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101.
102.
Journal of Geographical Systems - Although the effects of urban shrinkage on quality of life and the built environment have received a great deal of attention, the characteristics of those...  相似文献   
103.
The continuous improvement of analytical procedures using multi‐collector technologies in ICP‐mass spectrometry has led to an increased demand for isotope standards with improved homogeneity and reduced measurement uncertainty. For magnesium, this has led to a variety of available standards with different quality levels ranging from artefact standards to isotope reference materials certified for absolute isotope ratios. This required an intercalibration of all standards and reference materials, which we present in this interlaboratory comparison study. The materials Cambridge1, DSM3, ERM‐AE143, ERM‐AE144, ERM‐AE145, IRMM‐009 and NIST SRM 980 were cross‐calibrated with expanded measurement uncertainties (95% confidence level) of less than 0.030‰ for the δ25/24Mg values and less than 0.037‰ for the δ26/24Mg values. Thus, comparability of all magnesium isotope delta (δ) measurements based on these standards and reference materials is established. Further, ERM‐AE143 anchors all magnesium δ‐scales to absolute isotope ratios and therefore establishes SI traceability, here traceability to the SI base unit mole. This applies especially to the DSM3 scale, which is proposed to be maintained. With ERM‐AE144 and ERM‐AE145, which are product and educt of a sublimation–condensation process, for the first time a set of isotope reference materials is available with a published value for the apparent triple isotope fractionation exponent θapp, the fractionation relationship ln α(25/24Mg)/ln α(26/24Mg).  相似文献   
104.
The snails (Pomacea insularum) were collected from polluted and unpolluted sites at Juru River and the Universiti Putra Malaysia Lake, respectively. Besides the shells, the soft tissues of snails were dissected into 6 different parts: intestine, operculum, foot, pennial sac, lung sac and the remainder. They were analyzed for the concentrations of Cu, Cd, Zn, Pb, Ni and Fe. The present study found 6 interesting points. First, all the metal levels found in the different parts of P. insularum collected from Juru River were significantly (p<0.05) higher than those in the snails of unpolluted lake. These results were also supported by the sediment data in which the Juru River sediment had significantly (p<0.05) higher levels of metal than those in the unpolluted lake. Second, the high levels of Cd and Pb were found in the shell of P. insularum, indicating that it is a potential biomonitoring material for these metals. Third, intestine accumulated elevated levels of Zn, Ni and Fe and thus is a potential biomonitoring organ for the 3 metals. Fourth, high levels of Cu were found in the lung sac and this phenomenon could be related to this metal binding to metallothionein in this organ. Fifth, elevated level of Pb found in the soft tissues of P. insularum indicated that this snail is not suitable for human consumption since its pollution level was higher than the food safety guideline for Pb. Sixth, there was no significant difference (p>0.05) between the different sizes (small sizes: 30.5-33.2 mm; large sizes: 37.7-40.4 mm) of P. insularum. The first 5 points supported the use of different soft tissues of P. insularum as biomonitoring organs of heavy metal pollution in the freshwater ecosystem in Malaysia although further validation is required.  相似文献   
105.
Structurally bound upwelling and outflowing hot fluids in the city of Wiesbaden suggest an interesting geothermal potential at the northern margin of the permo‐carboniferous Saar–Nahe basin, Germany. The Saar–Nahe basin in the Wiesbaden area was previously not a target for intensive geophysical prospecting of the deep underground. We present an exploration concept to investigate potential geothermal reservoirs near Wiesbaden for heat and power production. The acquired geophysical exploration data give new insights into the local geometry and internal structure of the Saar–Nahe basin. The exploration combines a wide range of methods, including the analysis of data, a dense grid gravity survey, as well as two‐dimensional and three‐dimensional seismic surveys. The resulting data, which for the first time reveal the deep structure of the Mainz and Saar–Nahe basins near Wiesbaden down to a depth of c. 4,000 m, show that the Saar–Nahe basin is strongly segmented and contains deep‐reaching active faults. Combining these information with numerical models of the stresses in the fault system and of the temperature distribution in the exploration area, a promising drilling target has been identified, which promise high permeability at a low risk of induced or triggered seismicity.  相似文献   
106.
Horizontal drilling and hydraulic fracturing have enabled hydrocarbon recovery from unconventional reservoirs, but led to natural gas contamination of shallow groundwaters. We describe and apply numerical models of gas‐phase migration associated with leaking natural gas wells. Three leakage scenarios are simulated: (1) high‐pressure natural gas pulse released into a fractured aquifer; (2) continuous slow leakage into a tilted fractured formation; and (3) continuous slow leakage into an unfractured aquifer with fluvial channels, to facilitate a generalized evaluation of natural gas transport from faulty natural gas wells. High‐pressure pulses of gas leakage into sparsely fractured media are needed to produce the extensive and rapid lateral spreading of free gas previously observed in field studies. Transport in fractures explains how methane can travel vastly different distances and directions laterally away from a leaking well, which leads to variable levels of methane contamination in nearby groundwater wells. Lower rates of methane leakage (≤1 Mcf/day) produce shorter length scales of gas transport than determined by the high‐pressure scenario or field studies, unless aquifers have low vertical permeabilities (≤1 millidarcy) and fractures and bedding planes have sufficient tilt (~10°) to allow a lateral buoyancy component. Similarly, in fractured rock aquifers or where permeability is controlled by channelized fluvial deposits, lateral flow is not sufficiently developed to explain fast‐developing gas contamination (0‐3 months) or large length scales (~1 km) documented in field studies. Thus, current efforts to evaluate the frequency, mechanism, and impacts of natural gas leakage from faulty natural gas wells likely underestimate contributions from small‐volume, low‐pressure leakage events.  相似文献   
107.
Concepts of simplicity and complexity in modeling have been explored in papers, editorials, and talks. The concept is not well understood because there are at least two flavors of simplicity. Modelers envision simplicity (i.e., elegant simplicity) as the sought‐after goal in modeling, but naïve simplicity, which is the focus of this paper, is commonly unrecognized and dangerous. The problem is that naïve or simple ideas are often mistaken for settled science and come with the prospect of being more wrong than right. The concept of the so‐called simplicity cycle, in relation to classical problems of carbon‐14 age and salinity in closed‐basin lakes, is used to illustrate these points. The emerging problems of water‐mosquitoes‐diseases show the value of mapping new problems to the simplicity cycle. Researchers can “know what they do not know” and avoid the dangers of naïve simplicity.  相似文献   
108.
Exotic trees, such as willow (Salix spp.), have become invasive around New Zealand waterways. Lowland wetlands in particular are vulnerable, with invasions changing hydrology and causing biodiversity loss. Applying herbicide to the willow canopy is a cost-effective control method, however uncertainty remains around effects on wetland aquatic invertebrates. Within a North Island, New Zealand, wetland, we conducted a paired before-after, control-impact study to determine if aerially applied glyphosate (with adjuvants) affected invertebrate assemblages. No effect on communities was detected during the first year after glyphosate treatment, however significant differences between control and spray-exposed communities were found during the second year, coinciding with a significant drought event in March 2013. By the third year, no statistically significant differences were found between communities from control and spray-exposed sites. This study suggests that glyphosate use, in comparable environments, is unlikely to affect aquatic invertebrates. Furthermore, the study illustrates invertebrate communities’ resilience to drought events.  相似文献   
109.
The number of natural catastrophes in this decade is four times greater than in the 1960s; economic losses are eight times greater; and insured losses are 15 times greater. The insurance industry's financial interest is inter-dependent with climate and weather. Natural events drive the demand for insurance coverage and can threaten the viability of an insurer if it is over-exposed in high risk areas. Early in the 1990s, the industry began to recognize that historical data were potentially misleading with respect to future natural catastrophe exposure. The U.S. insurance industry is pursuing a variety of new approaches including: the use of catastrophe computer models to integrate the natural knowledge about extreme events taken from the sciences into the actuarial sciences. The evaluation of building codes and building code enforcement in every community in the country enhanced its support for hazard mitigation.  相似文献   
110.
This study presents the age control and environmental magnetism components of a new, late Pleistocene paleoclimate record for the Great Basin of western North America. Two new cores from the Summer Lake sub-basin of pluvial Lake Chewaucan, Oregon, USA are correlated to basin margin outcrops on the basis of tephrochronology, lithostratigraphy, sediment magnetism and paleomagnetic secular variation. Eleven tephra layers were found in the cores that correlate to tephra identified previously in the outcrop. The Olema ash was also found in one of the cores; its stratigraphic position, relative to 3 dated tephra layers, indicates that its age is 50-55 ka, somewhat younger than has been previously reported. The Summer Lake sediments are divided into deep and shallow lake lithosomes based on sedimentary features. The stratigraphic position of these lithosomes support the tephra-based correlations between the outcrop and the cores. These sediments contain a well resolved record of the Mono Lake Excursion (MLE) and an earlier paleomagnetic excursion as well as a high quality replication of the paleosecular variation immediately above the MLE.Relative sedimentation rates increased dramatically toward the depocenter during intervals of low-lake level. In contrast, during intervals of high-lake level, relative sedimentation rates were comparable along the basin axis from the basin margin to the depocenter. The magnetic mineralogy of the Summer Lake sediments is dominated by pseudo-single domain (titano)magnetite and intervals of high/low magnetite concentration coincide with lithosomes that indicate high/low lake levels. Magnetic grain size also varies in accord with bulk sediment grain size as indicated by the silt/clay ratio. To a first order, variations in magnetic parameters, especially those attributable to the concentration of magnetic minerals, correlate well with global glacial/interglacial oscillations as indicated by marine oxygen isotope stages. This relationship can be explained by increased dissolution of (titano)magnetite minerals as lake level dropped and the lake became more productive biologically. This inference is supported by a correspondence between lower concentrations of magnetite with higher levels of total organic carbon and vice-versa.  相似文献   
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