Millstone Hill Thomson scatter results for 1966 and 1967

Thomson (incoherent) scatter radar measurements of F-region electron densities and temperatures were made approximately twice per month throughout 1966 and 1967 at Millstone Hill for periods of 24 hr. Owing to the increase in sunspot activity the results display a rich variety of different types of behaviour. Geomagnetically quiet days tended to follow patterns observed near sunspot minimum. Thus in winter there is typically a marked diurnal variation in electron density with a peak near noon and often a smaller secondary maximum between 02 and 04 EST. In summer there is less day-to-night variation and the peak density is encountered near ground sunset. Usually h_maxF2 is higher in summer than winter and the layer thickness is larger also.Some magnetically disturbed days follow a distinct pattern in which N_max and h_max are normal during the first day of the storm until afternoon when they both increase to very high values. There is then a corresponding decrease in electron temperature. During the night the electron temperature often reaches abnormally high values, providing evidence of nocturnal heating. On the following day N_max and h_max are abnormally low.During 1967 instances in which the trough of low electron density moved south to occupy a position over Millstone became frequent. The electron temperature rose to particularly high values on these occasions. These morphological features are discussed in terms of current theoretical ideas. The results are also employed to derive seasonal variations of electron temperature and protonospheric heat flux. It is shown that since 1964 the protonospheric heat flux has been larger in winter than summer and displays a clear sunspot cycle variation.     

A geomagnetic secular variation study (31000–19 500 bp) in Western Canada

Summary. Palaeomagnetic results from 212 horizons spread evenly through an 18 m sedimentary sequence in southern British Columbia are reported. Radiocarbon ages suggest that the sequence spans the interval from 31 200 to 19 500 yr bp. No evidence for any large geomagnetic excursions (such as the so-called Mono Lake Excursion) is found, but a distinctive pattern of 'normal' secular variation is observed with declination and inclination swings of 45° and 25° peak to peak amplitude respectively. For the most part the secular variation consists of low amplitude oscillations about the field vector of a geocentric axial dipole expected at the site latitude, but three relatively large perturbations occur at approximately 4000 yr intervals. These perturbations systematically bias the overall mean to shallow inclinations and easterly declinations in a manner reminiscent of the spatially non-isotropic secular variation model proposed by Cox. The bias involved is about 6° in declination and 3° in inclination (overall mean D = 5.8°E, I = 64.2°, α95 = 0.9°, N = 212 horizons), which leads to a pole which is both 'far-sided' and 'right-handed'. If the horizons involved in the three major perturbations are eliminated the mean direction ( D = 1.2°E, I = 67.2°, α95 = 0.8°, N = 125 horizons) does not differ from that of a geocentric axial dipole despite the small cone of confidence.     

Weathering of sulfidic shale and copper mine waste: secondary minerals and metal cycling in Great Smoky Mountains National Park,Tennessee, and North Carolina,USA

Metal cycling via physical and chemical weathering of discrete sources (copper mines) and regional (non-point) sources (sulfide-rich shale) is evaluated by examining the mineralogy and chemistry of weathering products in Great Smoky Mountains National Park, Tennessee, and North Carolina, USA. The elements in copper mine waste, secondary minerals, stream sediments, and waters that are most likely to have negative impacts on aquatic ecosystems are aluminum, copper, zinc, and arsenic because these elements locally exceed toxicity guidelines for surface waters or for stream sediments. Acid-mine drainage has not developed in streams draining inactive copper mines. Acid-rock drainage and chemical weathering processes that accompany debris flows or human disturbances of sulfidic rocks are comparable to processes that develop acid-mine drainage elsewhere. Despite the high rainfall in the mountain range, sheltered areas and intermittent dry spells provide local venues for development of secondary weathering products that can impact aquatic ecosystems.Electronic Supplementary Material  Supplementary material is available for this article if you access the article at . A link in the frame on the left on that page takes you directly to the supplementary material.

Improved approaches to ecotoxicity testing of petroleum products

Crude oils produced in the North West shelf of Western Australia are highly volatile, a characteristic not shared by most of the Northern Hemisphere crude oils on which internationally accepted toxicity test protocols were developed. Because of this volatility and some other factors, the LC50 and EC50 values obtained from acute toxicity tests will be significantly affected by the changes of toxicant concentration in test solutions during the period of exposure. To address these issues all steps of a standard protocol for crude oil toxicity testing have been revised. A systematic study has been performed on factors which affect petroleum hydrocarbon solubilisation in aqueous systems during test solution preparations. The influence of mixing time, agitation energy and volume/interface ratio on a hydrocarbon concentration in a water-soluble fraction (WSF) was studied for heavy, medium and light crude oils. A study of the sensitivity of marine unicellular algae to WSF of crude oils was conducted with Isochrysis sp., Nannochloropsis-like sp. and Nitzchia closterium. Total concentrations of hydrocarbons dissolved in test solutions were estimated by UV-spectrometry and GC/FID chemical analyses. When the toxicant concentration decreased during the exposure period, the EC50 values derived from initial or final concentrations either underestimate or overestimate toxicity, respectively. Therefore, weighted average concentrations (WAC) calculated for the whole test period were recommended for expressing hydrocarbon concentrations in test solutions of crude oils. Toxicity indices calculated from WAC of total hydrocarbons for different crude oils can be compared regardless of the rates of hydrocarbon loss.     

The effect of organic materials on the mobility and toxicity of metals in contaminated soils

Organic materials such as compost are often proposed as suitable materials for the remediation of contaminated brownfield sites intended for soft end-use. In addition to vitalising the soil, they are also believed to immobilise metals thereby breaking contaminant-receptor pathways and reducing the ecotoxicity of the contaminants. However, some research has demonstrated contradictory effects between composts on metal immobilisation. In the present study, four different composts and a liming product containing organic matter (LimeX70) were tested to examine both their metal retention and toxicity reduction capabilities on three different metal contaminated soils. Leaching tests, a plant growth test with Greek cress (Lepidium sativum), an earthworm (Eisenia fetida) survival and condition test and a bacterial toxicity test using Vibrio fischeri were carried out. The leaching test results showed that spent mushroom compost caused an increase in metal concentration in the leachates, while LimeX70 caused a decrease. The variation in behaviour between different amendments for each soil was high, so a generic conclusion could not be drawn. Toxicity tests showed significant reduction of metal bioavailability and toxicity for Greek cress, earthworms and bacteria. The results also suggest that more research should be undertaken to understand the mechanisms involved in metal complexation using different types of organic matter, in order to optimise the use of organic materials like compost for soil remediation.     

Rapid quantification of humic and fulvic acids by HPLC in natural waters

A simple method based on high-performance size-exclusion chromatography (HPSEC) has been developed for rapid quantification of humic and fulvic acids (HA and FA) in stream waters. A Tsk-gel column was used to separate natural dissolved organic matter (DOM) into two components: peak A and B. In terms of HPSEC chromatograms and fluorescence patterns, peak A and B were similar to the corresponding XAD-extracted HA and FA, respectively. It is suggested that peak A fraction mainly consisted of HA, and peak B fraction FA. The similar separation of HA and FA using HPSEC and a conventional XAD method suggests the consistency of molecular size distribution and physical–chemical properties of DOM. HPSEC offers a simple and rapid method for the quantification of HA and FA instead of tedious extractions of humic substances. Analyses of natural water samples show that the calculation of HA/FA based on UV absorbance was under- or over-estimated, the calibration using the extracted HS allows a more accurate quantification. The fast screening of HA and FA provides useful quantitative and qualitative information that can be used in environmental or monitoring studies.     

Anglo-Saxon animal husbandry techniques revealed though isotope and chemical variations in cattle teeth

The Sr concentration and isotope composition of tooth enamel from domesticated animals from two neighbouring Anglo-Saxon settlements, at Empingham (6–7th century) and Ketton (10–12th century) in Rutland, central England, are compared both with each other, and with associated human populations. Data from the Empingham II site form discrete fields in Sr concentration and isotope composition space for cattle, pig and sheep with a partial overlap of the human and pig fields. By contrast there is significant overlap in all the animal and human data fields from the Ketton site. The differences in data distribution between the two sites are attributed to animal husbandry techniques, as the surface geology of the two areas is very similar, implying geological factors are an unlikely cause of the difference. It is suggested that the grazing and feeding patterns of animals at the Empingham II site were controlled and restricted, whereas at the Ketton site the animals grazed and foraged freely over a common area.     

Caledonian eclogite-facies metamorphism of Early Proterozoic protoliths from the North-East Greenland Eclogite Province

High-pressure metamorphic assemblages occur in mafic, ultramafic and a few intermediate rocks in a gneiss complex that covers an area of approximately 400 × 100 km in the North-East Greenland Caledonides. Detailed petrologic and geochronologic studies were carried out on three samples in order to clarify the P-T-t evolution of this eclogite province. Geothermobarometry yields temperature estimates of 700–800 °C and pressure estimates of at least 1.5 GPa from an eclogite sensu stricto and as high as 2.35 GPa for a garnet websterite. The eclogite defines a garnet-clinopyroxene-amphibole-whole rock Sm-Nd isochron age of 405 ± 24 Ma (MSWD 0.9). Isofacial garnet websterites define garnet-clinopyroxene-orthopyroxene-amphibole-whole rock-(biotite) ages of 439 ± 8 Ma (MSWD =2.1) for a coarse-grained sample and 370 ± 12 Ma (MSWD=0.6) for a finer-grained variety. Overgrowths on zircons from the fine-grained pyroxenite and the eclogite give a pooled ²⁰⁶Pb/²³⁸U SHRIMP age of 377 ± 7 Ma (n=4). Significantly younger Rb-Sr biotite ages of 357 ± 8, 330 ± 6 and 326 ± 6 agree with young Rb-Sr, K-Ar and ⁴⁰Ar/³⁹Ar mineral ages from the gneiss complex and indicate slow cooling of the eclogitic rocks. High-pressure metamorphism may have been at least 439 Ma old (Siluro-Ordovician) with cooling through amphibolite-facies conditions in the Devonian and continued crustal thinning and exhumation well into the Carboniferous. Sm-Nd whole rock model ages indicate the eclogite protoliths are Early Proterozoic in age, while ²⁰⁷Pb/²⁰⁶Pb SHRIMP ages of 1889 ± 18 and 1981 ± 8 from anhedral zircon cores probably reflect Proterozoic metasomatism. The samples have negative ɛ_Nd values (−5 to −16) and elevated ⁸⁷Sr/⁸⁶Sr ratios (0.708–0.715), consistent with field evidence that the eclogite protoliths were an integral part of the continental crust long before Caledonian metamorphism. The presence of a large Caledonian eclogite terrane in Greenland requires modification of current tectonic models that postulate subduction of Baltica beneath Laurentia during the Caledonian orogeny. Received: 9 October 1996 / Accepted: 7 July 1997     

Recrystallization of Magnesian Calcite Overgrowths on Calcite SeedsSuspended in Seawater

The formation and subsequent reactions of magnesiancalcite overgrowths on calcite were investigated bymeans of closed system seeded precipitationexperiments. These experiments demonstrated that(1) thin overgrowths of magnesian calcite are precipitatedon calcite seeds suspended in seawater;(2) the solubilities of the coatings increase outward from theseed crystals as a linear function of the log ofrelative coating thickness;(3) during the period ofthese experiments (up to 5.5 months), the magnesiancalcite coatings continued to increase in thickness,but became less soluble in composition. Thestabilization reaction, referred to asrecrystallization, can be described by the followingequation:Cax Mg(1-x) CO3 + [z + y(x + z)]Ca2++ 2yHCO3- ]= (1 + y)Ca(x + z)Mg(1 - x -z)CO3 + [z + y(x + z - 1)]Mg2++ y CO2 + yH20;]4) recrystallization rate is dependent on solutionsaturation state, with a reaction order of 3.2 forartificial seawater and 4.0 for natural seawater; and(5) by the cessation of the closed system experiments,overgrowth compositions approached that of the stablecalcite (a few mol % MgCO3).Armoring of suspended carbonate particles in thesurface oceans with magnesian calcite overgrowthswould provide an effective barrier to release of theoceanic supersaturation with respect to calcite. Thicknesses of such coatings would be limited by therecrystallization rate of the magnesian calcite. Estimates based on the recrystallization ratesdetermined in this work indicate coatings on the orderof 0.02 µm in thickness could form on particles asthey sink through the mixed layer. According to thesecalculations, the total amount of carbon precipitatedannually in magnesian calcite overgrowths iscomparable to the riverine flux of dissolved carbon tothe oceans. Field observations of severalinvestigators indicate the likely presence ofmagnesian calcite coatings on planktonic particles,and provide evidence for possible recrystallization ofbiogenic magnesian particles in the marineenvironment.     

Stability of power-law discs — II. The global spiral modes

This paper reports on the in-plane normal modes in the self-consistent and the cut-out power-law discs. Although the cut-out discs are remarkably stable to bisymmetric perturbations, they are very susceptible to one-armed modes. For this harmonic, there is no inner Lindblad resonance, thus removing a powerful stabilizing influence. A physical mechanism for the generation of the one-armed instabilities is put forward. Incoming trailing waves are reflected as leading waves at the inner cut-out, thus completing the feedback for the swing-amplifier. Growing three-armed and four-armed modes occur only at very low temperatures. However, neutral m  = 3 and m  = 4 modes are possible at higher temperatures for some discs. The rotation curve index β has a marked effect on stability. For all azimuthal wavenumbers, any unstable modes persist to higher temperatures and grow more vigorously if the rotation curve is rising (β < 0) than if the rotation curve is falling (β > 0). If the central regions or outer parts of the disc are carved out more abruptly, any instabilities become more virulent. The self-consistent power-law discs possess a number of unusual stability properties. There is no natural time-scale in the self-consistent disc. If a mode is admitted at some pattern speed and growth rate, then it must be present at all pattern speeds and growth rates. Our analysis — although falling short of a complete proof — suggests that such a two-dimensional continuum of non-axisymmetric modes does not occur and that the self-consistent power-law discs admit no global non-axisymmetric normal modes whatsoever. Without reflecting boundaries or cut-outs, there is no resonant cavity and no possibility of unstable growing modes. The self-consistent power-law discs certainly admit equi-angular spirals as neutral modes, together with a one-dimensional continuum of growing axisymmetric modes.