Studies of backscattered sea return with a CW, dual-frequency,X-band radar

A coherent, CW, dual-frequency,X-band radar was used to study microwave sea return from the Chesapeake Bay. It is shown that the product of the backseattered fields depends strongly on long surface wave properties. In particular, a sharp line is found in the product power spectrum whose frequency is that of the water wave whose wavelength is in resonance with the spatial period of the beat frequency between the two transmitted signals and whose wave vector is parallel to the horizontal line of sight. Thus, gravity wave dispersion relations can be obtained with the system. Furthermore, the degree of modulation of short waves by long ones is given by the intensity of the line. A broad background corresponding to the convolution of the single-frequency Doppler spectra is also seen in the product power spectrum. These results are shown to be interpretable by composite surface scattering theory.     

Lacustrine oxygen isotope record of 20th-century climate change in central EuropeL evaluation of climatic controls on oxygen isotopes in precipitation

We report oxygen isotope data from a 108-yr (1885–1993) sequence with annual laminae of bio-induced authigenic calcite in a frozen core from Baldeggersee, a small lake in Central Switzerland. These isotope results provide proxy data on the isotopic composition of past precipitation in the Baldeggersee catchment region and are quantitatively compared with instrumental climate data (i.e. mean annual air temperature and atmospheric circulation pattern indices) to evaluate climatic controls on oxygen isotopes in precipitation.Monitoring the isotope hydrology of Baldeggersee demonstrates that the oxygen isotopic composition of the lake water is controlled by the isotopic composition of local atmospheric precipitation (¹⁸O_p) and that the isotopic signal of precipitation is preserved, albeit damped, in the lake calcite oxygen isotope record (¹⁸O_c). Comparison of the calcite oxygen isotope proxy for ¹⁸O_p in the catchment with historical mean annual air temperature measurements from Bern, Switzerland confirms that authigenic calcite reliably records past annual air temperature in the region. This ¹⁸O_c/temperature relationship is calculated to be 0.39/°C for the period 1900–1960, based on an isotope mass-balance model for Baldeggersee. An exception is a 0.8 anomalous negative shift in calcite ¹⁸O values since the 1960s. Possible explanations for this recent ¹⁸O_c shift, as it is not related to mean annual air temperature, include changes in ¹⁸O_p due to synoptic circulation patterns. In particular, the 0.8 negative shift coincides with a trend towards a more dominant North Atlantic Oscillation (NAO) index. This circulation pattern would tend to bring more isotopically more negative winter precipitation to the region and could account for the 0.8 offset in ¹⁸O_c data.     

The Chemical Evolution of the Universe on its Smallest Scales: Dust in Stars,Disks and Planets

D15 Dust and gas in the inner accretion disk around the Herbig star MWC 147 resolved with infrared spectro‐interferometry D21 The effective temperature of OGLE‐TR‐10 – The Balmer α line D29 Metal Injection into the Intracluster Medium D30 Eigenmodes of circumstellar dust shells D40 Numerical Modelling Approach of Circumstellar Dust Shells Around Pulsating AGB Stars Aiming at Multi Time Scale Processes D45 UV radiation induced CO molecule formation patterns in low density PDRs D46 IR properties of calcite and dolomite at low temperatures D47 Observations and Models of Dusty Giants – Past and Present D51 A multi‐method approach to the outer layers of AGB stars D53 On the convective energy transport in M‐type brown dwarf atmospheres D70 Structure and Dust Composition of the TW Hya Disc D75 Chemical Abundances in the Carina Dwarf Spheroidal Galaxy D76 Kinematic and chemical constraints on the formation of M31's inner halo structures D77 IR band profiles of silicate and oxide dust obtained by laboratory measurements of free‐flying particles D98 Dust particle growth in protoplanetary disks D134 Comparative study of dust cloud modelling for substellar atmospheres D137 Photometric study of neglected binary DV Psc D154 Quantitative Spectroscopy of Deneb D160 Hot subluminous Ostars from the SDSS D166 Simultaneous Observations of Solar Ca II H and Ca II 8662 lines and Numerical Simulation of these lines D182 Present‐day carbon abundances in the solar vicinity D189 Detection of a giant planet around a pulsating extreme horizontal branch star: the oldest known planet? D200 Confirmation of a very young binary brown dwarf candidate with disk in Chamaeleon D208 Galaxy ages and metallicities in the cluster A1314 D217 Charge‐dipole induced dust gelation – fastening the process of dust growth in protoplanetary disks D246 Protoplanetary Disk Structure and Evolution     

Iron, sulfur, and carbon diagenesis in sediments of Tomales Bay, California

Analysis of 3-m sediment cores revealed that profiles of carbon (C), sulfur (S), and iron (Fe) varied with relative distance from marine and terrestrial sediment sources in Tomales Bay California. Despite relatively high sedimentation rates throughout the bay (historically 3–30 mm yr⁻¹), sulfate reduction of deposited organic matter led to free-sulfide accumulation in sediments only at the location farthest from terrestrial runoff, the source of reactive iron. Acid-volatile sulfide concentrations in all sediments (<10 μmol g⁻¹) were low relative to concentrations of chromiumreducible sulfide (up to 400 μmol g⁻¹ farthest from the reactive iron source). A calculated index of iron availability, used to describe sediment resistance to build-up of free sulfide, was lowest at this location. Recent, upward shifts in reactive Fe concentration and in the relative contribution of terrestrial orgnic carbon (measured as a shift in δ¹³C of bulk sediment organic matter) in all cores indicated that erosion and transport of sediments from the watershed surrounding Tomales Bay increased after European settlement in the 1850s.     

A modelling framework to simulate field‐scale nitrate response and transport during snowmelt: The WINTRA model

Modelling nutrient transport during snowmelt in cold regions remains a major scientific challenge. A key limitation of existing nutrient models for application in cold regions is the inadequate representation of snowmelt, including hydrological and biogeochemical processes. This brief period can account for more than 80% of the total annual surface runoff in the Canadian Prairies and Northern Canada and processes such as atmospheric deposition, overwinter redistribution of snow, ion exclusion from snow crystals, frozen soils, and snow‐covered area depletion during melt influence the distribution and release of snow and soil nutrients, thus affecting the timing and magnitude of snowmelt runoff nutrient concentrations. Research in cold regions suggests that nitrate (NO₃) runoff at the field‐scale can be divided into 5 phases during snowmelt. In the first phase, water and ions originating from ion‐rich snow layers travel and diffuse through the snowpack. This process causes ion concentrations in runoff to gradually increase. The second phase occurs when this snow ion meltwater front has reached the bottom of the snowpack and forms runoff to the edge‐of‐the‐field. During the third and fourth phases, the main source of NO₃ transitions from the snowpack to the soil. Finally, the fifth and last phase occurs when the snow has completely melted, and the thawing soil becomes the main source of NO₃ to the stream. In this research, a process‐based model was developed to simulate hourly export based on this 5‐phase approach. Results from an application in the Red River Basin of southern Manitoba, Canada, shows that the model can adequately capture the dynamics and rapid changes of NO₃ concentrations during this period at relevant temporal resolutions. This is a significant achievement to advance the current nutrient modelling paradigm in cold climates, which is generally limited to satisfactory results at monthly or annual resolutions. The approach can inform catchment‐scale nutrient models to improve simulation of this critical snowmelt period.     

Hydrology of hillslope‐wetland streams,Polar Bear Pass,Nunavut, Canada

Polar Bear Pass is a large High Arctic low‐gradient wetland (100 km²) bordered by low‐lying hills which are notched by a series of v‐shaped valleys. The spring and summer hydrology of two High Arctic hillslope‐wetland catchments, a first‐order stream, 0·2 km² Landing Strip Creek (LSC) and a larger second‐order basin, 4·2 km² Windy Creek (WC), is described here. A water balance framework was employed in 2008 to examine the movement of water from upland reaches into the low‐lying wetland. Snowcover was low in both basins (<50 mm in water equivalent units), but they both exhibited nival‐type regimes. After the main snowmelt season ended, runoff ceased in the smaller catchment (LSC), but not at the larger basin (WC) which continued to flow throughout the summer. Both basins responded to summer rains in different ways. At LSC, late‐summer continuous streamflow occurred only when rainfall satisfied the large soil moisture deficit in the upper bowl‐shaped zone of the basin. At WC, the presence of thinly thawed, ice‐rich polygonal terrain within the stream channel and in the upper reaches of the catchment likely limited infiltration in these near‐stream zones and enhanced runoff in response to both moderate and high rainfall. Subsequently, seasonal runoff ratios differed between the two sites (0·19 vs 0·68) as did the seasonal storage + residual (+16 vs ?50 mm). This suggests that the post‐snowmelt season runoff response to summer precipitation is very much modified by the unique basin characteristics (soil‐type, vegetation, ground ice) and their location within each stream order type. Copyright © 2010 John Wiley & Sons, Ltd.     

The Community Economic Impacts of Large Wildfires: A Case Study from Trinity County,California

Wildfires are increasing in severity and frequency in the American West, but there is limited understanding of their economic effects at the community level. We conducted a case study of the impacts of large wildfires in 2008 in Trinity County, California, by examining labor market, suppression spending, and qualitative interview data. We found that the 2008 fires had interrelated effects on several economic sectors in the county. Labor market data indicated a decrease in total private-sector employment and wages and an increase in public-sector employment and wages during the summer of 2008 compared to the previous year, while interviews captured more nuanced impacts for individual businesses.     

Recent anthropogenic impact in ancient Lake Ohrid (Macedonia/Albania): a palaeolimnological approach

Ancient lakes, which are important centres of biodiversity and endemism, are threatened by a wide variety of human impacts. To assess environmental impact on ancient Lake Ohrid we have taken short sediment cores from two contrasting site locations, comprising a site of urban pollution and an apparently pristine area. Recent impacts on water quality and ecology were assessed using sediment, geochemical, ostracode, and diatom data derived from analysis of two ²¹⁰Pb-dated sediment cores spanning the period from 1918 to 2009. According to the index of geoaccumulation, sediments were often moderately contaminated with As. Fe and Ni concentrations often exceeded reported maximum limits above which harmful effects on sediment-dwelling organisms are expected. Productivity in the (pristine) south-eastern part of Lake Ohrid (Sveti Naum) is generally lower than in the north, probably due to the strong influence of spring discharge. Low ostracode and diatom concentrations, low abundance of the epilimnetic diatom Cyclotella ocellata, and low values of TOC and TIC indicate a lower productivity from the early 1920s to the late 1980s. Since the mid 1970s, increased relative abundance of C. ocellata and increasing diatom concentration indicate increasing productivity in the south-eastern part. Rising numbers of ostracode valves and higher TIC and TOC contents in both sediment cores indicate an increase in productivity during the late 1980s. A slight increase in productivity near Sveti Naum continued from the early 1990s until 2009, witnessed by rising TC, TIC, and TOC content and a generally high number of ostracode valves and ostracode diversity. The area near the City of Struga (site of urban pollution) is also characterized by rising TOC and TIC contents and, furthermore, by increasing Cu, Fe, Pb, and Zn concentrations since the early 1990s. The recent reduction in the number of ostracode valves and ostracode diversity is probably caused by a higher heavy metal load into the lake. This suggests that living conditions for the endemic species in Lake Ohrid have become less favourable in the northern part of the lake, which might threaten the unique flora and fauna of Lake Ohrid.     

Determination of the aromaticity and the degree of aromatic condensation of a thermosequence of wood charcoal using NMR

Quantifying the role of black carbon (BC) in geochemical processes is difficult due to the heterogeneous character of its chemical structure. Chestnut wood charcoal samples produced at heat treatment temperatures (HTT) from 200-1000 °C were analysed using two different solid state ¹³C NMR techniques. First, aromaticity was determined as the percentage of total signal present in the aromatic region of ¹³C direct polarisation (DP) spectra. This was found to increase through the low temperature range of 200-400 °C; at higher temperatures, aromaticity was found to be >90%. Second, aromatic condensation was determined through the measurement of the chemical shift of ¹³C_benzene sorbed to the charcoals, which is influenced by the presence of “ring currents” in the aromatic domains of the charcoals. This technique was less sensitive to molecular changes through the lower temperature range, but showed there was a smooth increase in the degree of condensation of the aromatic structures with increasing temperature through the temperature range 400-1000 °C. Ab initio molecular modelling was used to estimate the size of aromatic domains in the charcoals based on the strength of the ring currents detected. These calculations indicated that charcoals produced at temperatures below 500 °C contain aromatic domains no larger than coronene (7 ring). At higher temperatures the size of these domains rapidly increases, with structures larger than a 19 ring symmetrical PAH being predominant in charcoals produced at temperatures above 700 °C. Data from this study were found to be generally consistent with previously published measurements using the benzenepolycarboxylic acid (BPCA) molecular marker method on the same set of samples.     

A Long-Term Study of Spawning Activity in a Florida Gulf Coast Population of Horseshoe Crabs (<Emphasis Type="BoldItalic">Limulus polyphemus</Emphasis>)

Populations of the American horseshoe crab (Limulus polyphemus) differ in broad areas of their biology. We observed a non-harvested, marked Florida Gulf coast population during their spring spawning (March–May) in 11 years across a 17-year period (1992–2009). Long-term changes occurred in the number of spawning pairs: the population was stable from 1992 to 2000 but increased markedly after 2000. Short-term variation in numbers of spawning pairs, unpaired females, unpaired males, and operational sex ratios was explained by changes over the season and during each week of spring tides and by differences in actual (not predicted) maximum high tide height. Wind direction strongly affected tidal inundation and the number of spawning horseshoe crabs. Tagging individuals revealed that females returned to the nesting beach less often than males and most females were re-sighted only within 1 week of spring tides. No animals were seen across more than 6 years. Implications for management are discussed.