Fate and effects of picric acid and 2,6-DNT in marine environments: toxicity of degradation products

The toxicity of transformation products of 2,6-dinitrotoluene (2,6-DNT) and 2,4,6-trinitrophenol (picric acid) were assessed in spiked sandy and fine-grained marine sediments and in seawater. Toxicity of pore water from sediments spiked with 2,6-DNT decreased for the macro-alga, Ulva fasciata, zoospores as biotransformation proceeded, but increased for the copepod, Schizopera knabeni, nauplii. The primary biotransformation product of 2,6-DNT, 2-amino-6-nitrotoluene, was also more toxic than the parent compound to copepod nauplii, but not to alga zoospores, in spiked seawater tests. Two biotransformation products of picric acid, picramic acid and 2,4-DNP, were more toxic than their parent compound. Porewater toxicity from picric acid-spiked sediments decreased significantly at the end of six-months incubation. Fine-grained sediment spiked with either ordnance compound had lower toxicity than its sandy counterpart after six months, suggesting faster microbial transformation in the former and production of less toxic products. Photo-transformation of 2,6-DNT in seawater resulted in a reduction in toxicity.     

Self-consistent equilibrium ocean tides

Summary. We compute the static response of the world ocean to an external zonal gravitational potential. The computation includes the effects of the self-attraction of the ocean, and the yielding of the Earth caused both by the external potential and the change in ocean load. We compare the computed tide with measurements of the fortnightly and monthly ocean tides. The short-wavelength departures from equilibrium found by Wunsch are still present. An average of observations at Pacific islands shows that the fortnightly tide departs significantly from equilibrium but the monthly may not. We have also calculated the effects of our computed tide on measurements of tidal gravity and tidal fluctuations in the length of day. Existing tidal gravity data are too imprecise to enable us to determine whether or not the spatial average of the ocean tides departs from equilibrium. The length of day data suggest that the monthly tide is farther from equilibrium than the fortnightly. We have not been able to resolve the apparent discrepancy between the length of day and ocean tide data.     

Fast-drift shadow events in Jupiter's decametric radio spectra

High-resolution dynamic spectra of Jovian S-bursts frequently reveal sloping gaps crossing bands of L-burst emission with drift rates comparable to those of S-bursts. These “fast-drift shadow” (FDS) events are often sharply bounded on one edge by an S-burst, and sometimes on both edges by a pair of S-bursts emanating from a common vertex. It is suggested that the investigation of such S- and L-burst interactions may provide new insights of considerable importance in the search for the Jovian decametric emission mechanism.     

Preliminary mariner 9 report on the geology of Mars

Mariner 9 pictures indicate that the surface of Mars has been shaped by impact, volcanic, tectonic, erosional and depositional activity. The moonlike cratered terrain, identified as the dominant surface unit from the Mariner 6 and 7 flyby data, has proven to be less typical of Mars than previously believed, although extensive in the mid- and high-latitude regions of the southern hemisphere. Martian craters are highly modified but their size-frequency distribution and morphology suggest that most were formed by impact. Circular basins encompassed by rugged terrain and filled with smooth plains material are recognized. These structures, like the craters, are more modified than corresponding features on the Moon and they exercise a less dominant influence on the regional geology. Smooth plains with few visible craters fill the large basins and the floors of larger craters; they also occupy large parts of the northern hemisphere where the plains lap against higher landforms. The middle northern latitudes of Mars from 90 to 150† longitude contain at least four large shield volcanoes each of which is about twice as massive as the largest on Earth. Steep-sided domes with summit craters and large, fresh-appearing volcanic craters with smooth rims are also present in this region. Multiple flow structures, ridges with lobate flanks, chain craters, and sinuous rilles occur in all regions, suggesting widespread volcanism. Evidence for tectonic activity postdating formation of the cratered terrain and some of the plains units is abundant in the equatorial area from 0 to 120° longitude.Some regions exhibit a complex semiradial array of graben that suggest doming and stretching of the surface. Others contain intensity faulted terrain with broader, deeper graben separated by a complex mosaic of flat-topped blocks. An east-west-trending canyon system about 100–200 km wide and about 2500 km long extends through the Coprates-Eos region. The canyons have gullied walls indicative of extensive headward erosion since their initial formation. Regionally depressed areas called chaotic terrain consist of intricately broken and jumbled blocks and appear to result from breaking up and slumping of older geologic units. Compressional features have not been identified in any of the pictures analyzed to data. Plumose light and dark surface markings can be explained by eolian transport. Mariner 9 has thus revealed that Mars is a complex planet with its own distinctive geologic history and that it is less primitive than the Moon.     

Toxicological and chemical assessment of ordinance compounds in marine sediments and porewaters

Toxicological and chemical studies were performed with a silty and a sandy marine sediment spiked with 2,6-dinitrotoluene (2,6-DNT), 2,4,6-trinitrophenylmethylnitramine (tetryl), or 2,4,6-trinitrophenol (picric acid). Whole sediment toxicity was analyzed by the 10-day survival test with the amphipod Ampelisca abdita, and porewater toxicity tests assessed macro-algae (Ulva fasciata) zoospore germination and germling growth, sea urchin (Arbacia punctulata) embryological development, and polychaete (Dinophilus gyrociliatus) survival and reproduction. Whole sediments spiked with 2,6-DNT were not toxic to amphipods. The fine-grained sediment spiked with tetryl was also not acutely toxic. The tetryl and picric acid LC50 values in the sandy sediment were 3.24 and 144 mg/kg dry weight, respectively. The fine-grained sediment spiked with picric acid generated a U-shaped concentration-response curve in the amphipod test, with increased survival both in the lowest and highest concentration. Grain-size distribution and organic carbon content strongly influenced the behavior of ordnance compounds in spiked sediments. Very low concentrations were measured in some of the treatments and irreversible binding and biodegradation are suggested as the processes responsible for the low measurements. Porewater toxicity varied with its sedimentary origin and with ordnance compound. The sea urchin embryological development test tended to be the least sensitive. Tetryl was the most toxic chemical in all porewater tests, and picric acid the least toxic. Samples spiked with 2,6-DNT contained a degradation product identified as 2-methyl-3-nitroaniline (also known as 2-amino-6-nitrotoluene), and unidentified peaks, possibly degradation products, were also seen in some of the picric acid- and tetryl-spiked samples. Degradation products may have played a role in observed toxicity.     

Local and regional variations in Central American arc lavas controlled by variations in subducted sediment input

The sedimentary section (at DSDP Site 495) on the subducting Cocos Plate has large stratigraphic changes in incompatible elements and element ratios, the result of early carbonate deposition followed by late hemipelagic deposition. Lavas from Central America define both local and regional geochemical trends that reflect the strong influence of the two Cocos Plate sediment units. Element ratios with large stratigraphic variations on the Cocos Plate (e.g. Ba/Th, U/La) define local variations within individual volcanic centers in Central America, indicating that marine stratigraphy controls some geochemical characteristics of the lavas. These local trends can be explained by changing the proportions of hemipelagic sediment input into the magma generation process. These local trends are observed in all the segments of the arc, regardless of the intensity of the slab signature. Regional variations are most clearly seen in element ratios that are nearly constant through the Cocos Plate sediment stratigraphy (e.g. Ba/La, U/Th), suggesting that regional variations reflect differences in the intensity of the flux from the subducting slab. The slab signal is strongest in Nicaragua and along the volcanic front. The signal decreases to the northwest and southeast of Nicaragua and toward the back arc. The large slab signature in the lavas from western Nicaragua occurs in the area with the thinnest continental crust and steepest dip of the slab. The mass flux of incompatible elements into the system is easily estimated, except for elements, like Pb, that have high and variable abundances in the basaltic oceanic crust section. The mass flux of elements out of the system depends on eruption rates, which are variable along the arc and only approximately known. Comparison of input and output fluxes for five different segments of the arc reveals that some elements (K, B, Cs, and Rb) are very efficiently delivered to the volcanoes from the subducted slab. Other elements (Sr, Ba, and U) are returned to the surface with moderate efficiency, whereas some elements (REEs) may come mostly from the mantle wedge with minor slab contribution. The relative order of recycling efficiencies of incompatible elements implies that a hydrous fluid dominates the transfer of material from the slab to mantle. Received: 7 September 1998 / Accepted: 30 September 1999     

Letter to the Editor

Mathematical Geosciences -