Distribution of aliphatic amines in CO,CV, and CK carbonaceous chondrites and relation to mineralogy and processing history

The analysis of water‐soluble organic compounds in meteorites provides valuable insights into the prebiotic synthesis of organic matter and the processes that occurred during the formation of the solar system. We investigated the concentration of aliphatic monoamines present in hot acid water extracts of the unaltered Antarctic carbonaceous chondrites, Dominion Range (DOM) 08006 (CO3) and Miller Range (MIL) 05013 (CO3), and the thermally altered meteorites, Allende (CV3), LAP 02206 (CV3), GRA 06101 (CV3), Allan Hills (ALH) 85002 (CK4), and EET 92002 (CK5). We have also reviewed and assessed the petrologic characteristics of the meteorites studied here to evaluate the effects of asteroidal processing on the abundance and molecular distributions of monoamines. The CO3, CV3, CK4, and CK5 meteorites studied here contain total concentrations of amines ranging from 1.2 to 4.0 nmol g^?1 of meteorite; these amounts are 1–3 orders of magnitude below those observed in carbonaceous chondrites from the CI, CM, and CR groups. The low‐amine abundances for CV and CK chondrites may be related to their extensive degree of thermal metamorphism and/or to their low original amine content. Although the CO3 meteorites, DOM 08006 and MIL 05013, do not show signs of thermal and aqueous alteration, their monoamine contents are comparable to those observed in moderately/extensively thermally altered CV3, CK4, and CK5 carbonaceous chondrites. The low content of monoamines in pristine CO carbonaceous chondrites suggests that the initial amounts, and not asteroidal processes, play a dominant role in the content of monoamines in carbonaceous chondrites. The primary monoamines, methylamine, ethylamine, and n‐propylamine constitute the most abundant amines in the CO3, CV3, CK4, and CK5 meteorites studied here. Contrary to the predominance of n‐ω‐amino acid isomers in CO3 and thermally altered meteorites, there appears to be no preference for the larger n‐amines.     

The amino acid composition of the Sutter's Mill CM2 carbonaceous chondrite

We determined the abundances and enantiomeric compositions of amino acids in Sutter's Mill fragment #2 (designated SM2) recovered prior to heavy rains that fell April 25–26, 2012, and two other meteorite fragments, SM12 and SM51, that were recovered postrain. We also determined the abundance, enantiomeric, and isotopic compositions of amino acids in soil from the recovery site of fragment SM51. The three meteorite stones experienced terrestrial amino acid contamination, as evidenced by the low d/l ratios of several proteinogenic amino acids. The d/l ratios were higher in SM2 than in SM12 and SM51, consistent with rain introducing additional l‐ amino acid contaminants to SM12 and SM51. Higher percentages of glycine, β‐alanine, and γ‐amino‐n‐butyric acid were observed in free form in SM2 and SM51 compared with the soil, suggesting that these free amino acids may be indigenous. Trace levels of d +l‐ β‐aminoisobutyric acid (β‐AIB) observed in all three meteorites are not easily explained as terrestrial contamination, as β‐AIB is rare on Earth and was not detected in the soil. Bulk carbon and nitrogen and isotopic ratios of the SM samples and the soil also indicate terrestrial contamination, as does compound‐specific isotopic analysis of the amino acids in the soil. The amino acid abundances in SM2, the most pristine SM meteorite analyzed here, are approximately 20‐fold lower than in the Murchison CM2 carbonaceous chondrite. This may be due to thermal metamorphism in the Sutter's Mill parent body at temperatures greater than observed for other aqueously altered CM2 meteorites.     

Coronal holes,solar wind streams,and geomagnetic activity during the new sunspot cycle

We have extended our previous study of coronal holes, solar wind streams, and geomagnetic disturbances from the declining phase (1973–1975) of sunspot cycle 20 through sunspot minimum (1976) into the rising phase (1977) of cycle 21. Using daily He I 10830 Å spectroheliograms and photospheric magnetograms, we found the following results:

1. As the magnetic field patterns changed, the solar atmosphere evolved from a structure having a few, large, long-lived, low-latitude coronal holes to one having numerous small, short-lived, high-latitude holes (in addition to the polar holes which persisted throughout this 5-year interval).
2. The high-latitude holes recurred with a synodic rotation period of 28–29 days instead of the 27-day period already known to be characteristic of low-latitude holes.
3. During 1976–1977 many coronal holes were intrinsically ‘weak’ in the sense that their average intensities did not differ greatly from the intensity of their surroundings. Such low-contrast holes were rare during 1973–1975.

An updated Bartels display of the occurrence of holes, wind speed, and geomagnetic activity summarizes the evolution of their characteristics and interrelations as the sunspot cycle has progressed. Long-lived, low-latitude holes have become rare but remain terrestrially effective. The more common high-latitude holes are effective only when the Earth lies at a relatively high heliographic latitude in the same solar hemisphere.     

Nondestructive determination of the physical properties of Antarctic meteorites: Importance for the meteorite—parent body connection

Photogrammetry is a low-cost, nondestructive approach for producing 3-D models of meteorites for the purpose of determining sample bulk density. Coupled with the use of a nondestructive magnetic susceptibility/electrical conductivity field probe, we present measurements for the interrogation of several physical properties, on a set of Antarctic meteorites. Photogrammetry is an effective technique over a range of sample sizes, with meteorite bulk density results that are closely comparable with literature values, determined using Archimedean glass bead or laser scanning techniques. The technique is completely noncontaminating and suitable for the analysis of rare or fragile samples, although there are limitations for analyzing reflective samples. It is also flexible, and, with variations in equipment setup, may be appropriate for samples of a wide range of sizes. X-ray computed tomography analyses of the same meteorite samples yielded slightly different bulk density results, predominantly for samples below 10 g, although the reason for this is unclear. Such analyses are expensive and potentially damaging to certain features of the sample (e.g., organic compounds), but may be useful in expanding the measurements to accommodate an understanding of internal voids within the sample, lending itself to measurement of grain density. Measurements of bulk density are valuable for comparisons with estimates of the bulk densities of asteroids that are suggested as meteorite parent bodies.     

Magnetograph measurements with temperature-sensitive lines

Certain discrepancies between theoretical and empirical calibrations of magnetograph response are resolved by recognizing the existence of line profile changes in magnetic regions. Many of the photospheric lines commonly used for magnetic field measurements weaken greatly in magnetic regions outside of sunspots. Unless due account is made of the line profile change, the magnetograph measurements underestimate magnetic flux and field strengths.The 5250.2 Å line is especially sensitive to weakening in magnetic regions. Measurements made with this line underestimate the true field by a factor ranging from about two on the linear portion of the profile to five near the line core.Kitt Peak National Observatory Contribution No. 500.Operated by the Association of Universities for Research in Astronomy Inc., under contract with the National Science Foundation.     

Pixel-based correction for Charge Transfer Inefficiency in the Hubble Space Telescope Advanced Camera for Surveys

Charge Transfer Inefficiency (CTI) due to radiation damage above the Earth's atmosphere creates spurious trailing in Hubble Space Telescope ( HST ) images. Radiation damage also creates unrelated warm pixels – but these happen to be perfect for measuring CTI. We model CTI in the Advanced Camera for Surveys (ACS)/Wide Field Channel and construct a physically motivated correction scheme. This operates on raw data, rather than secondary science products, by returning individual electrons to pixels from which they were unintentionally dragged during readout. We apply our correction to images from the HST Cosmic Evolution Survey (COSMOS), successfully reducing the CTI trails by a factor of ∼30 everywhere in the CCD and at all flux levels. We quantify changes in galaxy photometry, astrometry and shape. The remarkable 97 per cent level of correction is more than sufficient to enable a (forthcoming) reanalysis of downstream science products and the collection of larger surveys.     

The response of fishes to submerged aquatic vegetation complexity in two ecoregions of the mid-Atlantic bight: Buzzards Bay and Chesapeake Bay

Estuarine seagrass ecosystems provide important habitat for fish and invertebrates and changes in these systems may alter their ability to support fish. The response of fish assemblages to alteration of eelgrass (Zostera marina) ecosystems in two ecoregions of the Mid-Atlantic Bight (Buzzards Bay and Chesapeake Bay) was evaluated by sampling historical eelgrass sites that currently span a broad range of stress and habitat quality. In two widely separated ecoregions with very different fish faunas, degradation and loss of submerged aquatic vegetation (SAV) habitat has lead to declines in fish standing stock and species richness. The abundance, biomass, and species richness of the fish assemblage were significantly higher at sites that have high levels of eelgrass habitat complexity (biomass >100 wet g m^?2; density <100 shotts m^?2) compared to sites that have reduced eelgrass (biomass <100 wet g m^?2; density <100 shoots m^?2) or that have completely lost eelgrass. Abundance, biomass, and species richness at reduced eelgrass complexity sites also were more variable than at high eelgrass complexity habitats. Low SAV complexity sites had higher proportions of pelagic species that are not dependent on benthic habitat structure for feeding or refuge. Most species had greater abundance and were found more frequently at sites that have eelgrass. The replacement of SAV habitats by benthic macroalgae, which occurred in Buzzards Bay but not Chesapeake Bay, did not provide an equivalent habitat to seagrass. Nutrient enrichment-related degradation of eelgrass habitat has diminished the overall capacity of estuaries to support fish populations.     

Late Miocene sedimentary architecture of the Ebro Continental Margin (Western Mediterranean): implications to the Messinian Salinity Crisis

The Messinian Salinity Crisis (MSC) resulted from a significant multi-phase drop and subsequent reflooding of the Mediterranean Sea from 5.96 to 5.33 Ma. Well-developed drainage networks, characterized by step-like profiles and abrasion platforms, are associated to this event. The Ebro Continental Margin (Western Mediterranean) presents an additional complexity since the capture of the drainage of the adjacent subaerial Ebro Basin took place sometime prior to the Messinian stage. Using 3D seismic reflection data, this work provides new insights into the origin of the step-like profile of the Messinian erosional surface (MES) and timing of the capture of the subaerial Ebro Basin. The results obtained indicate a sedimentary-active continental slope and delta progradation during Middle-Late Miocene, in a normal regressive context associated to a pre-Messinian proto-Ebro River. The mature development attained by the Messinian Ebro River network during the MSC corroborates that the capture of the Ebro Basin occurred prior to the MSC. The configuration of the clinoforms below the MES suggests that deltaic sediments of the Messinian Paleo-Ebro River deposited during the Tortonian and initial Messinian sea-level drawdown. The MES formed at the top of the Tortonian Highstand, where a fluvial network was deeply carved, and in the topset region of the Messinian Falling Stage Systems Tract, where minor erosion occurred. Fluvial deposits are outstandingly preserved on the main valleys of the MES. Therefore, the step-like profile of the MES was not created during Zanclean inundation, but during the latest stages of the main Messinian sea-level fall and lowstand.     

The relationship between rock glacier and contributing area parameters in the Front Range of Colorado

Rock glaciers are an end unit of the coarse debris system that links frost weathering and rockfall to debris transport in mountainous environments. By examining topographic and climatic controls on creep, a better understanding of rock glacier formation and evolution could be obtained. A series of statistical tests were run comparing contributing area parameters (width, length, area, slope, headwall height, etc.) and rock glacier variables (width, length, area, thickness, slope, creep and temperature) in the Front Range of Colorado. Results showed that rock glacier width had the strongest correlation with contributing area width due to an abundance of lobate rock glaciers (r = 0.78). Rock glacier area and contributing area size were also related (r = 0.74), but are also a function of talus production factors. Mean surface velocity appears to be better correlated with thickness (r = 0.58) and length (r = 0.62), rather than slope (r = 0.33). Mean annual air temperature had a stronger exponential relationship with maximum velocities (r = 0.76) compared to mean annual velocity (r = 0.60). Front Range rock glacier velocities tend to decrease with warming, suggesting that the volume of ice and debris, rates of shear in plastic layers, or melt water may have a greater influence on deformation. Copyright © 2007 John Wiley & Sons, Ltd.     

Correcting lateral boundary biases in regional climate modelling: the effect of the relaxation zone

Climate Dynamics - Regional climate models (RCM) are an important tool for simulating atmospheric information at finer resolutions often of greater relevance to local scale climate change impact...