Low‐energy helium ion irradiation‐induced amorphization and chemical changes in olivine: Insights for silicate dust evolution in the interstellar medium

Abstract— We present the results of irradiation experiments aimed at understanding the structural and chemical evolution of silicate grains in the interstellar medium. A series of He+ irradiation experiments have been performed on ultra‐thin olivine, (Mg,Fe)₂SiO₄, samples having a high surface/volume (S/V) ratio, comparable to the expected S/V ratio of interstellar dust. The energies and fluences of the helium ions used in this study have been chosen to simulate the irradiation of interstellar dust grains in supernovae shock waves. The samples were mainly studied using analytical transmission electron microscopy. Our results show that olivine is amorphized by low‐energy ion irradiation. Changes in composition are also observed. In particular, irradiation leads to a decrease of the atomic ratios O/Si and Mg/Si as determined by x‐ray photoelectron spectroscopy and by x‐ray energy dispersive spectroscopy. This chemical evolution is due to the differential sputtering of atoms near the surfaces. We also observe a reduction process resulting in the formation of metallic iron. The use of very thin samples emphasizes the role of surface/volume ratio and thus the importance of the particle size in the irradiation‐induced effects. These results allow us to account qualitatively for the observed properties of interstellar grains in different environments, that is, at different stages of their evolution: chemical and structural evolution in the interstellar medium, from olivine to pyroxene‐type and from crystalline to amorphous silicates, porosity of cometary grains as well as the formation of metallic inclusions in silicates.     

AGB Phase Transition in Globular Clusters: A Tool for Dating Starbursts

A new method to detect and study young star clusters is presented. This is based on the knowledge that the light of stellar populations with ages between ∼ 200 Myr and ∼ 1/2 Gyr is dominated by very red, bright AGB stars. Star clusters undergoing this so-called ‘AGB phase transition’ are featured by very red V-K colours, like those of Magellanic Clouds clusters, while optical colours like B-V remain blue typical for young populations. The best channel for detecting star clusters in this age range is therefore the near IR. From the theoretical side, SSP models including properly the contribution of the bright AGB are required (Maraston, 1998). Using this strategy, we succesfully detected the AGB phase transition among the clusters of the merger remnant galaxy NGC 7252 (see Maraston etal., 2001). This revised version was published online in September 2006 with corrections to the Cover Date.     

Primordial noble gases in a graphite‐metal inclusion from the Canyon Diablo IAB iron meteorite and their implications

Abstract— We have carried out noble gas measurements on graphite from a large graphite‐metal inclusion in Canyon Diablo. The Ne data of the low‐temperature fractions lie on the mixing line between air and the spallogenic component, but those of high temperatures seem to lie on the mixing line between Ne‐HL and the spallogenic component. The Ar isotope data indicate the presence of Q in addition to air, spallogenic component and Ar‐HL. As the elemental concentration of Ne in Q is low, we could not detect the Ne‐Q from the Ne data. On the other hand, we could not observe Xe‐HL in our Xe data. As the Xe concentration and the Xe/Ne ratio in Q is much higher than that in the HL component, it is likely that only the contribution of Q is observed in the Xe data. Xenon isotopic data can be explained as a mixture of Q, air, and “El Taco Xe.” The Canyon Diablo graphite contains both HL and Q, very much like carbonaceous chondrites, retaining the signatures of various primordial noble gas components. This indicates that the graphite was formed in a primitive nebular environment and was not heated to high, igneous temperatures. Furthermore, a large excess of ¹²⁹Xe was observed, which indicates that the graphite was formed at a very early stage of the solar system when ¹²⁹I was still present. The HL/Q ratios in the graphite in Canyon Diablo are lower than those in carbonaceous chondrites, indicating that some thermal metamorphism occurred on the former. We estimated the temperature of the thermal metamorphism to about 500–600 °C from the difference of thermal retentivities of HL and Q. It is also noted that “El Taco Xe” is commonly observed in many IAB iron meteorites, but its presence in carbonaceous chondrites has not yet been established.     

Peak metamorphic temperatures in type 6 ordinary chondrites: An evaluation of pyroxene and plagioclase geothermometry

Abstract— Quantifying the peak temperatures achieved during metamorphism is critical for understanding the thermal histories of ordinary chondrite parent bodies. Various geothermometers have been used to estimate equilibration temperatures for chondrites of the highest metamorphic grade (type 6), but results are inconsistent and span hundreds of degrees. Because different geothermometers and calibration models were used with different meteorites, it is unclear whether variations in peak temperatures represent actual ranges of metamorphic conditions within type 6 chondrites or differences in model calibrations. We addressed this problem by performing twopyroxene geothermometry, using QUILF95, on the same type 6 chondrites for which peak temperatures were estimated using the plagioclase geothermometer (Nakamuta and Motomura 1999). We also calculated temperatures for published pyroxene analyses from other type 6 H, L, and LL chondrites to determine the most representative peak metamorphic temperatures for ordinary chondrites. Pyroxenes record a narrow, overlapping range of temperatures in H6 (865–926 °C), L6 (812–934 °C), and LL6 (874–945 °C) chondrites. Plagioclase temperature estimates are 96–179 °C lower than pyroxenes in the same type 6 meteorites. Plagioclase estimates may not reflect peak metamorphic temperatures because chondrule glass probably recrystallized to plagioclase prior to reaching the metamorphic peak. The average temperature for H, L, and LL chondrites (～900 °C), which agrees with previously published oxygen isotope geothermometry, is at least 50 °C lower than the peak temperatures used in current asteroid thermal evolution models. This difference may require minor adjustments to thermal model calculations.     

Northwest Africa 11024—A heated and dehydrated unique carbonaceous (CM) chondrite

Based on the high abundance of fine‐grained material and its dark appearance, NWA 11024 was recognized as a CM chondrite, which is also confirmed by oxygen isotope measurements. But contrary to known CM chondrites, the typical phases indicating aqueous alteration (e.g., phyllosilicates, carbonates) are missing. Using multiple analytical techniques, this study reveals the differences and similarities to known CM chondrites and will discuss the possibility that NWA 11024 is the first type 3 CM chondrite. During the investigation, two texturally apparent tochilinite–cronstedtite intergrowths were identified within two thin sections. However, the former phyllosilicates were recrystallized to Fe‐rich olivine during a heating event without changing the textural appearance. A peak temperature of 400–600 °C is estimated, which is not high enough to destroy or recrystallize calcite grains. Thus, calcites were never constituents of the mineral paragenesis. Another remarkable feature of NWA 11024 is the occurrence of unknown clot‐like inclusions (UCLIs) within fine‐grained rims, which are unique in this clarity. Their density and S concentration are significantly higher than of the surrounding fine‐grained rim and UCLIs can be seen as primary objects that were not formed by secondary alteration processes inside the rims. Similarities to chondritic and cometary interplanetary dust particles suggest an ice‐rich first‐generation planetesimal for their origin. In the earliest evolution, NWA 11024 experienced the lowest degree of aqueous alteration of all known CM chondrites and subsequently, a heating event dehydrated the sample. We suggest to classify the meteorite NWA 11024 as the first type 3 CM chondrite similar to the classification of CV3 chondrites (like Allende) that could also have lost their matrix phyllosilicates by thermal dehydration.     

The Gyldén‐type problem revisited: More refined analytical solutions

We resume and consistently extend our previous researches concerning the Gyldén‐type problem (a two‐body problem with time‐dependent equivalent gravitational parameter). To approach most of the concrete astronomical situations to be modelled in this way, we consider a periodic small perturbation. For the nonresonant case, we present a second‐order analytical solution. For the resonant case, we adopt the most realistic astronomical situation: only one dominant term of the Hamiltonian. In this case we point out a fundamental model of resonance, common to every resonant situation, and, moreover, identical to the first fundamental model of resonance . Considering the simplest model of periodic change of the equivalent gravitational parameter, we .nd that all possible resonances are con.ned to the first fundamental model. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Planetary theories with the aid of the expansions of elliptic functions

For coplanar circular orbits, the mutual perturbations between two bodies can be expressed in term of the argument of Jacobian elliptic functions instead of the difference of the mean longitudes. For a given pair of planets, such a change of time variable improves the convergence of the developments. At the first order of planetary masses an integration of Lagrange's equations for the osculating elements is performed. When compared to classical developments the results are reduced by an important factor. The method is then extended to the mutual perturbations of Jupiter and Saturn, at any order of planetary masses, either with Fourier series with two arguments, or with one argument solely, taking advantage of the close commensurability of the mean motions.     

Lunar motion: Theory and observations

Results of several fits of the lunar theory ELP 2000-82B and of Moons' theory of libration are presented. The theories are fitted both to JPL numerical integrations and to LLR observations     

Combining shock barometry with numerical modeling: Insights into complex crater formation—The example of the Siljan impact structure (Sweden)

Siljan, central Sweden, is the largest known impact structure in Europe. It was formed at about 380 Ma, in the late Devonian period. The structure has been heavily eroded to a level originally located underneath the crater floor, and to date, important questions about the original size and morphology of Siljan remain unanswered. Here we present the results of a shock barometry study of quartz‐bearing surface and drill core samples combined with numerical modeling using iSALE. The investigated 13 bedrock granitoid samples show that the recorded shock pressure decreases with increasing depth from 15 to 20 GPa near the (present) surface, to 10–15 GPa at 600 m depth. A best‐fit model that is consistent with observational constraints relating to the present size of the structure, the location of the downfaulted sediments, and the observed surface and vertical shock barometry profiles is presented. The best‐fit model results in a final crater (rim‐to‐rim) diameter of ~65 km. According to our simulations, the original Siljan impact structure would have been a peak‐ring crater. Siljan was formed in a mixed target of Paleozoic sedimentary rocks overlaying crystalline basement. Our modeling suggests that, at the time of impact, the sedimentary sequence was approximately 3 km thick. Since then, there has been around 4 km of erosion of the structure.