The altimetric satellite signal is the sum of the geoid and the dynamic topography, but only the latter is relevant to oceanographic applications. Poor knowledge of the geoid has prevented oceanographers from fully exploiting altimetric measurements through its absolute component, and applications have concentrated on ocean variability through analyses of sea level anomalies. Recent geodetic missions like CHAMP, GRACE and the forthcoming GOCE are changing this perspective. In this study, data assimilation is used to reconstruct the Tropical Pacific Ocean circulation during the 1993–1996 period. Multivariate observations are assimilated into a primitive equation ocean model (OPA) using a reduced order Kalman filter (the Singular Evolutive Extended Kalman filter). A 6-year (1993–1998) hindcast experiment is analyzed and validated by comparison with observations. In this experiment, the new capability offered by an observed absolute dynamic topography (built using the GRACE geoid to reference the altimetric data) is used to assimilate, in an efficient way, the in-situ temperature profiles from the TAO/TRITON moorings together with the T/P and ERS1&2 altimetric signal. GRACE data improves compatibility between both observation data sets. The difficulties encountered in this regard in previous studies such as Parent et al. (J Mar Syst 40–41:381–401, 2003) are now circumvented. This improvement helps provide more efficient data assimilation, as evidenced, by assessing the results against independent data. This leads in particular to significantly more realistic currents and vertical thermal structures.     

Centrifuge modelling of raked piles

Inclined piles are prohibited by many codes in seismic areas. Nevertheless the battered effect has not yet been clarified because very few data are available. The present work is a comparison, at reduced scale in the centrifuge, of the response of two simplified pile groups: a 1 × 2 vertical piles and 1 × 2 pile group with one inclined pile. Two configurations are considered: end-bearing and floating pile group, both with pile heads rigidly fixed with a massive cap. First, repeatability tests under horizontal cyclic loading were performed on both floating pile groups. Secondly, repeated horizontal impact tests were performed on both end-bearing pile groups. These impact tests, which highlight the influence of inclined piles on the inertial response of a group, are a first step for the more complex analysis of the performance of such groups under seismic loads where inertial and kinematic interactions are combined. The first part of this work revealed the influence of sand structure around the inclined pile tip on the repeatability of the tests performed on floating pile groups. The second part highlighted differences in the dynamic response between the two end-bearing pile groups through measurements of the pile cap acceleration, the bending moment profile and the axial load in the piles.     

The compatibility of erosion data at different temporal scales

Soil erosion processes have been studied intensively throughout the last decades and rates have been measured at the plot scale as well as at larger scales. However, the relevance of this knowledge for the modelling of long-term landscape evolution remains a topic of considerable debate. Some authors state that measurements of current rates are irrelevant to landscape evolution over a longer time span, as they are inconsistent with some fundamental characteristics of landscapes, such as the fact that the long-term sediment delivery ratio needs to be equal to 1 and that extrapolation of current rates would imply that all soils in Europe should have disappeared by now (e.g. Parsons, A.J., Wainwright, J., Brazier, R.E., Powell, D.M., 2006. Is sediment delivery a fallacy? Earth Surface Processes and Landforms 31, 1325–1328). In this study, we investigate if and to what extent estimates of long-term erosion rates are consistent with information obtained over much shorter time spans for the Loam Belt of Belgium.In a first step, observed short-term and long-term patterns in the Belgian loess area are compared statistically by classifying the study area into landscape element classes and comparing average erosion values per class. This analysis shows that the erosion intensities on the two temporal scales are of the same order of magnitude for each landscape element class. Next, the spatially distributed model WaTEM LT (Water and Tillage Erosion Model Long Term) is calibrated based on the available short-term data by optimising average erosion values for the same landscape element classes. Finally, the calibrated model is used to simulate long-term landform evolution, and is validated using long-term data based on soil profile truncation. We found that the model allows simulating landscape evolution on a millennial time scale using information derived from short-term erosion and deposition data. However, it is important that land use is taken into account for the calibration in order to obtain realistic patterns on a longer time scale. Our analysis shows that, at least for the study area considered, data obtained on erosion and deposition rates over various temporal scales have the same orders of magnitude, thereby demonstrating that measurements of current rates of processes can be highly relevant for interpreting long-term landscape evolution.     

Containerisation in the ports of Northern and Western Europe

This paper examines some of the contemporary features of containerisation at the ports of Northern and Western Europe. Ports are having to adjust to a wide range of forces, both local and global. Enhanced competition between ports is shaping developments. Ports have to keep pace with technological developments and thus there are great pressures to expand their facilities. In addition, links with hinterland markets have to be improved and extended. The paper demonstrates that these pressures are being felt throughout the port system, and through a series of individual and regional examples the dynamism of the European port system is exposed. This revised version was published online in July 2006 with corrections to the Cover Date.     

Deuterium, lithium and the density of the Universe

The main outcome of the primordial nucleosynthesis is the ability to account for the abundances of D, ³He, ⁴He and ⁷Li with the proper choice of the nuclear density parameter ω_B. The relative advantages/disadvantages of D and ⁷Li as the proper `baryometer' are discussed. In favour of D, the main arguments are the relative simplicity of the formation/destruction schema, but this is challenged by the large uncertainties on the choice of its actual `primordial' abundance and on the galactic evolution scheme. In favour of ⁷Li there are the confirmation of the so called `Spite plateau' and the observation of ⁶Li at the surface of at least one (may be two) Population II stars, but the paucity of such stars such as the possibility of scenarios in which the ⁷Li abundance could be affected even in these stars cannot be overlooked. This revised version was published online in July 2006 with corrections to the Cover Date.