The use of soft X-ray spectromicroscopy to investigate the distribution and composition of organic matter in a diatom frustule and a biomimetic analog

Diatoms play a significant role in the global carbon cycle through their role in biogenic silica production and the transport of organic matter to the seafloor. Recent work has shown that silicified diatom frustules contain a significant amount of organic matter, and that the proportion of diatom-bound organic matter increases with depth in the water column and sediments. Here, we investigate the association between organic matter and the mineral phase. We used a combination of scanning transmission X-ray microscopy (STXM) and carbon X-ray absorption near-edge structure (XANES) spectroscopy to characterize the distribution and composition of organic matter in frustules of the diatom Cylindrotheca closterium and a biomimetic silica gel. To our knowledge, this study represents the first successful attempt to simultaneously image and obtain chemical information about the organic matter within a diatom frustule using X-ray spectromicroscopy near the carbon edge. Organic carbon, most likely protein, was distributed throughout the frustules and was not removed by harsh chemical treatment. The physical structure of the frustules appeared to be related to the chemical composition of this organic matter, with aromatic or unsaturated carbon being concentrated in the most intricately patterned regions of the frustule. A similar physical and chemical structure was observed in a biomimetic silica gel precipitated spontaneously with polylysine. These results are consistent with the theory that organic constituents of diatom frustules direct silica precipitation and become incorporated within the silica matrix as it forms. The relationship between organic matter composition and silica morphology, the failure of harsh chemical treatments to remove this organic matter, and the spontaneous nature of the co-precipitation of silica and organic matter indicate some chemical interaction between the siliceous and organic components of diatom frustules. Frustule-bound organic matter should therefore be protected from decomposition in the water column or diagenetic alteration in sediments unless the frustule dissolves.     

稠油的成因、预测和深水开采——AAPG和AMGP稠油研讨会的回顾和技术摘要

美国石油地质学家学会（AAPG）联合墨西哥石油地质协会（AMGF）于2006年10月8～10日在Veracruz、Mexica召开了题为“稠油：成因、预测和深水开采”的海德伯研讨会。来自世界各地的90位地质科学家和工程师参加了会议。     

Sources and transport of suspended particulates in the Caribbean Sea

Gravimetric and light-scattering studies of total suspended matter reveal that the bulk of this material is introduced into the Caribbean through the passages of the Lesser Antilles, most likely the result of discharge of the Amazon and Orinoco Rivers. A broad suspended-matter high extends northward from the South American coast, apparently related to northward advection at the confluence of the westward-moving Caribbean Current and an easterly coastal countercurrent off Colombia. Particulate matter distribution may be accounted for by transport from the northern and eastern sills, with resuspension in the deep basins playing a minor role. Localized concentrations appear to be entering through the Greater Antillean sills, and then are carried westward by the prevailing currents.     

Distribution, condition, and growth of newly settled southern flounder (Paralichthys lethostigma) in the Galveston Bay Estuary, TX

Several flatfish species, including southern flounder (Paralichthys lethostigma) recruit to estuaries during early life. Therefore, evaluation of estuarine sites and habitats that serve as nurseries is critical to conservation and management. The present study used density data in conjunction with biochemical condition and growth measurements to evaluate settlement sites used by southern flounder in the Galveston Bay Estuary (GBE). In 2005, beam-trawl collections were made in three major sections of the GBE (East Bay, Galveston Bay, West Bay). Three sites were sampled in each bay. Within each sampling site, replicate collections were taken from three habitats: 1) marsh edge (< 1 m depth), 2) intermediate zone (10–20 m from marsh interface;  1 m depth), and 3) bay zone (typically > 100 m from marsh interface; depth > 1 m). Average size of southern flounder collected was 12–19 mm standard length, and peak densities occurred in January and February. Catch data indicated that densities of southern flounder were significantly greater in East Bay (2.75 per 100 m²) than in Galveston Bay (0.91 per 100 m²) or in West Bay (0.45 per 100 m²). Densities were statistically similar among habitats. Otolith-based estimates of age indicated that the majority of southern flounder collected were 35–45 days old and derived from early December to early January hatch-dates. Growth rates were similar among bays and among habitats, with the average growth rate being 0.40 mm day^− 1 (range: 0.21–0.76 mm day^− 1). RNA:DNA was above the established baseline value for nutritional stress, indicating that newly settled southern flounder in the GBE were in relatively high condition. Habitat-specific differences in RNA:DNA ratios were not observed; however, ratios were significantly lower in West Bay (average 8.0) than in East Bay (average 9.5) or in Galveston Bay (average 9.8), suggesting the condition of new recruits may vary spatially within the GBE. Findings from the current study suggest density and condition of newly settled southern flounder vary at the bay scale, suggesting that parts of GBE do not function equally as nurseries.     

Phenology-based delineation of irrigated and rain-fed paddy fields with Sentinel-2 imagery in Google Earth Engine

Paddy rice agriculture is practiced in both rain-fed and irrigated ecosystems in the Philippines. However, small farms are prevalent in the region, and current ...     

High-frequency coronal oscillations and coronal heating

At the 1980 total solar eclipse, we searched for high-frequency (0.1–2 Hz) oscillations in the intensity of the 5303-Å coronal green line, as a test of predictions of theories of coronal heating via magnetohydrodynamic waves. Portions of the image 2.5- or 5-arc sec across were fed to cooled photomultipliers using fiber-optic probes. We detected excess power in Fourier transforms of the data for the region between 0.5 and 2 Hz at the level of 1% or 2% of the incident power. Such oscillations could be associated with Alfvén waves that are trapped on loops a few thousand kilometers long or with fast waves that are trapped on loops a few thousand kilometers in diameter. Additional observations at the 1983 eclipse are planned to resolve atmospheric and instrumental contributions.     

Methane absorption in the Jovian atmosphere I. The Lorentz half-width in the 3v3 band at 1.1 μm

The Lorentz half-width α_L, of the fine-structure components of the methane 3v₃R-branch in the Jovian spectrum has been measured from photoelectric observations of the singlet R(1). A value of α_L = 0.088_?0.011^+0.015Å, or 0.072_?0.009+0.009 cm^?1, has been found. Curves of growth for the 3v₃R-branch manifolds have been calculated, using the measured value of α_L and assuming a reflecting-layer atmosphere. The Walker-Hayes (1967) equivalent widths have been reanalyzed for rotational temperature and methane abundance. The half-width derived here is significantly different from a similar measurement made by C. B. Farmer (1969). The source of the discrepancy remains obscure.