Difference in petrophysical properties between foliated and dilatant fault rocks in deeply buried clastics: The case of the Grès d'Annot Formation,SW French Alps

This study describes normal fault zones formed in foreland arkosic turbidites (the Grès d'Annot Formation, SW French Alps) under deep diagenesis conditions (~200 °C) and highlights the occurrence of two markedly different fault‐rock types: (1) the foliated fault rocks of the Moutière‐Restefond area; and (2) the dilatant fault rocks of the Estrop area. The deformation of (1) is dominated by intra‐ and transgranular fracturing, pressure solution of quartz and feldspar grains and syn‐kinematic phyllosilicate precipitation resulting from feldspar alteration. The combination of these mechanisms results in a strongly anisotropic strain with intense shortening normal to the foliation (pressure solution) and extension parallel to the foliation (quartz‐ and calcite‐sealed extension veins). This deformation implies local mass transfer that may be achieved without (or with limited) volume change. The deformation of (2) is expressed as dilatant quartz‐sealed veins and breccia textures in which the main mechanisms are transgranular fracturing and quartz precipitation. Type (2) implies fault volume increase, isotropy of deformation and mass transfer at distances larger than in type (1). This study discusses the origins of (1) and (2) and shows that the permeability of (1) is anisotropic, with higher values than the host rocks parallel to the Y main deformation axis (i.e. perpendicular to the slip vector), whereas the permeability of (2) is isotropic and equivalent to that of the host rocks.     

Neogene upper‐crustal cooling of the Olympus range (northern Aegean): major role of Hellenic back‐arc extension over propagation of the North Anatolia Fault Zone

The North Anatolian Fault Zone (NAFZ) is one of the most hazardous active faults on Earth, yet its Pliocene space‐time propagation across the north Aegean domain remains poorly constrained. We use low‐temperature multi‐thermochronology and inverse thermal modelling to quantify the cooling history of the upper crust across the Olympus range. This range is located in the footwall of a system of normal faults traditionally interpreted as resulting from superposed Middle–Late Miocene N–S stretching, related to the back‐arc extension of the Hellenic subduction zone, and a Pliocene‐Quaternary transtensional field, attributed to the south‐westward propagation of the NAFZ. We find that accelerated exhumational cooling occurred between 12 and 6 Ma at rates of 15–35 °C Ma^?1 and decreased to <3 °C Ma^?1 by 8–6 Ma. The absence of significant Plio‐Pleistocene cooling across Olympus suggests that crustal exhumation there is driven by late Miocene back‐arc extension, while the impact of the NAFZ remains limited.     

Modeling the environmental susceptibility of landfill sites in California

??The proper management of solid waste (SW) is a global environmental challenge. A major issue is the proper disposal of SW while balancing a wide range of criteria and working with different spatial data. In this study, we used geographic information system as a tool to perform multi-criteria decision analysis with an analytical hierarchy process to develop an environmental impact susceptibility model (EISM) for landfills. The model was applied to the state of California, USA and results are presented herein. In particular, the EISM considers factors such as geology, pedology, geomorphology, water resources, and climate as represented by 13 associated environmental indicators. The results of the EISM indicate that more than 75% of California’s territory is situated in areas with very low, low, and medium environmental impact susceptibility categories. However, in the remaining 25% of the state’s land, 61 landfills are located in the high and very high categories. These results are alarming because during the period from 2000 to 2015, these 61 landfills received approximately 308 million tons of SW, which corresponds to more than 57% of all SW disposed in California. The model results can be used toward mitigating the environmental impacts of these facilities.     

Post‐breakup burial and exhumation of the southern margin of Africa

Despite many years of study, the processes involved in the development of the continental margin of southern Africa and the distinctive topography of the hinterland remain poorly understood. Previous thermochronological studies carried out within a monotonic cooling framework have failed to take into account constraints provided by Mesozoic sedimentary basins along the southern margin. We report apatite fission track analysis and vitrinite reflectance data in outcrop samples from the Late Jurassic to Early Cretaceous sedimentary fill of the Oudtshoorn, Gamtoos and Algoa Basins (Uitenhage Group), as well as isolated sedimentary remnants further west, plus underlying Paleozoic rocks (Cape Supergroup) and Permian‐Triassic sandstones from the Karoo Supergroup around the Great Escarpment. Results define a series of major regional cooling episodes. Latest Triassic to Early Jurassic cooling which began between 205 and 180 Ma is seen dominantly in basement flanks to the Algoa and Gamtoos Basins. This episode may have affected a wider region but in most places any effects have been overprinted by later events. The effects of Early Cretaceous (beginning between 145 and 130 Ma) and Early to mid‐Cretaceous (120–100 Ma) cooling are both delimited by major structures, while Late Cretaceous (85–75 Ma) cooling appears to have affected the whole region. These cooling events are all interpreted as dominantly reflecting exhumation. Higher Late Cretaceous paleotemperatures in samples from the core of the Swartberg Range, coupled with evidence for localised Cenozoic cooling, are interpreted as representing Cenozoic differential exhumation of the mountain range. Late Cretaceous paleotemperatures between 60°C and 90°C in outcropping Uitenhage Group sediments from the Oudtshoorn, Gamtoos and Algoa Basins require burial by between 1.2 and 2.2 km prior to Late Cretaceous exhumation. Because these sediments lie in depositional contact with underlying Paleozoic rocks in many places, relatively uniform Late Cretaceous paleotemperatures across most of the region, in samples of both basin fill and underlying basement, suggest the whole region may have been buried prior to Late Cretaceous exhumation. Cenozoic cooling (beginning between 30 and 20 Ma) is focussed mainly in mountainous regions and is interpreted as representing denudation which produced the modern‐day relief. Features such as the Great Escarpment are not related to continental break up, as is often supposed, but are much younger (post‐30 Ma). This history of post‐breakup burial and subsequent episodic exhumation is very different from conventional ideas of passive margin evolution, and requires a radical re‐think of models for development of continental margins.     

The journey to work: a century of change

Summary The paper uses original quantitative and qualitative evidence to examine changes in the distance travelled and time spent on the journey to work in twentieth-century Britain. Emphasis is placed on variations by gender and location, and on the implications of modal change. We suggest that analysis of past commuting trends may have implications for contemporary transport policy.     

Accumulation in Svalbard glaciers deduced from ice cores with nuclear tests and Chernobyl reference layers

Mean net annual balance and the related spatio-temporal variations have been determined on the basis of well-dated artificial layers in shallow ice cores (Chernobyl, 1986, and atmospheric thermonuclear tests, mainly in 1961-62 in Novaya Zemlya). Seventy ice cores from 13 Svalbard glaciers have been analysed. On each glacier, in its accumulation area and at the highest elevation, one ice core was recovered down to about 40 m and sampled for radioactivity measurements to determine the 1986 and 1962-63 layer (1954 was the initial date of the nuclear tests). For each glacier, at least five complementary ice cores from the accumulation area were analysed to determine the Chernobyl reference layer. Six ice cores exhibit both the Chernobyl and nuclear tests layers and are of special interest in this study.
This work provides new data on the deposition rates of natural and artificial radioisotopes. Using ice cores samples from the Arctic glaciers, even with superimposed ice accumulation, it is possible to distinguish between the Chernobyl and the nuclear tests fallouts. This work also shows that the mean annual net balance did not significantly change for at least five ice core locations in the Svalbard glaciers for the two periods extending from 1963 to 1986 to the recent date of drilling.     

An Interpretation of ISO Guidelines for the Certification of Geological Reference Materials

Recommendations for the certification of reference materials, as published by the International Organisation for Standardisation (ISO), are reviewed and proposals made as to how they can be adapted for the certification of new geological reference materials. Whilst acknowledging the important contribution made by the large number of existing matrix-matched geological reference materials, it is recommended that future characterisation programmes should follow the ISO guidelines for certification, not the least so that laboratories can readily use the resultant samples to establish the traceability of geoanalytical results.     

Oxygen isotope constraints on the petrogenesis of the Sybille intrusion of the Proterozoic Laramie Anorthosite Complex

The origin of monzonitic intrusions that are associated with Proterozoic massif-type anorthosite complexes is controversial. A detailed oxygen isotope study of the Sybille intrusion, a monzonitic intrusion of the Laramie Anorthosite Complex (Wyoming), indicates that either derivation from a basaltic magma of mantle origin with a metasedimentary component (∼20%) incorporated early in its magmatic history, or a partial melt of lower crustal rocks is consistent with the data. The oxygen isotope compositions of plagioclase, pyroxene and zircon from the Sybille monzosyenite, the dominant rock type in the Sybille intrusion, were analyzed in order to establish the isotopic composition of the source of the magma. Plagioclase δ¹⁸O values range from 6.77 to 9.17‰. We interpret the higher plagioclase δ¹⁸O values (average 8.69 ± 0.30‰, n = 19) to be magmatic in origin, lower plagioclase δ¹⁸O values (average 7.51 ± 0.44‰, n = 22) to be the result of variable subsolidus alteration, and pyroxene δ¹⁸O values (average 6.34 ± 0.38‰, n = 19) to be the result of closed-system diffusional exchange during cooling. Low magnetic zircons, which have been shown to retain magmatic oxygen isotope values despite high grade metamorphism and extensive subsolidus hydrothermal alteration, have δ¹⁸O values (7.40 ± 0.24‰, n = 11) which are consistent with our interpretation of the plagioclase and pyroxene results. Oxygen isotope data from all three minerals indicate that the magmatic oxygen isotope composition of the Sybille intrusion is enriched in ¹⁸O relative to the composition of average or “normal” mantle-derived magmas. This enrichment is approximately twice the oxygen isotope enrichment that could result from closed-system fractionation, rendering a closed-system, comag- matic petrogenetic model between the Sybille intrusion and the mantle-derived anorthositic lithologies of the Laramie Anorthosite Complex improbable. Received: 7 April 1998 / Accepted: 19 January 1999     

Compression studies of gibbsite and its high-pressure polymorph

Various X-ray diffraction methods have been applied to study the compression behavior of gibbsite, Al(OH)₃, in diamond cells at room temperature. A phase transformation was found to take place above 3 GPa where gibbsite started to convert to its high-pressure polymorph. The high-pressure (HP) phase is quenchable and coexists with gibbsite at the ambient conditions after being unloaded. This HP phase was identified as nordstrandite based on the diffraction patterns obtained at room pressure by angle dispersive and energy dispersive methods. On the basis of this structural interpretation, the bulk modulus of the two polymorphs, i.e., gibbsite and nordstrandite, could be determined as 85 ± 5 and 70 ± 5 GPa, respectively, by fitting a Birch-Murnaghan equation to the compression data, assuming their K_o ^′ as 4. Molar volume cross-over occurs at 2 GPa, above which the molar volume of nordstrandite is smaller than that of gibbsite. The differences in the molar volume and structure between the two polymorphs are not significant, which accounts for the irreversibility of the phase transition. In gibbsite, the axial compressibility behaves as c/c _o > a/a _o > b/b _o. This is due to the fact that the dioctahedral sheets along the c-axis are held by the relatively weak hydrogen bonding, which results in the greater compressibility along this direction. In nord- strandite, the axial compressibility is b/b _o > c/c _o > a/a _o, which can also be interpreted as resulting from the the existence of hydrogen bonds along the b-axis. Received: 28 September 1998 / Revised, accepted: 22 December 1998