Denitrification in a Deep Basalt Aquifer: Implications for Aquifer Storage and Recovery

Aquifer storage and recovery (ASR) can provide a means of storing water for irrigation in agricultural areas where water availability is limited. A concern, however, is that the injected water may lead to a degradation of groundwater quality. In many agricultural areas, nitrate is a limiting factor. In the Umatilla Basin in north central Oregon, shallow alluvial groundwater with elevated nitrate‐nitrogen of <3 mg/L to >9 mg/L is injected into the Columbia River Basalt Group (CRBG), a transmissive confined aquifer(s) with low natural recharge rates. Once recovery of the injected water begins, however, NO₃‐N in the recovered water decreases quickly to <3 mg/L (Eaton et al. 2009), suggesting that NO₃‐N may not persist within the CRBG during ASR storage. In contrast to NO₃‐N, other constituents in the recovered water show little variation, inconsistent with migration or simple mixing as an explanation of the NO₃‐N decrease. Nitrogen isotopic ratios (δ¹⁵N) increase markedly, ranging from +3.5 to > +50, and correlate inversely with NO₃‐N concentrations. This variation occurs in <3 weeks and recovery of <10% of the originally injected volume. TOC is low in the basalt aquifer, averaging <1.5 mg/L, but high in the injected source water, averaging >3.0 mg/L. Similar to nitrate concentrations, TOC drops in the recovered water, consistent with this component contributing to the denitrification of nitrate during storage.     

Could surface roughness be a poor proxy for landslide age? Results from the Swabian Alb,Germany

The potential of surface roughness to quantify geomorphological landforms and processes has been enhanced with the availability of high‐resolution digital terrain models (DTM). Recent studies that attempt to identify landslide features with surface roughness have suggested that this measure of topographic heterogeneity may also be applied to estimate the relative age of landslides. This is a provisional study that explores the potential of this relationship by assessing the ability of surface roughness to act as a proxy for relative landslide age. The surface roughness for a set of 12 dated landslides in the Swabian Alb that occurred between 1789 and 1985 was calculated from a 1 m² spatial resolution LiDAR DTM with three algorithms: root‐mean‐square‐height (RMSH), standard deviation of slope (SDS), and direction cosine eigenvalue ratios (DCE). Scale‐dependence was analysed by calculating surface roughness for a range of moving window sizes (3 × 3, 5 × 5, 9 × 9 and 15 × 15), and surface roughness for each landslide was summarized by the median and upper quartile. Only weak correlations (best Spearman's rho 0.58) were present between landslide age and surface roughness. This correlation becomes weaker with increasing moving window size. Given weak observed associations and discussed challenges pertaining to the complexities of landslide morphology change over time, we currently find that surface roughness alone may not be justifiable to act as a proxy for landslide age for our study region. Furthermore, we recommend future studies should focus on addressing possible natural and anthropogenic factors such as land use change that may alter surface roughness. These studies may focus on one of the three roughness measures used here as they are strongly correlated. Copyright © 2014 John Wiley & Sons, Ltd.     

Stream temperature response to variable glacier coverage in coastal watersheds of Southeast Alaska

We measured stream temperature continuously during the 2011 summer run‐off season (May through October) in nine watersheds of Southeast Alaska that provide spawning habitat for Pacific salmon. The nine watersheds have glacier coverage ranging from 0% to 63%. Our goal was to determine how air temperature and watershed land cover, particularly glacier coverage, influence stream temperature across the seasonal glacial meltwater hydrograph. Multiple linear regression models identified mean watershed elevation (related to glacier extent) and watershed lake coverage (%) as the strongest landscape controls on mean monthly stream temperature, with the weakest (May) and strongest (July) models explaining 86% and 97% of the temperature variability, respectively. Mean weekly stream temperature was significantly correlated with mean weekly air temperature in seven streams; however, the relationships were weak to non‐significant in the streams influenced by glacial run‐off. Streams with >30% glacier coverage showed decreasing stream temperatures with rising summer air temperatures, whereas those with <30% glacier coverage exhibited summertime warming. Glaciers also had a cooling effect on monthly mean stream temperature during the summer (July through September) equivalent to a decrease of 1.1 °C for each 10% increase in glacier coverage. The maximum weekly average temperature (an index of thermal suitability for salmon) in the six glacial streams was substantially below the lower threshold for optimum salmon growth. This finding suggests that although glaciers are important for moderating summer stream temperatures, future reductions in glacier run‐off may actually improve the thermal suitability of some glacially dominated streams in Southeast Alaska for salmon. Copyright © 2013 John Wiley & Sons, Ltd.     

Historical variability and feedbacks among land cover,stream power,and channel geometry along the lower Canadian River floodplain in Oklahoma

In 1820, the lower Canadian River meandered through a densely forested floodplain. By 1898, most of the floodplain had been cleared for agriculture and changes in channel geometry and specific stream power followed, particularly channel widening and straightening with a lower potential specific stream power. In 1964, a large upstream hydropower dam was constructed, which changed the flow regime in the lower Canadian River and consequently the channel geometry. Without destructive overbank floods, the channel narrowed rapidly and considerably due to encroachment by floodplain vegetation. The lower Canadian River, which was once a highly dynamic floodplain‐river system, has now been transformed into a relatively static river channel. These changes over the past 200 years have not been linear or independent. In this article, we use a variety of data sources to assess these historical changes along the lower Canadian River floodplain and identify feedbacks among floodplain cultivation, dam construction, specific stream power, and channel width, slope, and sinuosity. Finally, we combine the results of our study with others in the region to present a biogeomorphic response model for large Great Plains rivers that characterizes channel width changes in response to climate variability and anthropogenic disturbances. Copyright © 2011 John Wiley & Sons, Ltd.     

Out‐of‐plane seismic response of vertically spanning URM walls connected to flexible diaphragms

A simplified numerical model was used to investigate the out‐of‐plane seismic response of vertically spanning unreinforced masonry (URM) wall strips. The URM wall strips were assumed to span between two flexible diaphragms and to develop a horizontal crack above the wall mid‐height. Three degrees of freedom were used to accommodate the wall displacement at the crack height and at the diaphragm connections, and the wall dynamic stability was studied. The equations of dynamic motion were obtained using principles of rocking mechanics of rigid bodies, and the formulae were modified to include semi‐rigid wall behaviour. Parametric studies were conducted that included calculation of the wall response for different values of diaphragm stiffness, wall properties, applied overburden, wall geometry and earthquake ground motions. The results of the study suggest that stiffening the horizontal diaphragms of typical low‐rise URM buildings will amplify the out‐of‐plane acceleration demand imposed on the wall and especially on the wall–diaphragm connections. It was found that upper‐storey walls connected to two flexible diaphragms had reduced stability for applied earthquake accelerograms having dominant frequency content that was comparable with the frequency of the diaphragms. It was also found that the applied overburden reduced wall stability by reducing the allowable wall rotations. The results of this study suggest that the existing American Society of Civil Engineers recommendations for assessment of vertically spanning walls overestimate the stability of top‐storey walls in multi‐storey buildings in high‐seismic regions or for walls connected to larger period (less stiff) diaphragms. Copyright © 2015 John Wiley & Sons, Ltd.     

Dissolved inorganic carbon sourcing using δ13CDIC from a karst influenced river system

Rivers, representing the primary conduits of dissolved inorganic carbon (DIC) from the continents to the oceans, are important components to the global carbon cycle. To better understand the complex carbon cycling dynamics within two nested, mixed lithology watersheds, two sites were studied along the karst influenced upper Green River in south‐central Kentucky, USA. Weekly samples were collected from June 2013 through May 2014 and analyzed for δ¹³C_DIC. The mixing model IsoSource was employed to better understand source partitioning differences over seasonal time spans and across the two nested basins. In both the lithologically mixed upstream basin (53% carbonate rocks, 47% siliciclastic) and carbonate rock dominated downstream basin (96% carbonate rocks in the drainage area between Greensburg and Munfordville, 78% in the total area upstream from Munfordville), DIC was primarily derived from soil respiration. The proportion of DIC from dissolved carbonate minerals derived from the downstream carbonate rock dominated basin was similar to the upstream basin, due to carbonate mineral dissolution having such a consistent effect on the overall DIC content of the river. Seasonally, soil respiration provided the most DIC from fall to winter. Early spring precipitation, combined with limited seasonal photosynthesis, shifted groundwater to be the primary source of DIC, bringing in a flush of carbonate mineral‐rich water during higher flows. This study provides insight into carbon dynamics across multiple lithologies and the important influence of seasonality using carbon isotope sourcing to determine carbonate mineral dissolution variability and aid in understanding its contribution to global carbon flux quantification. Copyright © 2015 John Wiley & Sons, Ltd.     

The influence of land surface changes on regional climate in Northwest China

Land surface changes effect the regional climate due to the complex coupling of land-atmosphere interactions. From 1995 to 2000, a decrease in the vegetation density and an increase in ground-level thermodynamic activity has been documented by multiple data sources in Northwest China, including meteorological, reanalysis from European Centre for Medium-Range Weather Forecasts （ECMWF）, National Oceanic and Atmospheric Administration＇s （NOAA） Advanced Very High Resolution Radiometer （AVHRR） and TIROS Operational Vertical Sounder （TOVS） satellite remote sensing data. As the ground-level thermodynamic activity increases, humid air from the surrounding regions converge toward desert （and semi-desert） regions, causing areas with high vegetation cover to become gradually more arid. Furthermore, land surface changes in Northwest China are responsible for a decrease in total cloud cover, a decline in the fraction of low and middle clouds, an increase in high cloud cover （due to thermodynamic activity） and other regional climatic adaptations. It is proposed that, beginning in 1995, these cloud cover changes contributed to a ＂green- house＂ effect, leading to the rapid air temperature increases and other regional climate impacts that have been observed over Northwest China.     

Growth modelling indicates hurricanes and severe storms are linked to low coral recruitment in the Caribbean

This study set out to test the hypothesis that hurricanes and tropical storms limit the recruitment and subsequent survival of massive non-branching corals on the barrier reef off the coast of Belize in the Gulf of Honduras. Overall, the surface areas of 523 individual coral specimens were measured, and recruitment dates were then modelled. There was no significant difference in coral cover or coral biodiversity between any of the sites studied (p > 0.1). There were significant differences in non-branching coral recruitment in years when hurricanes impacted the area (p < 0.05) compared with years when no hurricanes impacted the area. There were significantly more non-branching massive corals recruited in non-hurricane years (mean 7.7) than in hurricane years (mean 3.8; p = 0.011). When years with tropical storms are added to the years with hurricanes, there was significantly lower coral recruitment (mean 4.7) relative to non-storm or hurricane years (mean 7.4; p = 0.019). These results show that hurricanes and severe storms limited the recruitment and survival of massive non-branching corals of the Mesoamerican barrier reef and on patch reefs near the Belize coast in the Caribbean, and suggests that marine park managers may need to assist coral recruitment in years where there are hurricanes or severe storms.     

The benefits of climate change mitigation in integrated assessment models: the role of the carbon cycle and climate component

Integrated Assessment Models (IAMs) are an important tool to compare the costs and benefits of different climate policies. Recently, attention has been given to the effect of different discounting methods and damage estimates on the results of IAMs. One aspect to which little attention has been paid is how the representation of the climate system may affect the estimated benefits of mitigation action. In that respect, we analyse several well-known IAMs, including the newest versions of FUND, DICE and PAGE. Given the role of IAMs in integrating information from different disciplines, they should ideally represent both best estimates and the ranges of anticipated climate system and carbon cycle behaviour (as e.g. synthesised in the IPCC Assessment reports). We show that in the longer term, beyond 2100, most IAM parameterisations of the carbon cycle imply lower CO₂ concentrations compared to a model that captures IPCC AR4 knowledge more closely, e.g. the carbon-cycle climate model MAGICC6. With regard to the climate component, some IAMs lead to much lower benefits of mitigation than MAGICC6. The most important reason for the underestimation of the benefits of mitigation is the failure in capturing climate dynamics correctly, which implies this could be a potential development area to focus on.     

Coupling of anatectic reactions and dissolution of accessory phases and the Sr and Nd isotope systematics of anatectic melts from a metasedimentary source

Advances in field observations and experimental petrology on anatectic products have motivated us to investigate the geochemical consequences of accessory mineral dissolution and nonmodal partial melting processes. Incorporation of apatite and monazite dissolution into a muscovite dehydration melting model allows us to examine the coupling of the Rb-Sr and Sm-Nd isotope systems in anatectic melts from a muscovite-bearing metasedimentary source. Modeling results show that (1) the Sm/Nd ratios and Nd isotopic compositions of the melts depend on the amount of apatite and monazite dissolved into the melt, and (2) the relative proportion of micas (muscovite and biotite) and feldspars (plagioclase and K-feldspar) that enter the melt is a key parameter determining the Rb/Sr and ⁸⁷Sr/⁸⁶Sr ratios of the melt. Furthermore, these two factors are not, in practice, independent. In general, nonmodal partial melting of a pelitic source results in melts following one of two paths in ε_Nd-⁸⁷Sr/⁸⁶Sr ratio space. A higher temperature, fluid-absent path (Path 1) represents those partial melting reactions in which muscovite/biotite dehydration and apatite but not monazite dissolution play a significant role; the melt will have elevated Rb/Sr, ⁸⁷Sr/⁸⁶Sr, Sm/Nd, and ε_Nd values. In contrast, a lower temperature, fluid-fluxed path (Path 2) represents those partial melting reactions in which muscovite/biotite dehydration plays an insignificant role and apatite but not monazite stays in the residue; the melt will have lower Rb/Sr, ⁸⁷Sr/⁸⁶Sr, Sm/Nd, and ε_Nd values than its source. The master variables controlling both accessory phase dissolution (and hence the Sm-Nd system), and melting reaction (and hence the Rb-Sr systematics) are temperature and water content. The complexity in Sr-Nd isotope systematics in metasediment-derived melts, as suggested in this study, will help us to better understand the petrogenesis for those granitic plutons that have a significant crustal source component.