Upward infiltration–evaporation method to estimate soil hydraulic properties

Determination of saturated hydraulic conductivity, K_s, and the van Genuchten water retention curve θ(h) parameters is crucial in evaluating unsaturated soil water flow. The aim of this work is to present a method to estimate K_s, α and n from numerical analysis of an upward infiltration process at saturation (Cap0), with (Cap0 + h) and without (Cap0) an overpressure step (h) at the end of the wetting phase, followed by an evaporation process (Evap). The HYDRUS model as well as a brute-force search method were used for theoretical loam soil parameter estimation. The uniqueness and the accuracy of solutions from the response surfaces, K_s–n, α–n and K_s–α, were evaluated for different scenarios. Numerical experiments showed that only the Cap0 + Evap and Cap0 + h + Evap scenarios were univocally able to estimate the hydraulic properties. The method gave reliable results in sand, loam and clay-loam soils.     

Dissolution of hausmannite (Mn3O4) in the presence of the trihydroxamate siderophore desferrioxamine B

That microbial siderophores may be mediators of Mn(III) biogeochemistry is suggested by recent studies showing that these well known Fe(III)-chelating ligands form very stable Mn(III) aqueous complexes. In this study, we examine the influence of desferrioxamine B (DFOB), a trihydroxamate siderophore, on the dissolution of hausmannite, a mixed valence Mn(II, III) oxide found in soils and freshwater sediments. Batch dissolution experiments were conducted both in the absence (pH 4-9) and in the presence of 100 μM DFOB (pH 5-9). In the absence of the ligand, there is a sharp decrease in the extent of proton-promoted dissolution above pH 5 and no appreciable dissolution above pH 8. The resulting aqueous Mn²⁺ activities were in good agreement with previous studies, indirectly supporting the accepted two-step mechanism involving the formation of manganite and reprecipitation of hausmannite. Desferrioxamine B enhanced hausmannite dissolution over the entire pH range investigated, both via the formation of a Mn(III) complex and through surface-catalyzed reductive dissolution. Above pH 8, non-reductive ligand-promoted dissolution dominated, whereas below pH 8, dissolution was non-stoichiometric with respect to DFOB. Concurrent proton-promoted, ligand-promoted, reductive, and induced dissolution was observed, with Mn release by either reductive or induced dissolution increasing linearly with decreasing pH. The fast kinetics of the DFOB-promoted dissolution of hausmannite, as compared to iron oxides, suggest that the siderophore-promoted dissolution of Mn(III)-bearing minerals may compete with the siderophore-promoted dissolution of Fe(III)-bearing minerals.     

High-frequency multi-solute calibration using an in situ UV–visible sensor

Monitoring the temporal variation of solute concentrations in streams at high temporal frequency can play an important role in understanding the hydrological and biogeochemical behaviour of catchments. UV–visible spectrometry is a relatively inexpensive and easily used tool to infer those concentrations in streams at high temporal resolution. However, it is not yet clear which solutes can be modelled with such an in-situ sensor. Here, we installed a UV–visible spectrometer probe (200–750 nm) in a high-altitude tropical Páramo stream to record the wavelength absorbance at a 5-min temporal resolution. For calibration, we simultaneously sampled stream water at a 4-h frequency from February 2018 to March 2019 for subsequent laboratory analysis. Absorbance spectra and laboratory-determined solute concentrations were used to identify the best calibration method and to determine which solute concentrations can be effectively inferred using in situ spectrometry through the evaluation of six calibration methods of different mathematical complexity. Based on the Nash – Sutcliffe efficiency (NSE) and Akaike information criterion metrics, our results suggest that multivariate methods always outperformed simpler strategies to infer solute concentrations. Eleven out of 21 studied solutes (Al, DOC, Ca, Cu, K, Mg, N, Na, Rb, Si and Sr) were successfully calibrated (NSE >0.50) and could be inferred using UV–visible spectrometry even with a reduced daily sampling frequency. It is worth noting that most calibrated solutes were correlated with wavelengths (WLs) in the low range of the spectra (i.e., UV range) and showed relatively good correlation with DOC. The latter suggests that estimation of metal concentrations could be possible in other streams with a high organic load (e.g., peat dominated catchments). In situ operation of spectrometers to monitor water quality parameters at high temporal frequency (sub-hourly) can enhance the protection of human water supplies and aquatic ecosystems as well as providing information for assessing catchment hydrological functioning.     

Modeling aquifer�Criver interactions under the influence of groundwater abstraction in the Mancha Oriental System (SE Spain)

The Mancha Oriental System (MOS, 7,260?km²) is one of the largest aquifers within Spain, and is encompassed by the Jucar River Basin. Over the past 30?years, socioeconomic development within the region has been largely due to intensive use of groundwater resources for irrigating crops (1,000?km²). Groundwater pumping (406 million m³/year) has provoked a steady drop in the groundwater level and a reduction of MOS discharge to the Jucar River. The study aims to characterize the river?Caquifer relationship, to determine the influence that groundwater abstraction has on the river discharge. This research has advanced a three-dimensional large-scale numerical groundwater-flow model (MODFLOW 2000) in order to spatially and temporally evaluate, quantify and predict the river?Caquifer interactions that are influenced by groundwater abstraction in MOS. It is demonstrated that although groundwater abstraction increased considerably from the early 1980s to 2000, the depletion of water stored in the aquifer was lower than might be expected. This is mainly due to aquifer recharge from the Jucar River, induced by groundwater abstraction. The area of disconnection between the river and the water table (i.e. where groundwater head is lower than the riverbed) is found to have spread 20?km downstream from its position before pumping started.     

Does physics exhibit its negation?

In this Letter we give a brief sketch of the problem of scientific knowledge as it has been elaborated by Pauli and Jung on a non-physical ground. In addition, we try to find arguments in favour of their opinion in the territory of physics. If these reasons hold indeed, then an incompatibility in space-time-matter relationship can be indicated.