Spectral observations of spicules at two heights in the solar chromosphere

An observational program at the Sacramento Peak Observatory in 1965 provided high-dispersion spectra of the solar chromosphere in several spectral regions simultaneously. These regions included various combinations of the spectral lines Hα, Hβ and H?, the D₃-line of Hei, the infrared triplet of Oi, and the H- and K-lines and the infrared triplet of Caii. With the use of an image slicer the observations were made simultaneously at two heights in the solar chromosphere separated by several thousand kilometers. From these data we draw the following conclusions:

1. Emission of different lines arises in the same chromospheric features. The intensity ratio of lines of different elements varies significantly from spicule to spicule. For the H- and K-lines of ionized calcium, this ratio remains constant, independent of wavelength throughout the line, overall intensity, and height in the chromosphere. Two rare-earth lines in the wing of the H-line show no spicular structure at all.
2. The line-of-sight velocities of many features reverse as a function of time, although most spicules show velocities in only one direction. The simultaneous spectra at two heights show most spicules to have the same line-of-sight velocity at both. There may be an additional class of features, mostly rapidly moving, whose members have line-of-sight velocities that increase with height. These features comprise perhaps 10% of the total. Velocity changes occur simultaneously, to within 20 sec, at two heights separated by 1800 km, indicating velocities of propagation of hundreds of km/sec. The velocity field of individual features is often quite complicated; many spectral features are inclined to the direction of dispersion, implying that differential mass motions are present.
3. The existence of anomalously broad H and K profiles is real. Even with high dispersion and the best seeing, such profiles are not resolved into smaller features. The central reversal in K, H and Hα appears to remain unshifted when the wings are displaced in wavelength, indicating that the reversal is non-spicular.

     

The equation of state of Al,H-bearing SiO2 stishovite to 58 GPa

We have determined the P-V equation of state of Al-rich H-bearing SiO₂ stishovite by X-ray powder diffraction at pressures up to 58 GPa using synchrotron radiation. The sample contained 1.8 wt% Al₂O₃ and up to 500 ppm H₂O, and had a composition that would coexist with Mg-silicate perovskite in a subducted slab. By fitting a third-order Birch-Murnaghan equation of state to our compression data, we obtained a bulk modulus K _T0=298(7) GPa with K′=4.3(5). With K′ fixed to a value of 4, the bulk modulus K _T0=304(3) GPa. Our results indicate that Al³⁺ and H⁺ have a small effect on the elastic properties of stishovite. Compared with data obtained up to 43.8 GPa, peak intensities changed and we observed a decreased quality of fit to a tetragonal unit cell at pressures of 49 GPa and higher. These changes may be an indication that the rutile↔CaCl₂ transition occurs between these pressures. After laser annealing of the sample at 58.3(10) GPa and subsequent decompression to room conditions, the cell volume is the same as before compression, giving strong evidence that the composition of the recovered sample is also unchanged. This suggests that Al and H are retained in the sample under extreme P-T conditions and that stishovite can be an agent for transporting water to the deepest lower mantle.     

Chemical composition of the graphitic black carbon fraction in riverine and marine sediments at sub-micron scales using carbon X-ray spectromicroscopy

The chemical composition of the graphitic black carbon (GBC) fraction of marine organic matter was explored in several marine and freshwater sedimentary environments along the west coast of North America and the Pacific Ocean. Analysis by carbon X-ray absorption near-edge structure spectroscopy and scanning transmission X-ray microscopy shows the GBC fraction of Stillaguamish River surface sediments to be dominated by more highly ordered and impure forms of graphite, together forming about 80% of the GBC, with a smaller percent of an aliphatic carbon component. Eel River Margin surface sediments had very little highly ordered graphite, and were instead dominated by amorphous carbon and to a lesser extent, impure graphite. However, the GBC of surface sediments from the Washington State Slope and the Mexico Margin was composed almost solely of amorphous carbon. Pre-anthropogenic, highly oxidized deep-sea sediments from the open Equatorial Pacific Ocean contained over half their GBC in different forms of graphite as well as highly aliphatic carbon, low aromatic/highly acidic aliphatic carbon, low aromatic/highly aliphatic carbon, and amorphous forms of carbon. Our results clearly show the impact of graphite and amorphous C phases in the BC fraction in modern riverine sediments and nearby marine shelf deposits. The pre-anthropogenic Equatorial Pacific GBC fraction is remarkable in the existence of highly ordered graphite.     

A seismic retrofit method by connecting viscous dampers for microelectronics factories

The implementation of viscous dampers to microelectronics factories has been previously proved not to affect the micro‐vibration of the factories in operation so that the vibration‐sensitive manufacturing process will not be interfered. Therefore, a seismic retrofit strategy which employs the viscous dampers installed in between the exterior and interior structures of the ‘fab’ structure is proposed in the study. The design formulas corresponding to the proposed retrofit method are derived using the non‐proportional damping theory. Based on the study, it is found that the added damping ratio to the fab structure depends greatly on the frequency ratio of the two structures in addition to the damping coefficients of the added dampers. Outside the bandwidth of the frequency ratio in which the added damping ratio is very sensitive to the variation of the frequency ratio, the added damping ratio can be well captured using the classical damping theory. Copyright © 2007 John Wiley & Sons, Ltd.     

Limitations of ‘Rock-Eval’ pyrolysis for typing organic matter

Laboratory experimentation on whole-rock ‘Rock-Eval’ pyrolysis has shown that the characterization of organic matter through the use of a modified van Krevelen diagram, in which the hydrogen and oxygen indices are substituted for the atomic H/C and O/C ratios, produces questionable results. The hydrogen and oxygen indices have been found to be strongly affected by both matrix mineralogy and level of organic enrichment. It appears, therefore, that although the modified van Krevelen diagram maybe useful for tracing evolutionary pathways as organic matter matures, it can be very misleading when used to assess kerogen type.     

Die Ultrabasitmassive im Präkambrium des Staates Goiäs/Brasilien

The Brazilian state of Goiás and parts of Mato Grosso represent the centre of the Brazilian shield, between the Guaporé craton in the west and the São Francisco craton in the east. In contrast to opinions before, early Precambrian gneisses and migmatites form only small parts of the shield complex whereas middle and late Precambrian sequences dominate. From tectonic position, an eugeosynclinal central zone can be distinguished accompanied by younger miogeosynclinal series to the east and west. The ultrabasic massifs of Goiás can be differentiated into following types:

1. alpinotype serpentinised dunites and peridotites,
2. gabbro-pyroxenite-peridotite associations,
3. pyroxenite-metagabbro associations,
4. dunite-pyroxenite-alkalisyenite associations,
5. lamprophyre dykes.

Nos. 1, 2 and 3 are of Precambrian age whereas 4 and 5 are surely of post-Devonian, probably of Cretaceous age and can be attributed to the phase of Paraná volcanism. The most economic types at the moment (Nos. 1 and 2) yield Ni, Cu and Co in lateritic enrichment, Cr, Pt and related elements as primary constituents. Latest, the types 4 and 5 cause special interest. From their association with carbonatites they are related to the Araxá complex of Minas Gerais and anticipate mineralizations of Nb, Ta, Ti and P.     

Climate change and energy security: an analysis of policy research

The literature on climate change’s impacts on energy security is scattered across disparate fields of research and schools of thought. Much of this literature has been produced outside of the academy by scholars and practitioners working in “think tanks,” government agencies, and international/multilateral institutions. Here we reviewed a selected set of 58 articles and reports primarily from such sources and performed textual analysis of the arguments. Our review of this literature identifies three potential mechanisms for linking climate change and energy security: Climate change may 1) create second-order effects that may exacerbate social instability and disrupt energy systems; 2) directly impact energy supply and/or systems or 3) influence energy security through the effects of climate-related policies. We identify emerging risks to energy security driven by climate mitigation technology choices but find less evidence of climate change’s direct physical impacts. We used both empirical and qualitative selection factors for choosing the grey literature sample. The sources we selected were published in the last 5 years, available through electronic media and were written in language accessible to general policy or academic readers. The organizations that published the literature had performed previous research in the general fields of energy and/or climate change with some analytical content and identified themselves as non-partisan. This literature is particularly valuable to scholars because identifies understudied relationships that can be rigorously assessed through academic tools and methodologies and informs a translational research agenda that will allow scholars to engage with practitioners to address challenges that lie at the nexus of climate change and energy security.     

A Framework for Quantitative Assessment of Impacts Related to Energy and Mineral Resource Development

Natural resource planning at all scales demands methods for assessing the impacts of resource development and use, and in particular it requires standardized methods that yield robust and unbiased results. Building from existing probabilistic methods for assessing the volumes of energy and mineral resources, we provide an algorithm for consistent, reproducible, quantitative assessment of resource development impacts. The approach combines probabilistic input data with Monte Carlo statistical methods to determine probabilistic outputs that convey the uncertainties inherent in the data. For example, one can utilize our algorithm to combine data from a natural gas resource assessment with maps of sage grouse leks and piñon-juniper woodlands in the same area to estimate possible future habitat impacts due to possible future gas development. As another example: one could combine geochemical data and maps of lynx habitat with data from a mineral deposit assessment in the same area to determine possible future mining impacts on water resources and lynx habitat. The approach can be applied to a broad range of positive and negative resource development impacts, such as water quantity or quality, economic benefits, or air quality, limited only by the availability of necessary input data and quantified relationships among geologic resources, development alternatives, and impacts. The framework enables quantitative evaluation of the trade-offs inherent in resource management decision-making, including cumulative impacts, to address societal concerns and policy aspects of resource development.