Origin and evolution of oilfield brines from Tertiary strata in western Qaidam Basin: Constraints from <Superscript>87</Superscript>Sr/<Superscript>86</Superscript>Sr, δD, δ<Superscript>18</Superscript>O, δ<Superscript>34</Superscript>S and water chemistry

Chemistry of major and minor elements, ⁸⁷Sr/⁸⁶Sr, δD, δ¹⁸O and δ³⁴S of brines were measured from Tertiary strata and Quaternary salt lakes in the western Qaidam Basin. The water chemistry data show that all oilfield brines are CaCl₂ type. They were enriched in Ca²⁺, B³⁺, Li⁺, Sr²⁺, Br⁻, and were depleted in Mg²⁺, SO₄ ²⁻, which indicated that these brines had the characteristics of deeply circulated water. The relationship between δD and δ¹⁸O shows that all data of these brines decline towards the Global Meteoric Water Line (GWL) and Qaidam Meteoric Water Line (QWL), and that the intersection between oilfield brines and Meteoric Water Lines was close to the local spring and fresh water in the piedmont in the western Qaidam Basin. The results suggest that oilfield brines has initially originated from meteoric water, and then might be affected by water-rock metamorphose, because most oilfield brines distribute in the range of metamorphosing water. The ⁸⁷Sr/⁸⁶Sr values of most oilfield brines range from 0.71121 to 0.71194, and was less than that in salt lake water (>0.712), but close to that of halite in the study area. These imply that salt dissolution occurred in the process of migration. In addition, all oilfield brines have obviously much positive δ³⁴S values (ranging from 26.46‰ to 54.57‰) than that of salt lake brines, which was caused by bacterial sulfate reduction resulting in positive shift of δ³⁴S value and depleteed SO₄ ²⁻ in oilfield brines. Combined with water chemical data and δD, δ¹⁸O, ⁸⁷Sr/⁸⁶Sr, δ³⁴S values, we concluded that oilfield brines mainly originate from the deeply circulated meteoric waters, and then are affected by salt dissolution, water-rock metamorphose, sulfate reduction and dolomitization during the process of migration. These processes alter the chemical compositions of oilfield brines and accumulate rich elements (such as B, Li, Sr, Br, K and so on) for sustainable utilization of salt lake resources in the Qaidam Basin.     

Assessing desertification by using soil indices

Desertification generally refers to land degradation in arid, semiarid, and dry semi-humid climatic zones. It involves five principal processes: vegetation degradation, water erosion, wind erosion, salinization and waterlogging, and soil crusting and compaction. The aim of this study is assessing desertification using soil criteria. For this purpose, nine indices including sodium absorption ratio (SAR), soil gypsum percentage, soil texture, the content of HCO₃ ^?, the percentage of the organic matter, electrical conductivity (EC), pH, the content of the soil sodium, and chloride were used. The soil samples were taken in the north of Zayandeh-Rood River in Isfahan province of Iran, using soil data randomly sampled in a depth of 0–20 cm. After assessing the normality of the samples using Kolmogorov-Smirnov test, indices were imported into GIS environment and interpolated with IDW and normal and discrete kriging methods for delineating soil characteristics maps based on MEDALUS model. In this model, the data were firstly changed from 100 to 200. Thus 100 and 200 are estimated as the best and worst quality, respectively. Then the final map of soil criteria has been created by geometric mean of its indicators. The results showed that the maximum area is related to the medium class of desertification and is equal to 44,746 ha. The areas of severe and very severe classes of desertification are equal to 30,949 and 351 ha, respectively. The results also revealed that the indices of the organic matter and soil gypsum percentage are the most influential indices which affect desertification phenomenon.     

Histogram and variogram inference in the multigaussian model

Several iterative algorithms are proposed to improve the histogram and variogram inference in the framework of the multigaussian model. The starting point is the variogram obtained after a traditional normal score transform. The subsequent step consists in simulating many sets of gaussian values with this variogram at the data locations, so that the ranking of the original values is honored. The expected gaussian transformation and the expected variogram are computed by an averaging operation over the simulated datasets. The variogram model is then updated and the procedure is repeated until convergence. Such an iterative algorithm can adapt to the case of tied data and despike the histogram. Two additional issues are also examined, referred to the modeling of the empirical transformation function and to the optimal pair weighting when computing the sample variogram.     

New classes of spectral densities for lattice processes and random fields built from simple univariate margins

Quasi arithmetic and Archimedean functionals are used to build new classes of spectral densities for processes defined on any d-dimensional lattice \mathbbZ^d{\mathbb{Z}^d} and random fields defined on the d-dimensional Euclidean space \mathbbR^d{\mathbb{R}^d}, given simple margins. We discuss the mathematical features of the proposed constructions, and show rigorously as well as through examples, that these new classes of spectra generalize celebrated classes introduced in the literature. Additionally, we obtain permissible spectral densities as linear combinations of quasi arithmetic or Archimedean functionals, whose associated correlation functions may attain negative values or oscillate between positive and negative ones. We finally show that these new classes of spectral densities can be used for nonseparable processes that are not necessarily diagonally symmetric.     

Density,porosity, mineralogy,and internal structure of cosmic dust and alteration of its properties during high‐velocity atmospheric entry

X‐ray microtomography (XMT), X‐ray diffraction (XRD), and magnetic hysteresis measurements were used to determine micrometeorite internal structure, mineralogy, crystallography, and physical properties at μm resolution. The study samples include unmelted, partially melted (scoriaceous), and completely melted (cosmic spherules) micrometeorites. This variety not only allows comparison of the mineralogy and porosity of these three micrometeorite types but also reveals changes in meteoroid properties during atmospheric entry at various velocities. At low entry velocities, meteoroids do not melt and their physical properties do not change. The porosity of unmelted micrometeorites varies considerably (0–12%) with one friable example having porosity around 50%. At higher velocities, the range of meteoroid porosity narrows, but average porosity increases (to 16–27%) due to volatile evaporation and partial melting (scoriaceous phase). Metal distribution seems to be mostly unaffected at this stage. At even higher entry velocities, complete melting follows the scoriaceous phase. Complete melting is accompanied by metal oxidation and redistribution, loss of porosity (1 ± 1%), and narrowing of the bulk (3.2 ± 0.5 g cm^?3) and grain (3.3 ± 0.5 g cm^?3) density range. Melted cosmic spherules with a barred olivine structure show an oriented crystallographic structure, whereas other subtypes do not.     

Micromechanical approach to effective viscoelastic properties of micro‐fractured geomaterials

The aim of this paper is to formulate a micromechanics‐based approach to non‐aging viscoelastic behavior of materials with randomly distributed micro‐fractures. Unlike cracks, fractures are discontinuities that are able to transfer stresses and can therefore be regarded from a mechanical viewpoint as interfaces endowed with a specific behavior under normal and shear loading. Making use of the elastic‐viscoelastic correspondence principle together with a Mori‐Tanka homogenization scheme, the effective viscoelastic behavior is assessed from properties of the material constituents and damage parameters related to density and size of fractures. It is notably shown that the homogenized behavior thus formulated can be described in most cases by means of a generalized Maxwell rheological model. For practical implementation in structural analyses, an approximate model for the isotropic homogenized fractured medium is formulated within the class of Burger models. Although the approximation is basically developed for short‐term and long‐term behaviors, numerical applications indicate that the approximate Burger model accurately reproduce the homogenized viscoelastic behavior also in the transient conditions.     

Natural background levels and threshold values for groundwater in fluvial Pleistocene and Tertiary marine aquifers in Flanders,Belgium

Aquifers from the same typology can have strongly different groundwater chemistry. Deducing the groundwater quality of less well-characterized aquifers from well-documented aquifers belonging to the same typology should be done with great reserve, and can only be considered as a preliminary approach. In the EU’s 6th FP BRIDGE project “Background cRiteria for the IDentification of Groundwater thrEsholds”, a methodology for the derivation of threshold values (TV) for groundwater bodies is proposed. This methodology is tested on four aquifers in Flanders of the sand and gravel typology. The methodology works well for all but the Ledo-Paniselian aquifer, where the subdivision into a fresh and saline part is disproved, as a gradual natural transition from fresh to saline conditions in the aquifer is observed. The 90 percentile is proposed as natural background level (NBL) for the unconfined Pleistocene deposits, ascribing the outliers to possible influence of pollution. For the Tertiary aquifers, high values for different parameters have a natural origin and the 97.7 percentile is preferred as NBL. The methodology leads to high TVs for parameters presenting low NBL, when compared to the standard used as a reference. This would allow for substantial anthropogenic inputs of these parameters.     

Boltzmann constant in the model of expansive non-decelerative universe

From the observed present parameters of the Universe and the model properties of an expansive non-decelerative universe it results that the value of Boltzmann's constant (coefficient)k does not change only before the end of radiation era, but also in the matter era; with the increase of gauge factora, it decreases as (a ^–1)^1/4.     

Evaluation of Air Pollution Trend Using GIS and RS Applications in South West of Iran

In this paper, remote sensing and GIS have been used to assess the status of NO₂ at the south west of Iran. 221 data about concentration of NO₂ was extracted from Ozone Monitoring Instrument. Ordinary kriging and inverse distance weighting interpolation methods was used to interpolate data. Results showed that ordinary kriging method using cross-validation have had less error. North east of the study area has the highest concentration of NO₂ (329 molecule/cm²) and the concentration of NO₂ decreases from north east to South west of the study area. On the other hand, data trend results showed that the data seems to exhibit a fairly strong trend in the east west direction and a weaker one in the north–south direction.