Post‐orogenic evolution of the southern Pyrenees: constraints from inverse thermo‐kinematic modelling of low‐temperature thermochronology data

The late‐stage evolution of the southern central Pyrenees has been well documented but controversies remain concerning potential Neogene acceleration of exhumation rates and the influence of tectonic and/or climatic processes. A popular model suggests that the Pyrenees and their southern foreland were buried below a thick succession of conglomerates during the Oligocene, when the basin was endorheic. However, both the amount of post‐orogenic fill and the timing of re‐excavation remain controversial. We address this question by revisiting extensive thermochronological datasets of the Axial Zone. We use an inverse approach that couples the thermo‐kinematic model Pecube and the Neighbourhood inversion algorithm to constrain the history of exhumation and topographic changes since 40 Ma. By comparison with independent geological data, we identified a most probable scenario involving rapid exhumation (>2.5 km Myr^?1) between 37 and 30 Ma followed by a strong decrease to very slow rates (0.02 km Myr^?1) that remain constant until the present. Therefore, the inversion does not require a previously inferred Pliocene acceleration in regional exhumation rates. A clear topographic signal emerges, however: the topography has to be infilled by conglomerates to an elevation of 2.6 km between 40 and 29 Ma and then to remain stable until ca. 9 Ma. We interpret the last stage of the topographic history as recording major incision of the southern Pyrenean wedge, due to the Ebro basin connection to the Mediterranean, well before previously suggested Messinian ages. These results thus demonstrate temporally varying controls of different processes on exhumation: rapid rock uplift in an active orogen during late Eocene, whereas base‐level changes in the foreland basin control the post‐orogenic evolution of topography and exhumation in the central Pyrenees. In contrast, climate changes appear to play a lesser role in the post‐orogenic topographic and erosional evolution of this mountain belt.     

Dissociative excitation of SO2 by controlled electron impact

The fragmentation of SO₂ following dissociative electron impact excitation has been studied under single collision conditions for incident electron energies up to 500 eV. The emission spectrum in the far v.u.v. spectral range (450–1100Å) shows many features arising from excited neutral oxygen and ionized oxygen and sulphur fragments. Absolute emission cross sections have been measured for the most intense lines and the maximum values were found to range from 1–12 × 10^?19 cm² with an uncertainty of approx. ± 35%. Dissociation mechanisms are discussed and in some cases the dissociation path could be uniquely identified. The striking differences between the v.u.v. emission spectrum produced by single step dissociation of SO₂ and the spectra emitted by the plasma torus around Jupiter are discussed.     

Twisted Flux Tube Emergence Evidenced in Longitudinal Magnetograms: Magnetic Tongues

Bipolar active regions (ARs) are thought to be formed by twisted flux tubes, as the presence of such twist is theoretically required for a cohesive rise through the whole convective zone. We use longitudinal magnetograms to demonstrate that a clear signature of a global magnetic twist is present, particularly, during the emergence phase when the AR is forming in a much weaker pre-existing magnetic field environment. The twist is characterised by the presence of elongated polarities, called “magnetic tongues”, which originate from the azimuthal magnetic field component. The tongues first extend in size before retracting when the maximum magnetic flux is reached. This implies an apparent rotation of the magnetic bipole. Using a simple half-torus model of an emerging twisted flux tube having a uniform twist profile, we derive how the direction of the polarity inversion line and the elongation of the tongues depend on the global twist in the flux rope. Using a sample of 40 ARs, we verify that the helicity sign, determined from the magnetic polarity distribution pattern, is consistent with the sign derived from the photospheric helicity flux computed from magnetogram time series, as well as from other proxies such as sheared coronal loops, sigmoids, flare ribbons and/or the associated magnetic cloud observed in situ at 1 AU. The evolution of the tongues observed in emerging ARs is also closely similar to the evolution found in recent MHD numerical simulations. We also found that the elongation of the tongue formed by the leading magnetic polarity is significantly larger than that of the following polarity. This newly discovered asymmetry is consistent with an asymmetric Ω-loop emergence, trailing the solar rotation, which was proposed earlier to explain other asymmetries in bipolar ARs.     

Automated mapping of rock slope geometry,kinematics and stability with RSS-GIS

A GIS-implemented, deterministic approach for the automated spatial evaluation of geometrical and kinematical properties of rock slope terrains is presented. Based on spatially distributed directional information on planar geological fabrics and DEM-derived topographic attribute data, the internal geometry of rock slopes can be characterized on a grid cell basis. For such computations, different approaches for the analysis and regionalization of available structural directional information applicable in specific tectonic settings are demonstrated and implemented in a GIS environment. Simple kinematical testing procedures based on feasibility criteria can be conducted on a pixel basis to determine which failure mechanisms are likely to occur at particular terrain locations. In combination with hydraulic and strength data on geological discontinuities, scenario-based rock slope stability evaluations can be performed. For conceptual investigations on rock slope failure processes, a GIS-based specification tool for a 2-D distinct element code (UDEC) was designed to operate with the GIS-encoded spatially distributed rock slope data. The concepts of the proposed methodology for rock slope hazard assessments are demonstrated at three different test sites in Germany.     

Evaluation of the Presence of Methane in Złoczew Lignite: Comparison with Other Lignite Deposits in Poland

Natural Resources Research - Catastrophic cases of methane explosion during exploratory drilling within the Be?chatów ortholignite deposit have led to testing for methane in other Polish...     

Reduction of inorganic compounds in autoclaves by using suspended cellulose

Autoclaves are closed vessels in which liquids can be heated above their ‘normal' boiling points. As a consequence the pressure will rise. This equipment has permitted a variety of processes like the syntheses of organics and the leaching of metal ores. Pressure technologies can be used for accelerating reactions, for specific syntheses or they offer an environmental or economical alternative for existing processes. Wet pressure oxidation of sewage sludge, an organic waste product, has become a proven technology. If less oxygen is added than stoichiometrically required for a complete oxidation, cellulose will break down by a different reaction mechanism, releasing electrons. Under these circumstances reduction of inorganic compounds is possible.     

Fluid inclusion and cathodoluminescence studies on fluorite from the Kerio valley, Kenya

The Kerio valley lies between the Elgeyo escarpment and the Tugen hills which mark the western margin of the Kenya rift valley. The main fluorite deposits are located in the southern part of the valley at Kimwarer, Choff and Kamnaon.Three types of inclusion fillings were identified: Liquid+Vapour, Liquid+Daughter Minerals and Liquid. The L+V type is dominant. Inclusions occur as clusters, trails along the crystal growth zones and as isolated ones. Low salinities, apparently lower than the 5% wt. NaCl equivalent, were established. Homogenization temperatures suggest that fluorite mineralization took place at different stages and at temperatures between 120 and 180 °C. Isolated readings above 180°C may be referring to the original inclusions in limestone. These measurements and the absence of CO₂ in the inclusions, as well as the occurrence of vugs and crustifications with fluorite, suggest that mineralization took place at relatively shallow depths.Emission spectrum lines representing Eu²⁺, Dy³⁺, Tb³⁺ and Sm³⁺ in fluorite were identified. Sm³⁺ was detected only in the pinkish luminescence of veined fluorite, whereas the pinkish zone in banded fluorite contains Tb³⁺. Eu²⁺ which gives the strongest emission lines in the blue part of the visible spectrum, apparently is responsible for the strong blue cathodoluminescence (CL) in fluorite. The dominance of Eu²⁺ peaks further points to the fact that fluorite mineralization in the Kerio valley took place in an environment that was enriched in Lanthanide Rare Earth Elements (LREE). The presence of rare earths and radioactive elements in fluorite points towards their enrichment in the environment of fluorite mineralization. A juvenile origin of mineral forming solutions is proposed.Two generations of fluorite were established: allotriomorphic fluorite, forming the matrix, and the idiomorphic variety, occurring either in barite or in druzes in early fluorite. Barite in turn forms idiomorphic crystals in allotriomorphic fluorite. Relics of calcite occur in both K-feldspars and in early fluorite. Oxides and hydroxides of Fe, Mn, Ti and Al commonly occur in open spaces in fluorite. Of significance is the presence of gold in fluorite. Fluorite mineralization is of hydrothermal origin in the post-Miocene era and was formed as a result of metasomatic replacement of marble and open space fillings.