Dynamic characteristics and horizontal transports of internal solitons generated at the Columbia River plume front

River plume front-generated internal solitons play an important role in the interaction between the plume and coastal waters. The internal solitons drive a non-harmonic velocity field, resulting in a horizontal transport that carries plume water seaward and redistributes nutrients and sediments. In this study, we present observations of internal solitons generated at the Columbia River plume front that separates the new, tidal plume, older plume and coastal waters. Scale analyses suggest that the plume front-generated internal solitons are highly non-linear waves, and their dynamic properties do not conform to any weakly non-linear theory. Thus, a high-order Korteweg–de Vries (KdV) theory is used to analyze the internal solitons. The comparison between theoretical values and cruise data shows that the high-order KdV model is much better than the weakly non-linear theories for prediction of the soliton dynamic parameters. Based on the model, we develop theoretical and numerical solutions of the soliton-induced upper layer horizontal transport and Lagrangian water parcel transport distance, which shows that the water particle drift, during the internal soliton passage, is as far as 1 km, and demonstrates the role of the internal solitons on the exchange between the plume and ambient coastal water. Energy fluxes caused by the internal solitons are estimated using the high-order KdV theory. The leading soliton fluxes 2.0×10³ W m⁻¹ per unit crest length, and carries energy of 4.2×10⁵ J m⁻¹. The total energy carried by the eight internal solitons is 1.6×10⁶ J m⁻¹, about 70% of the total frontal energy.     

Carbon dioxide segregation in 1:4 and 1:9 CO2:H2O ices

The mid-infrared spectra of mixed vapor deposited ices of CO₂ and H₂O were studied as a function of both deposition temperature and warming from 15 to 100 K. The spectra of ices deposited at 15 K show marked changes on warming beginning at 60 K. These changes are consistent with CO₂ segregating within the ice matrix into pure CO₂ domains. Ices deposited at 60 and 70 K show a greater degree of segregation, as high as 90% for 1:4 CO₂:H₂O ice mixtures deposited at 70 K. As the ice is warmed above 80 K, preferential sublimation of the segregated CO₂ is observed. The kinetics of the segregation process is also examined. The segregation of the CO₂ as the ice is warmed corresponds to temperatures at which the structure of the water ice matrix changes from the high density amorphous phase to the low density amorphous phase. We show how these microstructural changes in the ice have a profound effect on the photochemistry induced by ultraviolet irradiation. These experimental results provide a framework in which observations of CO₂ on the icy bodies of the outer Solar System can be considered.     

Regional Considerations of Coastline Change,Tsunami Damage and Recovery along the Southern Coast of the Bay of Izmit (The Kocaeli (Turkey) Earthquake of 17 August 1999)

Co-seismic phenomena along the south coastline included liquefaction, subsidenceand tsunami. Construction on areas composed of fluvial and alluvial sediments aswell as unconsolidated fill increased the risk by creating potential for amplificationof seismic waves. Cyclic mobility liquefaction was common along the coastline, andlevel-ground liquefaction was observed. Flow liquefaction is held forth as a possibilityin the Deirmendere submarine landslide. Damage to structures was markedly more in areas of unconsolidated sediments. One or more tsunami struck immediately after the event; the uniformity of tsunami impact indicating a wave coming from 310° suggests that submarine faulting was the major source of tsunami. Over 800,000 m² of subsidence resulted from sediment slumping, fault controlled subsidence, and possibly post-liquefaction sediment compaction. After a brief period of post-event abandonment, reclamation and use of coastal areas is well underway. This creates a tension between human desires pushing for quick and inexpensive re-inhabitation of the coastal areas, and the needs for zoning and building codes for risk reduction. In this high-risk area suchcontrary cultural mandates cannot yield ideal results. It is suggested that an alternativemodel of immediate post-event creation of parks and natural areas that would yield benefit is preferable in coastal areas rather than the enforcement approach currently favored.     

Elasticity of antigorite,seismic detection of serpentinites,and anisotropy in subduction zones

Serpentinization of the mantle wedge is an important process that influences the seismic and mechanical properties in subduction zones. Seismic detection of serpentines relies on the knowledge of elastic properties of serpentinites, which thus far has not been possible in the absence of single-crystal elastic properties of antigorite. The elastic constants of antigorite, the dominant serpentine at high-pressure in subduction zones, were measured using Brillouin spectroscopy under ambient conditions. In addition, antigorite lattice preferred orientations (LPO) were determined using an electron back-scattering diffraction (EBSD) technique. Isotropic aggregate velocities are significantly lower than those of peridotites to allow seismic detection of serpentinites from tomography. The isotropic V_P/V_S ratio is 1.76 in the Voigt–Reuss–Hill average, not very different from that of 1.73 in peridotite, but may vary between 1.70 and 1.86 between the Voigt and Reuss bonds. Antigorite and deformed serpentinites have a very high seismic anisotropy and remarkably low velocities along particular directions. V_P varies between 8.9 km s^? 1 and 5.6 km s^? 1 (46% anisotropy), and 8.3 km s^? 1 and 5.8 km s^? 1 (37%), and V_S between 5.1 km s^? 1 and 2.5 km s^? 1 (66%), and 4.7 km s^? 1 and 2.9 km s^? 1 (50%) for the single-crystal and aggregate, respectively. The V_P/V_S ratio and shear wave splitting also vary with orientation between 1.2 and 3.4, and 1.3 and 2.8 for the single-crystal and aggregate, respectively. Thus deformed serpentinites can present seismic velocities similar to peridotites for wave propagation parallel to the foliation or lower than crustal rocks for wave propagation perpendicular to the foliation. These properties can be used to detect serpentinite, quantify the amount of serpentinization, and to discuss relationships between seismic anisotropy and deformation in the mantle wedge. Regions of high V_P/V_S ratios and extremely low velocities in the mantle wedge of subduction zones (down to about 6 and 3 km.s^?1 for V_P and V_S, respectively) are difficult to explain without strong preferred orientation of serpentine. Local variations of anisotropy may result from kilometer-scale folding of serpentinites. Shear wave splittings up to 1–1.5 s can be explained with moderately thick (10–20 km) serpentinite bodies.     

Determination of land degradation causes in Tongyu County,Northeast China via land cover change detection

Tongyu County in Northeast China is highly prone to land degradation due to its fragile physical settings characterized by a flat topography, a semi-arid climate, and a shallow groundwater table. This study aims to determine the causes of land degradation through detecting the long-term trend of land cover changes. Degraded lands were mapped from satellite images recorded in 1992 and 2002. These land cover maps revealed that the area subject to land degradation in the form of soil salinization, waterlogging and desertification increased from 2400 to 4214 km², in sharp contrast to most severely degraded land that decreased by 122.5 km². Newly degraded land stems from productive farmland (263 km²), harvested farmland (551 km²), and grassland (468 km²). Therefore, the worsened degradation situation is attributed to excessive reclamation of grassland for farming, over cultivation, overgrazing, and deforestation. Mechanical, biological, ecological and engineering means should be adopted to rehabilitate the degraded land.     

Two methods for pore network of porous media

Two approaches of generating pore networks of porous media are presented to capture the pore fabric. The first methodology extracted pore structure from a computer simulated packing of spheres. The modified Delaunay tessellation was used to describe the porous media, and modified Nelder–Mead method in conjunction with three pore‐merging algorithms was used to generate the pore size and coordination number distributions of the randomly packed spheres. The Biconical Abscissa Asymmetric CONcentric bond was used to describe the connection between two adjacent voids. This algorithm was validated by predicting pore structure of a cubic array of spheres of equal radius with known pore sizes, throat sizes and coordination number distributions. The predicted distributions of pore structure agreed well with the measured. Then, the algorithm was used to predict pore structure and permeability of randomly packed spherical particles, and predicted permeability values were compared with published experimental data. The results showed that the predicted permeability values were in good agreement with those measured, confirming the proposed algorithm can capture the main flow paths of packed beds. The second methodology generated an equivalent pore network of porous media, of which the centers of voids were located in a regular lattice with constant pore center distance. However, this network allowed for matching both main geometrical and topological characteristics of the porous media. A comparison of the two approaches suggested that the second approach can also be used as a predictive tool to quantitatively study the microscopic properties of flow through porous media. Copyright © 2012 John Wiley & Sons, Ltd.     

An experimental study of magnesium-isotope fractionation in chlorophyll-a photosynthesis

Measurements are presented of the magnesium isotopic composition of chlorophyll-a, extracted from cyanobacteria, relative to the isotopic composition of the culture medium in which the cyanobacteria were grown. Yields of 50-93% chlorophyll-a were achieved from the pigment extracts of Synechococcus elongatus, a unicellular cyanobacteria. This material was then digested using concentrated nitric acid to extract magnesium. Separation was accomplished using columns of cation-exchange resin, which achieved a 103 ± 10% yield of magnesium from chlorophyll-a. This procedure ensured accurate measurement of the magnesium-isotopic ratios without isobaric interferences using a multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS). We find a slight depletion in the heavier isotopes of magnesium in chlorophyll-a relative to culture medium, early growth phase: Δ²⁶Mg = −0.71(±0.35)‰ and Δ²⁵Mg = −0.37(±0.18)‰; late growth phase: Δ²⁶Mg = −0.53(±0.20)‰ and Δ²⁵Mg = −0.26(±0.11)‰, due to an apparent mass-dependent fractionation. We suggest that the small fractionation results from chelation during intracellular processes. A likely candidate for this chelation step involves the magnesium-chelatase enzyme, which mediates the insertion of magnesium to the tetrapyrrole ring during chlorophyll-a biosynthesis. Proof of this hypothesis can be tested with biological controls whereby steps in the enzymatic pathways of chlorophyll synthesis are selectively suppressed.     

Soil characterization based on land cover heterogeneity over a tropical landscape: an integrated approach using earth observation data-sets

Soil is a vital part of the natural environment and is always responding to changes in environmental factors, along with the influences of anthropogenic factors and land use changes. The long-term change in soil properties will result in change in soil health and fertility, and hence the soil productivity. Hence, the main aim of this paper focuses on the analysis of land use/land cover (LULC) change pattern in spatial and temporal perspective and to present its impact on soil properties in the Merawu catchment over the period of 18?years. Post classification change detection was performed to quantify the decadal changes in historical LULC over the periods of 1991, 2001 and 2009. The pixel to pixel comparison method was used to detect the LULC of the area. The key LULC types were selected for investigation of soil properties. Soil samples were analysed in situ to measure the physicochemical soil properties. The results of this study show remarkable changes in LULC in the period of 18?years. The effect of land cover change on soil properties, soil compaction and soil strength was found to be significant at a level of <0.05.     

Using gravity and topography-implied anomalies to assess data requirements for precise geoid computation

Many regions around the world require improved gravimetric data bases to support very accurate geoid modeling for the modernization of height systems using GPS. We present a simple yet effective method to assess gravity data requirements, particularly the necessary resolution, for a desired precision in geoid computation. The approach is based on simulating high-resolution gravimetry using a topography-correlated model that is adjusted to be consistent with an existing network of gravity data. Analysis of these adjusted, simulated data through Stokes’s integral indicates where existing gravity data must be supplemented by new surveys in order to achieve an acceptable level of omission error in the geoid undulation. The simulated model can equally be used to analyze commission error, as well as model error and data inconsistencies to a limited extent. The proposed method is applied to South Korea and shows clearly where existing gravity data are too scarce for precise geoid computation.     

东北地区农业结构转型时期土地利用变化的成因与效应

During the last decade of the 20th century, extensive conversion in agricultural land use took place in Northeast China. The goal of this study is to ascertain its spatial distribution and regional differentiation, determine its causes, and analyze its environmental impact, Especially we attempt to elucidate how institutional constraints have facilitated the change at a time of agrarian restructuring when newly emerging free market was hybridized with the former planned economy. Information on six categories of land use was mapped from interpretation of Landsat TM images recorded in 1990,1995 and 2000. Most of land use changes took place during the first half of the decade, coinciding with abrupt and chaotic changes in government directives. Farmland was changed mainly to woodland,water body and built-up areas while woodland and grassland were converted chiefly to farmland.Spatially, the change from farmland to woodland was restricted to the west of the study area. The change from grassland to farmland took place in the grazing and farming interlocked west. These chaotic and occasionally conflicting changes were largely caused by lack of stability and consistency in agricultural land use policies promulgated. They have exerted adverse impacts on the local environment, including land degradation, increased flooding, and modified climate regime.