The P-wave velocity structure of Deception Island,Antarctica, from two-dimensional seismic tomography

Deception Island is a volcanic island with a flooded caldera that has a complex geological setting in Bransfield Strait, Antarctica. We use P-wave arrivals recorded on land and seafloor seismometers from airgun shots within the caldera and around the island to invert for the P-wave velocity structure along two orthogonal profiles. The results show that there is a sharp increase in velocity to the north of the caldera which coincides with a regional normal fault that defines the northwestern boundary of the Bransfield Strait backarc basin. There is a low-velocity region beneath the caldera extending from the seafloor to > 4 km depth with a maximum negative anomaly of 1 km/s. Refracted arrivals are consistent with a 1.2-km-thick layer of low-velocity sediments and pyroclastites infilling the caldera. Synthetic inversions show that this layer accounts for only a small portion of the velocity anomaly, implying that there is a significant region of low velocities at greater depths. Further synthetic inversions and melt fraction calculations are consistent with, but do not require, the presence of an extensive magma chamber beneath the caldera that extends downwards from ≤ 2 km depth.     

Eruptive style of the young high-Mg basaltic-andesite Pelagatos scoria cone,southeast of México City

The eruption of the Pelagatos scoria cone in the Sierra Chichinautzin monogenetic field near the southern suburbs of Mexico City occurred less than 14,000 years ago. The eruption initiated at a fissure with an effusive phase that formed a 7-km-long lava flow, and continued with a phase of alternating and/or simultaneous explosive and effusive activity that built a 50-m-high scoria cone on the western end of the fissure and formed a compound lava flow-field near the vent. The eruption ended with the emplacement of a short lava flow that breached the cone and was accompanied by weak explosions at the crater. Products consist of a microlite-rich high-Mg basaltic andesite. Samples were analyzed to determine the magma’s initial properties as well as the effects of degassing-induced crystallization on eruptive style. Although distal ash fallout deposits from this eruption are not preserved, a recent quarry exposes a large section of the scoria cone. Detailed study of exposed layers allows us to elucidate the mode of cone-building activity. Petrological and textural data, combined with models calibrated by experimental work and melt-inclusion analyses of similar magmas elsewhere, indicate that the magma was initially hot (>1,200°C), gas-rich (up to 5 wt.% H₂O), crystal-poor (~10 vol.% Fo₉₀ olivine phenocrysts) and thus poorly viscous (40–80 Pa s). During the early phase, low magma ascent velocity at the fissure vent allowed low-viscosity magma to degas and crystallize during ascent, producing lava flows with elevated crystal contents at T < 1,100°C, and blocky surfaces. Later, the closure of the fissure by cooling dikes focused the magma flow at a narrow section of the fissure. This led to an increased magma ascent velocity. Rapid and shallow degassing (<3 km deep) triggered ~40 vol.% microlite crystallization. Limited times for gas-escape and higher magma viscosity (6 × 10⁵–4 × 10⁶ Pa s) drove strong explosions of highly (60–80 vol.%) and finely vesicular magma. Coarse clasts broke on landing, which implies brittle behavior due to complete solidification. This requires sufficient time to cool and in turn implies ejection heights of over 1 km, which is much higher than “normal” Strombolian activity. Hence, magma viscosity significantly impacts eruption style at monogenetic volcanoes because it affects the kinetics of shallow degassing. The long-lasting eruptions of Jorullo and Paricutin, which produced similar magmas in western México, were more explosive. This can be related to higher magma fluxes and total erupted volumes. Implications of this study are important because basaltic andesites are commonly erupted to form monogenetic scoria cones of the Trans-Mexican Volcanic Belt.     

Soil moisture dynamics at high temporal resolution in a semiarid Mediterranean watershed with scattered tree cover

Subsurface water flows play a key role in the distribution of water and solutes and thereby in the water availability for plants. However, the characterization of different flow processes (i.e. matrix and preferential flow), the frequency and factors that cause them, is relatively rare. This characterization enables a better understanding of spatio‐temporal variability of water resources and allows for the design of models to be improved. Using a method based on the time derivative of soil moisture variation known as maximum wetting slope, types of soil wetting processes were classified and quantified. For this, capacitance sensors, which registered the volumetric water content at high temporal resolution (30 min) for more than two hydrological years, were installed at different depths and placed in soil moisture stations with different vegetation covers, lithology and topographic position. Results indicated that there is a general behaviour or pattern of soil moisture dynamics in the catchment with a dominant occurrence of slower soil wetting processes (>50%), caused by matrix flows, and a low occurrence of those faster processes (<30%), originated by preferential flows. Nevertheless, when the total volume of water is considered, preferential flow becomes the dominant process, so that the ecological role of both flow types becomes prominent in water‐limited environments. Statistical multivariate analyses based on data‐mining techniques proved that although both flow types depend on variables associated with precipitation and antecedent soil moisture conditions, faster soil wetting processes are mainly related to variables such as rainfall intensity and topography, while slower soil wetting processes are related to flow velocity, soils or vegetation. Copyright © 2015 John Wiley & Sons, Ltd.     

Spatial distribution of phytoplankton cells in small elongated lakes subject to weak diurnal wind forcing

The horizontal distribution of phytoplankton in a medium-size canyon type reservoir, forced by weak winds of 3–4 ms^?1, is largely driven by the interaction of the large-scale circulation and processes regulating the vertical distribution of algal cells in the water column. These drivers, in turn, are subject to diurnal variations, making our understanding of the horizontal distribution of phytoplankton a challenging task. A three-dimensional physical-–ecological model is used to understand the spatial distribution of algae and the role of diurnal variations in the physical–biological drivers. The model was used to demonstrate that the large-scale circulation induced during the day is more efficient generating patchiness than the circulation existing at night, when convectively driven turbulence homogenizes the upper layers. Different spatial distributions develop for different populations and under different forcing scenarios, characterized in terms of the directionality of wind forcing, wind magnitude and the lags between winds and diel heat fluxes. The time scales needed so that algal biomass in the surface exhibit significant longitudinal gradients—T _P —will vary depending on the algal group, and its ability to regulate its vertical position. These scales are shorter for those species that either migrate actively in the water column or exhibit positive buoyancy (Cryptophytes or Positive buoyant algae). In El Gergal, these scales T _P are on the order of a few days. Synoptic changes in the meteorological forcing, like the passing of a front, could potentially change the longitudinal distribution of algal biomass if they persist for periods of time longer than T _P .     

Weathering phases recorded by gnammas developed since last glaciation at Serra da Estrela, Portugal

The morphometrical analysis of gnammas (weathering pits) in granite landscapes has been used to establish the relative chronology of recent erosive surfaces and to provide the weathering history in a region. To test the validity of gnammas as relative chronometer indicators, and the reliability of the obtained weathering record, two sites have been studied in Serra da Estrela, Portugal. The first site is within the limits of the glacier that existed in these mountains during the last glaciation, whereas the second site is located in an unglaciated sector of the mountains, which preserves a longer record of weathering in the bedrock surface. The number of gnamma weathering phases recorded in the latter site (8) is larger than those from the former (6). Correlation between both measurement stations based on morphometrical criteria is excellent for the younger six weathering phases (1 to 6). Consequently, the parameter used for relative chronology (δ-value) has been verified to be age dependent, although absolute values are modulated by microclimate due to altitude variations. The weathering record was essentially duplicated once the surfaces at both sites were exposed, demonstrating the reliability of gnamma evolution as a post-glacial environmental indicator for the region.     

Architecture and development of the alluvial sediments of the Upper Jurassic Tordillo Formation in the Cañada Ancha Valley, northern Neuquén Basin, Argentina

The Upper Jurassic Tordillo Formation at Cañada Ancha area, northern Neuquén Basin, Argentina, comprises a multi-stage suit of predominantly alluvial sediments that is heterolithic in nature. In that suit, several lithofacies, architectural elements, and bounding surfaces of different order have been identified and their lateral and vertical distribution characterized. This analysis allowed the differentiation of 3 main units (lower, middle and upper), 20 subunits (C-1 to C-20), and the characterization of their alluvial styles.The lower unit (which comprises subunits C-1 to C-4) is mainly formed by fine- to medium-grained sandstones, which become medium- to coarse-grained towards the top. These sandstones characterize settings ranging from floodplains with isolated, unconfined flows, to more complex, vertically stacked, multi-storey sheet sandstones of braided fluvial systems. The middle unit (C-5 to C-10) is dominated by pale brown-grey fine-to coarse-grained sands and medium size subangular to angular conglomerates, which reflect amalgamated complexes of sandstone sheets and downstream accretion macroforms. Remarkably, this alluvial sedimentation was episodically punctuated by volcaniclastic flows. The upper unit (C-11 to C-20) consists of finer sediments, mainly pink to white fine-to medium grained sandstones and red to green siltstones. Towards the top, bioturbation becomes important, and also the presence of volcanosedimentary flows is noticeable. Fluvial settings include braided sheet sandstones with waning flood deposits evolving to isolated high-sinuosity fluvial systems, with flash flood deposits. At the top of this unit, facies may suggest marine influence.Vertical changes in the fluvial style result from both climatic and tectonic controls. A semiarid to arid climate and the active tectonism linked to the eastward migration of the Andean volcanic arc determined major bounding surfaces, fluvial style evolution and the presence of the volcano-sedimentary deposits. Different stages of high and low subsidence rates has been deduced from the vertical stacking of sediments.     

Sublacustrine hydrothermal seeps and silicification of microbial bioherms in the Ediacaran Oued Dar'a caldera,Anti‐Atlas,Morocco

This paper presents a case study of the sublacustrine precipitation of hydrothermal silica ± TiO₂ in the Ediacaran Mançour Group of the Saghro inlier, Anti‐Atlas, Morocco. Lacustrine carbonates containing stromatolitic mats and bioherms occur in ephemeral ponds developed within the Oued Da'ra caldera. Its syn‐eruptive infill consists of pyroclastites, ashflow tuffs, and subsidiary lava flows and sills, whereas inter‐eruptive deposition is mainly represented by slope‐related debris‐flow breccias and landslides, alluvial fans and fluvial channels. Carbonate production took place in a mosaic of differentially subsiding, fault‐bounded intra‐caldera blocks controlled by episodic collapse‐induced drowning, pyroclastic blanketing and migration of alluvial/fluvial environments. After microbial carbonate production, the carbonates recorded several early‐diagenetic processes, punctuated by polyphase fissuring (controlling secondary permeability) locally linked to hydrothermal influx. Three generations of carbonate cements are recognisable: (i) fibrous, botryoidal and blocky/drusy mosaics of calcite; (ii) idiotopic mosaics of dolomite caused by flushing of hypersaline Mg‐rich brines; and (iii) euhedral to drusy calcite via dedolomitization. The δ¹³C and δ¹⁸O values from carbonate cements broadly become successively isotopically lighter, as a result of meteoric and hydrothermal influence, and were probably overprinted by the Panafrican‐3 phase that affected the top of the Mançour Group. Two mechanisms of silicification are involved: (i) early‐diagenetic occlusion of interparticle pores at the sediment/water interface of pyroclastic substrates and reefal core and flanks; and (ii) hydrothermal precipitation of silica ± TiO₂ lining fissures and vuggy porosity encased in the host rock. Silica conduits cross‐cutting lacustrine mats and bioherms exhibit high potential of preservation in collapsed volcanic calderas. Primary fluid inclusions of hydrothermal silica contain brine relics with NaCl/CaCl₂ ratios of 2·1 to 4·4, representing minimum entrapment temperatures of about 142 to 204°C, and abiotic hydrocarbons (heavy alkanes) related to serpentinization of the volcanic and volcanosedimentary basement of the Oued Dar'a caldera.     

Contrasting environmental effects of astronomically driven climate change on three Eocene hemipelagic successions from the Basque–Cantabrian Basin

Several processes can contribute to the formation of hemipelagic limestone–marl alternations as a consequence of astronomically driven climate change. The aim of this study was to decipher which environmental factors governed the formation of three Eocene hemipelagic successions of the Basque–Cantabrian Basin using a comprehensive set of physical and bulk carbonate geochemical data (bed thickness, mineralogy, %CaCO₃, δ¹³C and δ¹⁸O). The results show that the significance of several environmental processes varied depending on the palaeogeographic setting and eccentricity‐modulated precessional seasonality. In the Sopelana starved deep‐sea basin, limestones were formed as a consequence of high pelagic carbonate productivity during periods of warm seawater and sluggish circulation, which corresponded with periods of low seasonality (summers at aphelion); conversely, marls accumulated when pelagic carbonate productivity decreased during periods with cooler waters and more vigorous circulation, which occurred when seasonality was higher (summers at perihelion). In the Gorrondatxe submarine fan fringe, marls accumulated when high seasonality produced significant continental rainfall and run‐off, causing the dilution of pelagic carbonate sedimentation with terrigenous supplies. In the Oyambre upper slope, marls also accumulated when seasonality was high, as pelagic carbonate productivity decreased due to both the expansion of low‐salinity waters on the ocean surface and the increase in continentally derived nutrients, which caused detrimental seawater conditions for calcareous plankton. Both in Gorrondatxe and Oyambre, limestones accumulated when boreal summer at aphelion caused low seasonality, which allowed relatively stable conditions to prevail. At minimum eccentricity, when precession‐driven seasonality contrast diminished, changes in pelagic carbonate productivity were significant in the three sections. On the contrary, at maximum eccentricity, when seasonality peaked due to summers occurring at perihelion, the effects of other environmental processes, such as continental and oceanic currents, became influential. However, the influence of these processes minimized when summertime coincided with aphelion at maximum eccentricity and seasonality was weakest.     

Influence of Organic Enrichment and <Emphasis Type="Italic">Spisula subtruncata</Emphasis> (da Costa, 1778) on Oxygen and Nutrient Fluxes in Fine Sand Sediments

The role of labile organic material and macrofaunal activity in benthic respiration and nutrient regeneration have been tested in sublittoral fine sand sediments from the Gulf of Valencia (northwestern Mediterranean Sea). Three experimental setups were made using benthic chambers. One experiment was performed in-situ through the annual cycle in a well-sorted fine sand community. The remaining experiments were carried out with mesocosms under laboratory conditions: one with different concentrations of organic enrichment (mussel meat and concentrated diatoms culture), and the other adding two different densities of the endofaunal bivalve Spisula subtruncata. Biochemical variables in surface sediment and changes in oxygen consumption and nutrient fluxes throughout incubation period were studied in each experiment. In the in situ incubations, dissolved oxygen (DO) fluxes showed a strong correlation with sedimentary biopolymeric fraction of organic carbon. Organic enrichment in the laboratory experiments was responsible for increased benthic respiration. However, sediment response (expressed as DO uptake and dissolved inorganic nitrogen—DIN—release) between oligotrophic and eutrophic conditions was more intense than between eutrophic and hypertrophic conditions. S. subtruncata abundances close to 400 and 850 ind m^?2 also intensified benthic metabolism. DO uptake and DIN production in mesocosms with added fauna were between 60 and 75 % and 65–100 % higher than in the control treatment respectively. The results of these three experiments suggest that the macrobenthic community may increase the benthic respiration by roughly a factor of two in these bottoms, where S. subtruncata is one of the dominant species. Both organic enrichment and macrobenthic community in general, and S. subtruncata in particular, did not seem to have a relevant role in P and Si cycles in these sediments.     

Cambrian–early Ordovician volcanism across the South Armorican and Occitan domains of the Variscan Belt in France: Continental break-up and rifting of the northern Gondwana margin

The Cambrian–lower Ordovician volcanic units of the South Armorican and Occitan domains are analysed in a tectonostratigraphic survey of the French Variscan Belt. The South Armorican lavas consist of continental tholeiites in middle Cambrian–Furongian sequences related to continental break-up. A significant volcanic activity occurred in the Tremadocian, dominated by crustal melted rhyolitic lavas and initial rifting tholeiites. The Occitan lavas are distributed into five volcanic phases: (1) basal Cambrian rhyolites, (2) upper lower Cambrian Mg-rich tholeiites close to N-MORBs but crustal contaminated, (3) upper lower–middle Cambrian continental tholeiites, (4) Tremadocian rhyolites, and (5) upper lower Ordovician initial rift tholeiites. A rifting event linked to asthenosphere upwelling took place in the late early Cambrian but did not evolve. It renewed in the Tremadocian with abundant crustal melting due to underplating of mixed asthenospheric and lithospheric magmas. This main tectono-magmatic continental rift is termed the “Tremadocian Tectonic Belt” underlined by a chain of rhyolitic volcanoes from Occitan and South Armorican domains to Central Iberia. It evolved with the setting of syn-rift coarse siliciclastic deposits overlain by post-rift deep water shales in a suite of sedimentary basins that forecasted the South Armorican–Medio-European Ocean as a part of the Palaeotethys Ocean.