Constraining Holocene sea levels using U‐Th ages of phreatic overgrowths on speleothems from coastal caves in Mallorca (Western Mediterranean)

Phreatic overgrowths on speleothems (POS) are carbonate formations deposited at the water table of caves in unique karstic coastal settings having morphologies that can be directly related to sea level at the time of formation. The U‐Th ages of calcite and aragonite overgrowths collected from the modern water table in coastal caves on Mallorca (Cova de Cala Varques A and Cova des Pas de Vallgornera) were determined using high‐precision MC‐ICPMS techniques. U‐Th ages indicate that phreatic carbonate deposition occurred between ca 2·8 and at least 0·6 ka BP and are in accord with an archeologically estimated age of 3·7–3·0 ka BP for a drowned prehistoric construction at a depth of 1 m below current sea level in a cave from the same area. Speleothem δ¹³C and δ¹⁸O and chemical composition of cave pools provide supportive evidence that POS reflect mixing between seawater and brackish water table. Copyright © 2010 John Wiley & Sons, Ltd.     

Diurnal asymmetry of radio wave absorption on anomalous winter days

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Reconstruction of paleocoastlines for the northwestern South China Sea since the Last Glacial Maximum

The range of relative sea level rise in the northwestern South China Sea since the Last Glacial Maximum was over 100 m. As a result, lowland regions including the Northeast Vietnam coast, Beibu Gulf, and South China coast experienced an evolution from land to sea. Based on the principle of reconstructing paleogeography and using recent digital elevation model, relative sea level curves, and sediment accumulation data, this paper presents a series of paleogeographic scenarios back to 20 cal. ka BP for the northwestern South China Sea. The scenarios demonstrate the entire process of coastline changes for the area of interest. During the late glacial period from 20 to 15 cal. ka BP, coastline slowly retreated, causing a land loss of only 1×10⁴ km², and thus the land-sea distribution remained nearly unchanged. Later in 15–10 cal. ka BP coastline rapidly retreated and area of land loss was up to 24×10⁴km², causing lowlands around Northeast Vietnam and South China soon to be underwater. Coastline retreat continued quite rapidly during the early Holocene. From 10 to 6 cal. ka BP land area had decreased by 9×10⁴km², and during that process the Qiongzhou Strait completely opened up. Since the mid Holocene, main controls on coastline change are from vertical crustal movements and sedimentation. Transgression was surpassed by regression, resulting in a land accretion of about 10×10⁴km². Supported by Key Laboratory of Marginal Sea Geology, Chinese Academy of Sciences (Grant No. MSGL0711), the Guangdong Natural Science Foundation (Grant No. 04001309) and Open Fund of the Key Laboratory of Marine Geology and Environment, Chinese Academy of Sciences (Grant No. MGE2007KG04)     

Electrical structure of the upper mantle beneath Central Europe: Results of the CEMES project

In the years 2001–2003, we accomplished the experimental phase of the project CEMES by collecting long-period magnetotelluric data at positions of eleven permanent geomagnetic observatories situated within few hundreds kilometers along the south-west margin of the East European Craton. Five teams were engaged in estimating independently the magnetotelluric responses by using different data processing procedures. The conductance distributions at the depths of the upper mantle have been derived individually beneath each observatory. By averaging the individual cross-sections, we have designed the final model of the geoelectrical structure of the upper mantle beneath the CEMES region. The results indicate systematic trends in the deep electrical structure of the two European tectonic plates and give evidence that the electrical structure of the upper mantle differs between the East European Craton and the Phanerozoic plate of west Europe, with a separating transition zone that generally coincides with the Trans-European Suture Zone.     

Extremely slow slope movements influencing the stability of Spis Castle,UNESCO site

Spis Castle, a monument included in the UNESCO World Heritage Site list (Eastern Slovakia) is built on a travertine mound overlying soft Paleogene rocks. Lateral spreading resulting from the subsidence of strong upper travertine into soft claystone strata has fractured and separated the castle rock into several cliffs. The differential movement of individual cliff faces is the primary influence on the stability of the monument. In order to monitor and quantify the movement, two techniques were adopted: a mechanical-optical TM-71 crack gauge and a demec gauge (demountable mechanical—SOMET type crack gauge). This paper presents the results and interpretation of medium and short-term monitoring at the site.     

Reduction of surface subsidence risk by fly ash exploitation as filling material in deep mining areas

The possibility of filling empty underground spaces, which exist owing to the extraction of mineral raw materials, with fly ash and cement fly ash mixes has been studied for the purpose of reducing the impact of deep mining on the surface. The method of physical modelling was used to study the behaviour of fly ash mixes deposited in extracted mine spaces. The models were constructed for two different geometries of underground extracted mine spaces: into cavities of the type of large slits created in the course of mining in steeply lode deposits without subsequently filling the empty space and in vertical shafts of rectangular or circular cross-section with horizontal side headings that have partly caved in due to mine shocks or other seismic events.     

Timing of Holocene sand accumulation along the coast of central and SE Vietnam

In Vietnam, the coastal sand barriers and dunes located in front of the steep slopes of the high rising Truong Son Mountains are sensitive to climate and environment change and give evidence for Holocene sea-level rise. The outer barrier sands were deposited shortly before or contemporaneous with the local sea-level high stand along the Van Phong Bay postdating the last glacial maximum (LGM). Optically stimulated luminescence (OSL) dating yielded deposition ages ranging from 8.3 ± 0.6 to 6.2 ± 0.3 ka for the stratigraphically oldest exposed barrier sands. Further periods of sand accumulation took place between 2.7 and 2.5 ka and between 0.7 and 0.5 ka. The youngest period of sand mobilisation was dated to 0.2 ± 0.01 ka and is most likely related to reworked sand from mining activities. At the Suoi Tien section in southern central Vietnam, the deposition of the inner barrier sands very likely correlate with an earlier sea-level high stand prior to the last glaciation. OSL age estimates range from 276 ± 17 to 139 ± 15 ka. OSL dating significantly improves our knowledge about the sedimentary dynamics along the coast of Vietnam during the Holocene.     

Re–Os age of non-mineralized black shale from the Kupferschiefer, Poland, and implications for metal enrichment

Six samples of non-mineralized black shale from a Kupferschiefer section in the northern part of the Polish Zechstein Basin (Zdrada IG-8 drill hole: 1026.16–1026.90 m) were studied for Re–Os isotopes and selected major and trace elements. These black shales, averaging 5.82 wt.% C_org and 1.69 wt.% S_tot, display very low base metal values (up to 106 ppb Cu, 792 ppb Pb, and 144 ppb Zn) and have abundances of 64–1376 ppb Re and 0.37–1.25 ppb Os, with a ¹⁸⁷Os/¹⁸⁸Os ratio of 6.95–22.5. The regression of all Re–Os data yields an age of 247 ± 20 Ma, which is within the range of uncertainties of previous Rb–Sr and K–Ar geochronological studies. The scatter in the Re–Os data can be explained in terms of fluctuations in sedimentary conditions, i.e., restricted basin with terrestrial influence.     

Thermal expansion and high-temperature P21/c–C2/c phase transition in clinopyroxene-type LiFeGe2O6 and comparison to NaFe(Si,Ge)2O6

A synthetic clinopyroxene with composition LiFe³⁺Ge₂O₆, monoclinic s.g. P2₁/c, a = 9.8792(7), b = 8.8095(5), c = 5.3754(3) Å, β = 108.844(6)°, V = 442.75(16) ų, has been studied by in situ low- and high-temperature single-crystal X-ray diffraction. The variation of lattice parameters and the intensity of the b-type reflections (h + k = 2n + 1, only present in the P-symmetry) with increasing temperature showed a displacive phase transition from space group P2₁/c to C2/c at a transition temperature T _tr = 789 K, first order in character, with a sudden volume increase of 1.6% and a decrease of β by 1° at the transition. This spontaneous dilatation is reversible, shows a limited hysteresis of ±10°C, and corresponds to the vanishing of the b-type reflections, thus indicating a symmetry increase to space group C2/c. Below T _tr an expansion is observed for all the cell parameters, while the β angle remained almost constant; at T > T _tr the thermal volume expansion is due to dilatation of the structure in the $(\bar{1}\,0\,1) A synthetic clinopyroxene with composition LiFe³⁺Ge₂O₆, monoclinic s.g. P2₁/c, a = 9.8792(7), b = 8.8095(5), c = 5.3754(3) ?, β = 108.844(6)°, V = 442.75(16) ?³, has been studied by in situ low- and high-temperature single-crystal X-ray diffraction. The variation of lattice parameters and the intensity of the b-type reflections (h + k = 2n + 1, only present in the P-symmetry) with increasing temperature showed a displacive phase transition from space group P2₁/c to C2/c at a transition temperature T _tr = 789 K, first order in character, with a sudden volume increase of 1.6% and a decrease of β by 1° at the transition. This spontaneous dilatation is reversible, shows a limited hysteresis of ±10°C, and corresponds to the vanishing of the b-type reflections, thus indicating a symmetry increase to space group C2/c. Below T _tr an expansion is observed for all the cell parameters, while the β angle remained almost constant; at T > T _tr the thermal volume expansion is due to dilatation of the structure in the ([`1] 0 1)(\bar{1}\,0\,1) plane, mostly along [0 1 0], and pure shear in the (0 1 0) plane due to the decrease of β. From comparison with silicate analogues, the germanate clinopyroxenes are more expansible, while the P2₁/c expands more than the C2/c phase. The evolution of Q ² (calculated as the normalized intensity of b-type reflections) with T in the framework of the Landau theory has been done using a standard expression for a first order phase transition. We observe a jump of Q ₀² = 0.538(2) at T _tr, with T _c of 481(7) K, b/a = −2,290 K, and c/a = 3,192 K, and thus far from being tri-critical point. A closely related composition (LiFe³⁺Si₂O₆) shows an equivalent phase transition at 228 K, which is very close to the tri-critical point and 561 K cooler. This result indicates that a change in the composition of tetrahedral sites can have dramatic effects on the P2₁/c ↔ C2/c displacive phase transition in clinopyroxenes. The major changes observed in the evolution of the crystal structure with T are observed in the M2 polyhedron, with a volume decrease by ca. 13.3%, compared to ca. 1.3% observed in the M1 polyhedron. The tetrahedra behave as rigid units with neither a significant change of volume at T > T _tr (<1‰), nor a change of tilting of the basal plane. No change in coordination is observed at T > T _tr in the M2 polyhedron, which remains sixfold coordinated although a strong deformation of this polyhedron is observed. This deformation is related to a strong change by 51.4° at T _tr of the kinking angle (O3–O3–O3 angle) of the B-chain of tetrahedra, which switches from O-rotated to S-rotated [from 143.3(5)° to 194.7(6)°]. The A-chain is S-rotated at T < T _tr [206.8(5)° at 703 K] and extends by 12° at the transition.