Occurrence and exploration of gas hydrate in the marginal seas and continental margin of the Asia and Oceania region

Supplies of conventional natural gas and oil are declining fast worldwide, and therefore new, unconventional forms of energy resources are needed to meet the ever-increasing demand. Amongst the many different unconventional natural resources are gas hydrates, a solid, ice-like crystalline compound of methane and water formed under specific low temperature and high pressure conditions. Gas hydrates are believed to exist in large quantities worldwide in oceanic regions of continental margins, as well as associated with permafrost regions in the Arctic. Some studies to estimate the global abundance of gas hydrate suggest that the total volume of natural gas locked up in form of gas hydrates may exceed all known conventional natural gas reserves, although large uncertainties exist in these assessments. Gas hydrates have been intensively studied in the last two decades also due to connections between climate forcing (natural and/or anthropogenic) and the potential large volumes of methane trapped in gas hydrate accumulations. The presence of gas hydrate within unconsolidated sediments of the upper few hundred meters below seafloor may also pose a geo-hazard to conventional oil and gas production. Additionally, climate variability and associated changes in pressure-temperature regimes and thus shifts in the gas hydrate stability zone may cause the occurrence of submarine slope failures.Several large-scale national gas hydrate programs exist especially in countries such as Japan, Korea, Taiwan, China, India, and New Zealand, where large demands of energy cannot be met by domestic supplies from natural resources. The past five years have seen several dedicated deep drilling expeditions and other scientific studies conducted throughout Asia and Oceania to understand gas hydrates off India, China, and Korea. This thematic set of publications is dedicated to summarize the most recent findings and results of geo-scientific studies of gas hydrates in the marginal seas and continental margin of the Asia, and Oceania region.     

Foraminifera from the continental slope off Cape Hatteras, North Carolina

The recent benthic meiofaunal foraminiferal assemblage from the continental slope (590-2 003 m) off Cape Hatteras, North Carolina exhibits high species richness and evenness, moderate diversity values, and lacks numerically dominant species. The preserved planktic assemblage has relatively low species richness, high evenness, low diversity, and a few numerically dominant species. Approximately 9% of the benthic species are those that typically live within continental shelf depth ranges. The benthic assemblage abundances and diversities do not follow depth patterns or geophysical characteristics. No biogeographic boundary can be described within the study area for meiofaunal foraminifera. Oxygen limitation does not appear to be a factor affecting the benthos of the North Carolina continental slope based upon the community structure of the benthic foraminifera, if total assemblage is assumed to reflect the recently living community. The high carbonate content of sediments in the area may be explained by foraminiferal tests. Within the study area, the foraminiferal assemblages are uniform, and probably reflect relative consistency of primary environmental variables as well as dynamic downslope transport and high influx of material from the water column in the vicinity where the Gulf Stream and the Western Boundary Undercurrent cross.     

Wave-induced surge motion of a tension leg structure

An analytical solution for the coupling problem of a two-dimensional tension leg structure interacting with a monochromatic linear wave train in an inviscid and incompressible fluid is presented. The tension legs are considered to be linearly elastic. The flow is further assumed to be irrotational and single-valued velocity potentials can then be defined.The boundary value problem is incorporated into a scattering and a radiation problem. The boundary value problems are then solved separately and combined to resolve all unknowns. The complete solutions of the velocity potentials are represented by the series of eigen-functions, and the surge motion of the structure is described in terms of the incident wave properties.The analytical solution is compared with a computer-coded numerical solution utilizing the boundary element method. The solutions agree very well, and both predict a resonant frequency for a specific structure which is different from the natural frequency of the structure due to the presence of the evanescent waves caused by the structure.     

Measurement of the redox speciation of iron in seawater by catalytic cathodic stripping voltammetry

Catalytic cathodic stripping voltammetry (CSV) preceded by adsorptive collection of complexes of 1-nitroso-2-napthol (NN) can be used to determine iron in seawater. It is shown here that iron(II) is effectively masked in the presence of 2,2-dipyridyl (Dp) so that iron(III) is measured selectively. The concentration of iron(II) is then calculated as the difference between the concentrations of reactive iron (Fe_R) in the absence and presence of 2 μM Dp, Fe_R being defined as that which was complexed by 20 μM NN at pH 6.9 in the presence of 1.8 mM H₂O₂ and 5 ppm sodium dodecyl sulphate. A 30 min reaction time was allowed for Dp to react with iron(II) in seawater prior to the determination of reactive iron(III) using the same conditions as used for Fe_R. Detection limits of 0.08 nM, 0.077 nM and 0.12 nM were obtained for Fe_R, iron(III) and iron(II), respectively, using a 60 s deposition time.The method was utilised to determine the redox speciation of iron in the northern North Sea. Concentrations of Fe_R ranged between 0.8 and 3.5 nM with nutrient-like depth profiles. Iron(II) was found to be present at concentrations up to 1.2 nM, the highest concentrations occurring in the upper 20 m of the water column.     

Risk of dike failure due to flow slides

Flow slides may affect the stability of dikes. A flow slide is an instability of a submerged slope caused by liquefaction of loose, (medium) fine sand. Whether a flow slide will occur depends on the properties of the sand, which are a function of its density, and the geometry of the slope, as determined by wave and current induced scour and sedimentation. The influence of sand properties and the geometry parameters on the risk of flow slides are discussed. The application of a flow slide prediction method to an example and a risk analysis is briefly discussed.     

Last glacial sea-level changes and paleogeography of the Korea (Tsushima) Strait

The Korea (Tsushima) Strait is an important seaway through which the warm Tsushima Current flows into the East Sea (Japan Sea). A paleogeographic map constrained by a regional sea-level curve developed on the basis of a number of recent ¹⁴C radiocarbon dates suggests that the Korea Strait was not closed during the last glacial period. Rather, it was open as a channel-like seaway linking the western North Pacific and the East Sea. Some fraction of the paleo-Tsushima Current inflow presumably continued at that time through the Korea Strait. The activity of the paleo-Tsushima Current is evidenced by the distribution pattern of river-derived lowstand deposits, consisting of a beach/shoreface complex and lowstand deltaic wedges. Received: 16 April 1999 / Revision accepted: 25 February 2000     

An inventory of factors that affect polysaccharide production by Phaeocystis globosa

Phaeocystis material contains polysaccharides that are built from at least eight different monosaccharides. Differences have been reported between the carbohydrate composition of different Phaeocystis species, and also between samples taken from Phaeocystis globosa blooms in different areas. In order to elucidate factors that could play a role in determining variation in carbohydrate composition and production, a number of Phaeocystis globosa strains were studied under laboratory conditions. Although there was a clear distinction of a northern and a southern cluster in the Phaeocystis globosa strains based on RAPD analysis, the differences in the composition of the mucopolysaccharides were relatively small. The contribution of glucose, however, ranged from 7–85% of total sugars. A strain that was cultured in seawaters of diverse origin produced polysaccharides of a different composition, suggesting the effect of environmental factors. The presence of bacteria affected neither the amount, nor the composition of the carbohydrates that were produced by Phaeocystis globosa. Glucose is part of both the intracellular polysaccharide pool and of the mucopolysaccharides in the colony matrix. Using specific digestion of the intracellular chrysolaminaran by laminarinase, the distribution of polysaccharides over different pools could be assessed. During growth of an axenic, mucus-producing strain, the portion of glucose present as chrysolaminaran appeared to increase. The polyglucose that was not digested by laminarinase remains unidentified. This study shows that environmental factors rather than strain differences determine differences in the sugar composition of Phaeocystis globosa, especially with respect to the glucose content of the material. A difference in the contribution of glucose could be correlated to the portion of cells in the culture that are not in the colonies. Our study emphasises that for studying polysaccharide dynamics in Phaeocystis globosa it is important to be able to discriminate between the different polysaccharide pools. Preliminary results of an enzymatic approach were promising     

Seasonal circulation in the southeastern Huanghai Sea

The seasonal circulation in the southeastern Huanghai Sea has been studied with hydrographic data,which were observed in February and June 1994 and bimonthly during 1970-1990,and numerical model results.Horiwntal distributions of temperature and salinity in 1994 are quite different due to strong tidal mixing so that we need a analysis to see the real distributions of water masses.The mixing ratio analysis with the data of 1970-1990 shows the connection of the waters in the west coasts of Kotea Peninsula with warm and saline waters from the south in summer,which means northward inflows along the west coasts of Korea Peninsula in summer.With this flow,the seasonal circulations,which are deduced from the seasonal change of water mass distributions in the lower layer,are warm inflows in winter and mld outflows in summer in the central Huanghai Sea,and cold outflows in winter and warm inflows in summer along the west coasts of Korea Peninsula.The seasonally changed inflows might be the Huanghai Sea Warm Current.The monsoon winds can drive such circulations.However,summer monsoon winds are weak and irregular.As one of other possible dynamics,the variation of Kuroshio transport is numerically studied with allowing sea level fluctuations.Although it should be studied more,it possibly drives the summer circulations.The real circulations seem to be driven by both of them.