Correcting lateral boundary biases in regional climate modelling: the effect of the relaxation zone

Climate Dynamics - Regional climate models (RCM) are an important tool for simulating atmospheric information at finer resolutions often of greater relevance to local scale climate change impact...     

Structure Inclination Angles in the Convective Atmospheric Surface Layer

Two-point correlations of the fluctuating streamwise velocity are examined in the atmospheric surface layer over the salt flats of Utah’s western desert, and corresponding structure inclination angles are obtained for neutral, stable and unstable conditions. The neutral surface-layer results supplement evidence for the invariance of the inclination angle given in Marusic and Heuer (Phys Rev Lett 99:114504, 2007). In an extension of those results it is found that the inclination angle changes drastically under different stability conditions in the surface layer, varying systematically with the Monin–Obukhov stability parameter in the unstable regime. The variation is parametrized and subsequently can be used to improve existing near-wall models in the large-eddy simulation of the atmospheric surface layer.     

The amino acid composition of the Sutter's Mill CM2 carbonaceous chondrite

We determined the abundances and enantiomeric compositions of amino acids in Sutter's Mill fragment #2 (designated SM2) recovered prior to heavy rains that fell April 25–26, 2012, and two other meteorite fragments, SM12 and SM51, that were recovered postrain. We also determined the abundance, enantiomeric, and isotopic compositions of amino acids in soil from the recovery site of fragment SM51. The three meteorite stones experienced terrestrial amino acid contamination, as evidenced by the low d/l ratios of several proteinogenic amino acids. The d/l ratios were higher in SM2 than in SM12 and SM51, consistent with rain introducing additional l‐ amino acid contaminants to SM12 and SM51. Higher percentages of glycine, β‐alanine, and γ‐amino‐n‐butyric acid were observed in free form in SM2 and SM51 compared with the soil, suggesting that these free amino acids may be indigenous. Trace levels of d +l‐ β‐aminoisobutyric acid (β‐AIB) observed in all three meteorites are not easily explained as terrestrial contamination, as β‐AIB is rare on Earth and was not detected in the soil. Bulk carbon and nitrogen and isotopic ratios of the SM samples and the soil also indicate terrestrial contamination, as does compound‐specific isotopic analysis of the amino acids in the soil. The amino acid abundances in SM2, the most pristine SM meteorite analyzed here, are approximately 20‐fold lower than in the Murchison CM2 carbonaceous chondrite. This may be due to thermal metamorphism in the Sutter's Mill parent body at temperatures greater than observed for other aqueously altered CM2 meteorites.     

An investigation of sand–dust storm events and land surface characteristics in China using NOAA NDVI data

Observations from 560 weather stations in China show that sand–dust storms occur most frequently in April in north China. The region consists of Sub-dry Mid Temperate, Dry Mid Temperate, Sub-dry South Temperate and Dry South Temperate Zones and much of the land surface is desert or semi-desert: it is relatively dry with minimal rainfall and a high annual mean temperature. In most regions of China, the annual mean frequency of sand–dust events decreased sharply between 1980 and 1997 and then increased from 1997 to 2000. Statistical analyses demonstrate that the frequency of sand–dust storms correlates highly with wind speed, which in turn is strongly related to land surface features; on the other hand, a significant correlation between storm events and other atmospheric quantities such as precipitation and temperature was not observed. Accordingly, land surface cover characteristics (vegetation, snowfall and soil texture) may play a significant role in determining the occurrence of sand–dust storms in China. Analysis of Normalized Difference Vegetation Index derived from National Oceanic and Atmospheric Administration and Empirical Orthogonal Function show that since 1995 surface vegetation cover in large areas of Northern China has significantly deteriorated. Moreover, a high correlation is shown to exist among the annual occurrence of sand–dust storms, surface vegetation cover and snowfall. This suggests that the deterioration of surface vegetation cover may strongly influence the occurrence of sand–dust storms in China. Soils with coarse and medium textures are found to be more associated with sand–dust storms than other soils.     

Assessment of the interstellar processes leading to deuterium enrichment in meteoritic organics

Abstract— The presence of isotopic anomalies is the most unequivocal demonstration that meteoritic material contains circumstellar or interstellar components. In the case of organic compounds in meteorites and interplanetary dust particles (IDPs), the most useful isotopic tracer has been deuterium (D). We discuss four processes that are expected to lead to D enrichment in interstellar materials and describe how their unique characteristics can be used to assess their relative importance for the organics in meteorites. These enrichment processes are low‐temperature gas phase ion‐molecule reactions, low‐temperature gas‐grain reactions, gas phase unimolecular photodissociation, and ultraviolet photolysis in D‐enriched ice mantles. Each of these processes is expected to be associated with distinct regiochemical signatures (D placement on the product molecules, correlation with specific chemical functionalities, etc.), especially in the molecular population of polycyclic aromatic hydrocarbons (PAHs). We describe these differences and discuss how they may be used to delineate the various interstellar processes that may have contributed to meteoritic D enrichments. We also briefly discuss how these processes may affect the isotopic distributions in C, O, and N in the same compounds.     

Detection of new hydrocarbons in Uranus' atmosphere by infrared spectroscopy

Ethane (C₂H₆), methylacetylene (CH₃C₂H or C₃H₄) and diacetylene (C₄H₂) have been discovered in Spitzer 10-20 μm spectra of Uranus, with 0.1-mbar volume mixing ratios of (1.0±0.1)×¹⁰⁻⁸, (2.5±0.3)×¹⁰⁻¹⁰, and (1.6±0.2)×¹⁰⁻¹⁰, respectively. These hydrocarbons complement previously detected methane (CH₄) and acetylene (C₂H₂). Carbon dioxide (CO₂) was also detected at the 7-σ level with a 0.1-mbar volume mixing ratio of (4±0.5)×¹⁰⁻¹¹. Although the reactions producing hydrocarbons in the atmospheres of giant planets start from radicals, the methyl radical (CH₃) was not found in the spectra, implying much lower abundances than in the atmospheres of Saturn or Neptune where it has been detected. This finding underlines the fact that Uranus' atmosphere occupies a special position among the giant planets, and our results shed light on the chemical reactions happening in the absence of a substantial internal energy source.     

B and V lightcurves and pole positions of three S-class asteroids

B. anb V lightcurves have been obtained for three S-class asteroids—29 Amphitrite, 39 Laetitia, and 43 Ariadne. Pole positions and shapes for each of these asteroids are derived, and comments on small features present in their lightcurves are made. A small color variation for 39 Laetitia is also found.     

Rock physics analysis for time-lapse seismic at Schiehallion Field, North Sea

Rock physics analysis plays a vital role in time‐lapse seismic interpretation because it provides the link between changes in rock and fluid properties and the resulting seismic data response. In this case study of the Schiehallion Field, we discuss a number of issues that commonly arise in rock physics analyses for time‐lapse studies. We show that:

• 1 Logarithmic fits of dry bulk (K_dry) and shear (G_dry) moduli vs. effective pressure (P_eff) are superior to polynomial fits.
• 2 2D surface fits of K_dry and G_dry over porosity (φ) and effective pressure using all the core data simultaneously are more useful and accurate than separate 1D fits over φ and P_eff for each individual core.
• 3 One average set (facies) of K_dry(φ, P_eff) and G_dry(φ, P_eff) can be chosen to represent adequately the entire Schiehallion reservoir.
• 4 Saturated velocities and densities modelled by fluid substitution of K_dry(φ, P_eff), G_dry(φ, P_eff) and the dry bulk density ρ_dry(φ) compare favourably with well‐log velocities and densities.
• 5 P‐ and S‐wave impedance values resulting from fluid substitution of K_dry(φ, P_eff), G_dry(φ, P_eff) and ρ_dry(φ) show that the largest impedance changes occur for high porosities and low effective pressures.
• 6 Uncertainties in K_dry(φ, P_eff) and G_dry(φ, P_eff) derived for individual cores can be used to generate error surfaces for these moduli that represent bounds for quantifying uncertainties in seismic modelling or pressure–saturation inversion.

     

Geochemical characteristics of crustal anatexis during the formation of migmatite at the Southern Sierra Nevada,California

We provide data on the geochemical and isotopic consequences of nonmodal partial melting of a thick Jurassic pelite unit at mid-crustal levels that produced a migmatite complex in conjunction with the intrusion of part of the southern Sierra Nevada batholith at ca. 100 Ma. Field relations suggest that this pelitic migmatite formed and then abruptly solidified prior to substantial mobilization and escape of its melt products. Hence, this area yields insights into potential mid-crustal level contributions of crustal components into Cordilleran-type batholiths. Major and trace-element analyses in addition to field and petrographic data demonstrate that leucosomes are products of partial melting of the pelitic protolith host. Compared with the metapelites, leucosomes have higher Sr and lower Sm concentrations and lower Rb/Sr ratios. The initial ⁸⁷Sr/⁸⁶Sr ratios of leucosomes range from 0.7124 to 0.7247, similar to those of the metapelite protoliths (0.7125–0.7221). However, the leucosomes have a much wider range of initial ε_Nd values, which range from −6.0 to −11.0, as compared to −8.7 to −11.3 for the metapelites. Sr and Nd isotopic compositions of the leucosomes, migmatites, and metapelites suggest disequilibrium partial melting of the metapelite protolith. Based on their Sr, Nd, and other trace-element characteristics, two groups of leucosomes have been identified. Group A leucosomes have relatively high Rb, Pb, Ba, and K₂O contents, Rb/Sr ratios (0.15<Rb/Sr<1.0), and initial ε_Nd values. Group B leucosomes have relatively low Rb, Pb, Ba, and K₂O contents, Rb/Sr ratios (<0.15), and initial ε_Nd values. The low Rb concentrations and Rb/Sr ratios of the group B leucosomes together suggest that partial melting was dominated by water-saturated or H₂O-fluxed melting of quartz + feldspar assemblage with minor involvement of muscovite. Breakdown of quartz and plagioclase with minor contributions from muscovite resulted in low Rb/Sr ratios characterizing both group A and group B leucosomes. In contrast, group A leucosomes have greater contributions from K-feldspar, which is suggested by: (1) their relatively high K concentrations, (2) positive or slightly negative Eu anomalies, and (3) correlation of their Pb and Ba concentrations with K₂O contents. It is also shown that accessory minerals have played a critical role in regulating the partitioning of key trace elements such as Sm, Nd, Nb, and V between melt products and residues during migmatization. The various degrees of parent/daughter fractionations in the Rb–Sr and Sm–Nd isotopic systems as a consequence of nonmodal crustal anatexis would render melt products with distinct isotopic signatures, which could profoundly influence the products of subsequent mixing events. This is not only important for geochemical patterns of intracrustal differentiation, but also a potentially important process in generating crustal-scale as well as individual pluton-scale isotopic heterogeneities.