Seasonal Oxygen Dynamics in a Warm Temperate Estuary: Effects of Hydrologic Variability on Measurements of Primary Production,Respiration, and Net Metabolism

Seasonal responses in estuarine metabolism (primary production, respiration, and net metabolism) were examined using two complementary approaches. Total ecosystem metabolism rates were calculated from dissolved oxygen time series using Odum’s open water method. Water column rates were calculated from oxygen-based bottle experiments. The study was conducted over a spring-summer season in the Pensacola Bay estuary at a shallow seagrass-dominated site and a deeper bare-bottomed site. Water column integrated gross production rates more than doubled (58.7 to 130.9 mmol O₂ m^?2 day^?1) from spring to summer, coinciding with a sharp increase in water column chlorophyll-a, and a decrease in surface salinity. As expected, ecosystem gross production rates were consistently higher than water column rates but showed a different spring-summer pattern, decreasing at the shoal site from 197 to 168 mmol O₂ m^?2 day^?1 and sharply increasing at the channel site from 93.4 to 197.4 mmol O₂ m^?2 day^?1. The consistency among approaches was evaluated by calculating residual metabolism rates (ecosystem ? water column). At the shoal site, residual gross production rates decreased from spring to summer from 176.8 to 99.1 mmol O₂ m^?2 day^?1 but were generally consistent with expectations for seagrass environments, indicating that the open water method captured both water column and benthic processes. However, at the channel site, where benthic production was strongly light-limited, residual gross production varied from 15.7 mmol O₂ m^?2 day^?1 in spring to 86.7 mmol O₂ m^?2 day^?1 in summer. The summer rates were much higher than could be realistically attributed to benthic processes and likely reflected a violation of the open water method due to water column stratification. While the use of sensors for estimating complex ecosystem processes holds promise for coastal monitoring programs, careful attention to the sampling design, and to the underlying assumptions of the methods, is critical for correctly interpreting the results. This study demonstrated how using a combination of approaches yielded a fuller understanding of the ecosystem response to hydrologic and seasonal variability.     

Fate and transport of volatile organic compounds in glacial till and groundwater at an industrial site in Northern Ireland

Volatile organic compound (VOC) contamination of subsurface geological material and groundwater was discovered on the Nortel Monkstown industrial site, Belfast, Northern Ireland. The objectives of this study were to (1) investigate the characteristics of the geological material and its influences on contaminated groundwater flow across the site using borehole logs and hydrological evaluations, and (2) identify the contaminants and examine their distribution in the subsurface geological material and groundwater using chemical analysis. This report focuses on the eastern car park (ECP) which was a former storage area associated with trichloroethene (TCE) degreasing operations. This is where the greatest amount of volatile organic compounds (VOCs), particularly TCE, were detected. The study site is on a complex deposit of clayey glacial till with discontinuous coarser grained lenses, mainly silts, sands and gravel, which occur at 0.45–7.82 m below ground level (bgl). The lenses overall form an elongated formation that acts as a small unconfined shallow aquifer. There is a continuous low permeable stiff clayey till layer beneath the lenses that performs as an aquitard to the groundwater. Highest concentrations of VOCs, mainly TCE, in the geological material and groundwater are in these coarser lenses at ∼4.5–7 m bgl. Highest TCE measurements at 390,000 μg L⁻¹ for groundwater and at 39,000 μg kg⁻¹ at 5.7 m for geological material were in borehole GA19 in the coarse lens zone. It is assumed that TCE gained entrance to the subsurface near this borehole where the clayey till was thin to absent above coarse lenses which provided little retardation to the vertical migration of this dense non-aqueous phase liquid (DNAPL) into the groundwater. However, TCE is present in low concentrations in the geological material overlying the coarse lens zone. Additionally, VOCs appear to be associated with poorly drained layers and in peat <3.0 m bgl in the ECP. Some indication of natural attenuation as VOCs degradation products vinyl chloride (VC) and dichloromethane (DCM) also occur on the site.     

Return migration of 1.5 generation Korean New Zealanders: Short‐term and long‐term motives

Through in‐depth interviews and participant observation with 40 1.5 generation Korean New Zealander returnees, we explore life trajectories and identify both short‐ and long‐term reasons for return. Short‐term reasons for return include moving home when entering adulthood in order to begin a career, gaining new experiences and finding a future spouse. Longer term influences include the difficulties of living as minority‐status immigrants in the host society, transnational connections and a longing for a sense of ‘home’. Our consideration of longer term migration strategies sheds light upon the often forgotten difficulties and complexities that can underlie an individual's return.     

Benthic metabolism and nutrient cycling along an estuarine salinity gradient

Benthic metabolism and nutrient exchange across the sediment-water interface were examined over an annual cycle at four sites along a freshwater to marine transect in the Parker River-Plum Island Sound estuary in northeastern Massachusetts, U.S. Sediment organic carbon content was highest at the freshwater site (10.3%) and decreased along the salinity gradient to 0.2% in the sandy sediments at the marine end of the estuary. C:N ratios were highest in the mid estuary (23:1) and lowest near the sea (11:1). Chlorophyll a in the surface sediments was high along the entire length of the estuary (39–57 mg chlorophyll a m⁻²) but especially so in the sandy marine sediments (172 mg chlorophyll a m⁻²). Chlorophyll a to phaeophytin ratios suggested most chlorophyll is detrital, except at the sandy marine site. Porewater sulfide values varied seasonally and between sites, reflecting both changes in sulfate availability as overlying water salinity changed and sediment metabolism. Patterns of sediment redox potential followed those of sulfide. Porewater profiles of inorganic N and P reflected strong seasonal patterns in remineralization, accumulation, and release. Highest porewater NH₄ ⁺ values were found in upper and mid estuarine sediments, occasionally exceeding 1 mM N. Porewater nitrate was frequently absent, except in the sandy marine sediments where concentrations of 8 μM were often observed. Annual average respiration was lowest at the marine site (13 mmol O₂ m⁻² d⁻¹ and 21 mmol TCO₂ m⁻² d⁻¹) and highest in the mid estuary (130 mmol O₂ m⁻² d⁻¹ and 170 mmol TCO₂ m⁻² d⁻¹) where clam densities were also high. N₂O and CH₄ fluxes were low at all stations throughout the year: Over the course, of a year, sediments varied from being sources to sinks of dissolved organic C and N, with the overall spatial pattern related closely to sediment organic content. There was little correlation between PO₄ ³⁻ flux and metabolism, which we attribute to geochemical processes. At the two sites having the lowest salinities, PO₄ ³⁻ flux was directed into the sediments. On average, between 22% and 32% of total system metabolism was attributable to the benthos. The mid estuary site was an exception, as benthic metabolism accounted for 95% of the total, which is attributable to high densities of filter-feeding clams. Benthic remineralization supplied from less than 1% to over 190% of the N requirements and 0% to 21% of the P requirements of primary producers in this system. Estimates of denitrification calculated from stoichiometry of C and N fluxes ranged from 0% for the upper and mid estuary site to 35% for the freshwater site to 100% of sediment organic N remineralization at the marine site. We hypothesize that low values in the upper and mid estuary are attributable to enhanced NH₄ ⁺ fluxes during summer due to desorption of exchangeable ammonium from rising porewater salinity. NH₄ ⁺ desorption during summer may be a mechanism that maintains high rates of pelagic primary production at a time of low inorganic N inputs from the watershed.     

Monitoring the grazing resources of the Badia region, Jordan, using remote sensing

In this paper we discuss how low spatial resolution (1 km) ERS ATSR-2 and NOAA AVHRR satellite data were used to map and monitor changes in the grazing vegetation of the Badia region of Jordan. This area is typical of many arid zone grazing areas, comprising sparse vegetation and highly reflective soils. These two factors were found to severely limit the usefulness of satellite-derived vegetation indices that are frequently used to map and monitor vegetation in more temperate areas. Furthermore, the relationship between vegetation indices and percentage vegetation cover was found to be site-specific, thus reducing their application for large-scale vegetation monitoring. As an alternative, a hybrid geometric optical/empirically based model was developed for the area. This was based on the illumination geometry and reflectance values from the red and near-infrared scattergram of the satellite images. The output of the model was a series of maps indicating percentage vegetation cover for different dates and these were used to construct maps showing areas of vegetation change. Strong correlations (r²=0.837) were found between estimates of percentage vegetation cover derived from the model, and measurements made at a series of 16 field sites in the area. The use of geometric optical models based on satellite imagery improves the ability to map areas of grazing vegetation in arid areas such as the Badia and provides a good alternative to the use of vegetation indices.     

Assessment of Offshore New Jersey Sources of Beach Replenishment Sand by Diversified Application of Geologic and Geophysical Methods

Beach replenishment serves the dual purpose of maintaining a source of tourism and recreation while protecting life and property. For New Jersey, sources for beach sand supply are increasingly found offshore. To meet present and future needs, geologic and geophysical techniques can be used to improve the identification, volume estimation, and determination of suitability, thereby making the mining and manag ing of this resource more effective. Current research has improved both data collection and interpretation of seismic surveys and vibracore analysis for projects investigating sand ridges offshore of New Jersey. The New Jersey Geological Survey in cooperation with Rutgers University is evaluating the capabilities of digital seismic data (in addition to analog data) to analyze sand ridges. The printing density of analog systems limits the dynamic range to about 24 dB. Digital acquisition systems with dynamic ranges above 100 dB can permit enhanced seismic profiles by trace static correction, deconvolution, automatic gain scaling, horizontal stacking and digital filtering. Problems common to analog data, such as wave-motion effects of surface sources, water-bottom reverberation, and bubble-pulse-width can be addressed by processing. More than 160 line miles of digital high-resolution continuous profiling seismic data have been collected at sand ridges off Avalon, Beach Haven, and Barnegat Inlet. Digital multichannel data collection has recently been employed to map sand resources within the Port of New York New Jersey expanded dredge-spoil site located 3 mi offshore of Sandy Hook, New Jersey. Multichannel data processing can reduce multiples, improve signal-to-noise calculations, enable source deconvolution, and generate sediment acoustic velocities and acoustic impedance analysis. Synthetic seismograms based on empirical relationships among grain size distribution, density, and velocity from vibracores are used to calculate proxy values for density and velocity. The seismograms are then correlated to the digital seismic profile to confirm reflected events. They are particularly useful where individual reflection events cannot be detected but a waveform generated by several thin lithologic units can be recognized. Progress in application of geologic and geophysical methods provides advan tages in detailed sediment analysis and volumetric estimation of offshore sand ridges. New techniques for current and ongoing beach replenishment projects not only expand our knowledge of the geologic processes involved in sand ridge origin and development, but also improve our assessment of these valuable resources. These reconnaissance studies provide extensive data to the engineer regarding the suitability and quantity of sand and can optimize placement and analysis of vibracore samples.     

Hydrothermal sediments associated with a relict back-arc spreading center in the Shikoku Basin, recovered from the Nankai accretionary prism, Japan

The hemipelagic mudrocks of the Nankai accretionary prism, Japan, contain hydrothermal deposits associated with a relict spreading center in the Shikoku Basin. Initial work on core samples from Ocean Drilling Program site 808 found several samples with elevated concentrations of calcium, magnesium, iron and manganese, at depths of between 1060 and 1111 m below sea floor. However, the origin of these sediments was uncertain, due to a lack of data. There was no recorded evidence of whether these elevated concentrations were present throughout this interval of core, or if they were present as discrete layers with the background hemipelagic mudrocks in between. In the present study the core was resampled, and the sediments with anomalous chemical compositions were found to be present in discrete layers. This fact, along with a detailed interpretation of their geochemistry, has allowed them to be identified as hydrothermal sediments, associated with the relict spreading center in the Shikoku Basin. The lower (older) two layers display a chemical composition typical of umbers, while the upper (younger) two layers are metalliferous mudrocks typical of deposits found further from the spreading center.     

Conserving agricultural heritage systems through tourism: Exploration of two mountainous communities in China

Community plays an important role in the preservation of agricultural heritage system （AHS）. Recently, many AHS have been valorized as interesting resources for rural tourism. The expectations are that tourism development （TD） can be supportive for the conservation of AHS while creating benefits for local communities. In this study, two mountainous pilot villages （Longxian and Xiaohuang） in a global conservation project for traditional agricutural systems - Globally Important Agricultural Heritage Systems （GIAHS） were selected to identify the relationship between AHS conservation and TD. The study undertook in-depth interviews, and questionnaires of village residents and informal discussions with local villagers. A t-test and a linear regression model were implemented to explore the comparative dimensions of the two communities with different geographical location, economic situation, and stage of TD. The research found some similarities and differences in the two mountainous communities during AHS conservation and TD. Firstly, AHS are preservaed well in both villages unconsiously, while the residents in Xiaohuang value more highly the heritage elements than the respondents in Longxian, and the villagers in Xiaohuang are more worried about their heritage system; Secondly, both villages expect lots of benefits from TD and they clearly perceive more positive than negative impact from tourism and thus approve TD, while the hugedifferent perception on transportation and accessibility in the two villages reflects the bottleneck of TD in Xiaohuang village. At the same time, the respondents from Xiaohuang perceive more positive and fewer negative impact from tourism than the respondents from Longxian. Thirdly, the respondents in the two villages all show positive attitudes towards participation in tourism mostly motivated by the high income expectation. The main factors to determine the community perception in two villages were also analyzed based on the data process. A location-based coneeputal framework of AHS conservation in partnership with TD at community scale is proposed at the end of the paper. The dynamics of tourism development, that could enhance a better understanding of the complex relationship between conservation objectives and tourism development are discussed.     

Long-term impact of the proglacial lake Jökulsárlón on the flow velocity and stability of Breiðamerkurjökull glacier,Iceland

Proglacial lakes are becoming ubiquitous at the termini of many glaciers worldwide due to continued climate warming and glacier retreat, and such lakes have important consequences for the dynamics and future stability of these glaciers. In light of this, we quantified decadal changes in glacier velocity since 1991 using satellite remote sensing for Breiðamerkurjökull, a large lake-terminating glacier in Iceland. We investigated its frontal retreat, lake area change and ice surface elevation change, combined with bed topography data, to understand its recent rapid retreat and future stability. We observed highly spatially variable velocity change from 1991 to 2015, with a substantial increase in peak velocity observed at the terminus of the lake-terminating eastern arm from ~1.00 ± 0.36 m day⁻¹ in 1991 to 3.50 ± 0.25 m day⁻¹ in 2015, with mean velocities remaining elevated from 2008 onwards. This is in stark comparison to the predominately land-terminating arms, which saw no discernible change in their velocity over the same period. We also observed a substantial increase in the area of the main proglacial lake (Jökulsárlón) since 1982 of ~20 km², equating to an annual growth rate of 0.55 km² year⁻¹. Over the same period, the eastern arm retreated by ~3.50 km, which is significantly greater than the other arms. Such discrepancies between the different arms are due to the growth and, importantly, depth increase of Jökulsárlón, as the eastern arm has retreated into its ~300 m-deep reverse-sloping subglacial trough. We suggest that this growth in lake area, forced initially by rising air temperatures, combined with the increase in lake depth, triggered an increase in flow acceleration, leading to further rapid retreat and the initiation of a positive feedback mechanism. These findings may have important implications for how increased melt and calving forced by climate change will affect the future stability of large soft-bedded, reverse-sloped, subaqueous-terminating glaciers elsewhere. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd