Geochemical Atlas of the Slovak Republic at a scale of 1:1,000,000

The Geochemical Atlas of Slovak Republic (49,036 km²) at a scale of 1 : 1,000,000 was compiled during 1991–1995 together with maps of associated geochemical and ecological features at a scale of 1 :200,000. Investigations were aimed at the evaluation of concentrations and distributions of Al, As, Ba, Be, Ca, Ce, Co, Cd, Cs, Cr, Cu, Fe, Ga, Hg, K, La, Li, Mg, Mn, Mo, Na, Ni, P, Pb, Rb, Sb, Se, Sn, Sr, Th, U, V, W, Y, Zn, Zr in groundwater (16,359 samples), stream sediments (24,422 samples), rocks (3839 samples), soils (9892 samples from 4946 profiles; A and C horizons of each profile were sampled) and forest biomass (the foliage of the forest tree species from 3063 plots was sampled). In groundwater field measurements of temperature, pH, conductivity, dissolved O₂, acidity, alkalinity were done. The evaluation was oriented to the natural radioactivity of the Slovak territory as follows: rocks (K, U, Th, U_tot and dose rate, 15,573 reference spectrometric points), radon risk and water (U_nat, ²²⁶Ra, ²²²Rn; 5271 samples). The main objective of the Geochemical Atlas was to construct single-component maps showing concentrations of chemical elements, compounds and measured parameters in the researched media of Slovakia at a scale of 1 : 1,000.000 and to create interactive databases of chemical composition and/or measured parameters of groundwater, biomass, rocks, soils, stream sediments and natural radioactivity, for the entire territory of the Slovak Republic. The single-component maps are not constructed in the part ‘Rocks’, where all the main rocks types of Slovakia are presented in the ‘Map of lithogeochemical rock types of Slovakia at a scale of 1: 500,000’. The edition of six atlases has been planned. In 1997 the first three atlases will appear (Groundwater, Biomass, Natural Radioactivity). Publishing of last three atlases (Rocks, Soils, Stream Sediments) is planned for 1998. Since the analytical works on stream sediments were finished during 1997, it was not possible to present here the results of that part of the Geochemical Atlas.     

Spectral analysis of oscillations with a time-variable frequency

Summary The paper presents a method of evaluating oscillations with a time-variable frequency using a computer. The given function is first interpolated at points which are not distributed equidistantly in time, but the digitizing step varies with time according to a known optional regularity. The spectrum of the obtained function is computed for various of these interpolations and tests are run to determine when the interpolation best compensates the time variation of the frequency. The initial and terminal frequency in the given sample is then determined. The usability of this method with respect to various types of oscillations with a variable frequency and its accuracy in comparison to sonagrams are discussed.     

Comparison between Pollutant Concentration in the Samples of Fog and Rime Water Collected at Mt. Milešovka

The article aims at showing the differences in concentration of pollutants that are contained in the samples of fog and/or low cloud water in comparison with the water from rime. The results follow from the fog and rime measurements made at Mt. Mileovka (eské Stedohoí Mountains). They are compared with the results of other studies that also report the differences in fog and rime chemistry.     

Trace element mobility in the mylonite zone within the ophiolite aureole,St. Anthony Complex,Newfoundland

The late syntectonic mylonite zone (45–100 m thick) within the dynamothermal aureole of the St. Anthony Complex in northwestern Newfoundland was derived from surrounding quartz and epidote amphibolites by deformation and the nearly isovolumetric metasomatism. Amphibolites have a composition typical of light REE-depleted ocean-floor tholeiites. Mylonites (biotite amphibolites) resemble transitional alkali basalts in major and trace element composition and in the interrelation among relatively immobile elements such as Ti, Zr, Nb, Y and P. Their REE patterns are enriched in light REE and show gradual depletion of heavy REE with La/Yb ratios ranging from 8.4 to 18.4. The results emphasize the need for caution in interpreting the concentration and ratios of any elements in mafic rocks which have been affected by metasomatism in an amphibolite facies shear zone.     

An autochthonous Avalonian basement source for the latest Ordovician Brenton Pluton in the Meguma terrane of Nova Scotia: U–Pb–Hf isotopic constraints and paleogeographic implications

International Journal of Earth Sciences - The Ediacaran–Ordovician Meguma Supergroup was thrust over Avalonia basement prior to the intrusion of post-Acadian, ca. 370 Ma, S-type...     

Interpolation by regularized spline with tension: II. Application to terrain modeling and surface geometry analysis

A general approach to the computation of basic topographic parameters independent of the spatial distribution of given elevation data is developed. The approach is based on an interpolation function with regular first and second order derivatives and on application of basic principles of differential geometry. General equations for computation of profile, plan, and tangential curvatures are derived. A new algorithm for construction of slope curves is developed using a combined grid and vector approach. Resulting slope curves better fulfill the condition of orthogonality to contours than standard grid algorithms. Presented methods are applied to topographic analysis of a watershed in central Illinois.     

Trace element geochemistry of paleozoic amphibolites from S. W. Spain

Summary Mid-grade low P/high T Paleozoic amphibolites from Acebuches (S. W. Spain) represent a mostly isochemically metamorphosed basaltic suite which is partly cumulative and partly differentiated. They have chemical compositions and element variations similar to ocean-floor tholeiites. The amphibolites may be related to the early stages of rapid rifting during the formation of the Variscan belt.

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Geochemie der Spurenelemente in Paläozoischen Amphiboliten aus Südwest-Spanien

Zusammenfassung Amphibolite mittleren Metamorphose-Grades (niedrige Drucke, hohe Temperaturen) von Acebuches, Südwest-Spanien, repräsentieren eine weithin isochemisch metamorphosierte Abfolge von Basalten, die teils differenzierte und teils Cumulus-Gesteine waren. Chemismus und Element-Variationen entsprechen den Tholeiiten von Ozeanböden. Diese Amphibolite können den Frühstadien intensiver Grabenbildung im Zuge der Entstehung des Varistischen Gürtels zugeordnet werden.

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Anisotropies of in-phase,out-of-phase,and frequency-dependent susceptibilities in three loess/palaeosol profiles in the Czech Republic; methodological implications

The relationship between the anisotropy of frequency-dependent magnetic susceptibility (fdAMS) and the anisotropy of out-of-phase magnetic susceptibility (opAMS) was investigated theoretically and also empirically at three loess/palaoesol profiles in Prague and in Southern Moravia. The data treatment was made in terms of mean susceptibility, degree of AMS, and orientations of principal susceptibilities. It has shown that the fdAMS and opAMS can serve as indicators of the preferred orientations of ultrafine magnetic particles that are on transition between superparamagnetic and stable single domain states in rocks, soils and environmental materials. In loess/palaeosol sequences, the fdAMS and opAMS correlate reasonably, because they are due to magnetic particles of similar grain sizes. The fdAMS and opAMS can be both coaxial with standard AMS (i.e. anisotropy of in-phase susceptibility - ipAMS) or non-coaxial indicating slightly different orientations of viscous magnetic particles.     

On the accuracy of location of local shocks on the territory of Czechoslovakia and adjacent areas

Summary The calculation procedures for determining epicentre parameters of weak near shocks with foci in Poland are discussed and tested for explosions with known epicentres.

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Deciphering an Archean mantle plume: Abitibi greenstone belt,Canada

The 2724–2722 Ma Stoughton-Roquemaure Group (SRG) of the Abitibi greenstone belt (the Archean Superior Province, Canada) is a ≤ 2 km thick komatiite–basalt succession intermittently exposed for about 50 km along strike. The ultramafic and mafic rocks occur mainly as pillowed, brecciated, and massive flows with well preserved spinifex textures in the komatiites. Volcanological, comparative stratigraphic and geochemical studies of the group along a volcanic marker horizon at the base of the succession allow the assessment of magma emplacement processes and mantle source rocks. Major feeder channels, secondary distributary tubes surrounded by pillowed flows with minor breccias and hyaloclastites display facies architecture of small volume flow fields (1–2 km³). Within the SRG, Al-depleted (ADK; Barberton-type) and Al-undepleted (AUK; Munro-type) komatiitic lavas are intercalated with tholeiitic basalt flows at a m- to 10s of m scale. Basalts and komatiites are inferred to be mantle plume-related; both rock types form two groups with characteristics of ADK and AUK including Al₂O₃/TiO₂ ~ 9–12 for ADK versus 17–22 for AUK, as well as (Gd/Yb)_n with > 1.3 versus ~ 1, respectively. The interdigitation of compositionally different flow units, limited extent of SRG volcanic rocks and facies architecture with the prevalence of small volume flows argue for a relatively small, heterogeneous mantle plume during the incipient stage of the evolution of the Archean Abitibi belt. Assuming that the scale of heterogeneities is comparable to the field expression of compositional changes and stratigraphy, it can be suggested that geochemical plume ‘layering’ is on 10s to 100s of m-scale. The evolution of this Archean mantle plume from inception to demise compares favorably with the Yellowstone hotspot which is assumed to have developed over 17 m.y. and had a diameter of about 300 km.