β-环糊精包合态三氟氯氰杀虫剂的制备

为了进一步提高三氟氯氰菊酯农药的防治效果。寻找适宜的农药新剂型，我们用液相法制备了三氟氯氰菊酯－β－环糊精包合物，并以水为基质进行了稳定性观察，同时又以差热分析法和气相色谱法确认了包合物的形成，以旋光度法证明两者间的包合比。结果表明，三氟氯氰菊酯与β-环糊精可形成1：1型包合物，该包合物稳定性高，具有一定的水溶性，而且在水中稳定，所以有望通过环糊 包合作用将三氟氯氰菊酯帛成水剂；当以气相法测试包合态三氟氯氰菊酯含量时，必须将其解络，使之成为游离状态，然后按常规方法进行含量测定。     

红壤丘陵区农业开发中的生态环境效应及其调控

文章以江西余江县为例。通过实验研究，历史资料对比分析及邻近参照等方法。研究红壤区农业开发中的生态环境效应。农业开发引起的微观环境效应在于改变土壤水分及其运动状况，加速土壤物质迁移及降低土壤肥力质量；区域性效应是植被减少，农业面源污染，水土流失扩大及气候异常；全球性影响除区域集聚效应外，则是农业活动中产生的温室气体对全球气候的影响等，采取的调控对策主要是：保持合理开发，适当减轻土地压力，优化农业开发模式，更新农业耕作技术。强化环境整治与生态建设。     

松辽盆地后五家户气田沉积相特征与控气作用

本文对松辽盆地东南部后五家户气田划分出22种沉积微相,建立7种相层序,分析了扇三角洲及三角洲沉积环境对天然气成藏的控制作用。指出了扇三角洲前缘砂体和三角洲前缘砂体较为发育,沉积物源来自气田东北部和东南部两个方向。后五家户气田多为构造—岩性气藏和岩性气藏。     

Discussion on the feature of strong earthquake: Orderly distribution in time, space and intensity before the Western Kunlun Mountain Pass M=8.1 earthquake

Introduction The Western Kunlun Mountain Pass M=8.1 earthquake occurred on November 14, 2001 is the other M=8 earthquake occurred 50 years after Dangxiong, Tibet M=8.0 earthquake in Chinese mainland. The earthquake has caused the attention of the seismologists in the following aspects: 1) The fracture length is more than 400 km, which is far away from the estimated length by the statistic empirical function between the magnitude and the fracture length (WANG, et al, 2002); 2) The aftersh…     

U–Pb zircon chronostratigraphy of early-Pliocene ignimbrites from La Pacana, north Chile: implications for the formation of stratified magma chambers

High spatial resolution U–Pb dates of zircons from two consanguineous ignimbrites of contrasting composition, the high-silica rhyolitic Toconao and the overlying dacitic Atana ignimbrites, erupted from La Pacana caldera, north Chile, are presented in this study. Zircons from Atana and Toconao pumice clasts yield apparent ²³⁸U/²⁰⁶Pb ages of 4.11±0.20 Ma and 4.65±0.13 Ma (2σ), respectively. These data combined with previously published geochemical and stratigraphic data, reveal that the two ignimbrites were erupted from a stratified magma chamber. The Atana zircon U–Pb ages closely agree with the eruption age of Atana previously determined by K–Ar dating (4.0±0.1 Ma) and do not support long (>1 Ma) residence times. Xenocrystic zircons were found only in the Toconao bulk ignimbrite, which were probably entrained during eruption and transport. Apparent ²³⁸U/²⁰⁶Pb zircon ages of 13 Ma in these xenocrysts provide the first evidence that the onset of felsic magmatism within the Altiplano–Puna ignimbrite province occurred approximately 3 Myr earlier than previously documented.     

Onshore and offshore seismic and lithostratigraphic analysis of a deeply incised Quaternary buried valley system in the Northern Netherlands

High-resolution seismic data (onshore and offshore), geophysical borehole data as well as detailed lithofacies from airlift boreholes were acquired in northern Netherlands on and around the island of Ameland. Marine and land seismic data combined with information from land boreholes have been explored with the objective of providing a sedimentary model. Qualitative seismic facies analysis of the valley fill commonly shows a thin unit with high amplitude reflectors at the base. Thick units of variable seismic facies (transparent to high amplitude) occur higher up in the sequence. Onlap is common at mid–upper levels within the sandy valley fill (with clay in mm layering), and a transparent seismic facies, corresponding to firm clays, is common at the top. Almost all lithological unit boundaries recognised within core parameters correspond with seismic unconformities within error margins. Subunits contain multiple cyclical trends in gamma ray and grain size. Cyclical trends show lower order fluctuations in gamma radiation on a scale of less than 1 m. Gamma-ray pattern variability between units, e.g. in general coarsening-up or fining-up units, suggests migration of subaqueous outwash fans or ice margin fluctuations. Seismic results could support a headward excavation and backfilling process suggested by Praeg [Morphology, stratigraphy and genesis of buried Elsterian tunnel valleys in the southern North Sea basin [PhD thesis]: University of Edinburgh, 207 pp.; Journal of Applied Geophysics, (this volume)] as being responsible for the formation of buried valleys. On a lithological scale, a more complicated, detailed and cyclical pattern arises. Catastrophic processes are considered unlikely as being responsible for the infill sequence because of the observed small-scale facies variability and because of the presence of diamicton layers. Diamicton layers at the base of basal unconformities as well as higher in sequence could suggest subglacial deformation by grounded ice before and during the valley-fill process.     

盆地岩石圈结构与油气成藏及分布

本文综述了大陆岩石圈研究现状和克拉通盆地、裂谷盆地和前陆盆地的岩石圈结构特征,指出在古裂谷、褶皱带或区域性深断裂等陆壳构造薄弱带上发育起来的多期叠合盆地,具有很好的含油气前景。大型含油气盆地往往存在地幔上隆、地壳减薄和地壳内低速层,盆地基底沉降与盖层沉积厚度较大。适度的后期构造活动改造和岩浆活动有利于沉积盆地内油气生成与保存。     

Evidence for fullerenes in solid bitumen from pillow lavas of Proterozoic age from Mítov (Bohemian Massif, Czech Republic)

Andesitic pillow lavas containing biogenic, solid bitumen (SB) are a constituent of a Neoproterozoic volcanosedimentary sequence (Teplá-Barrandian unit, Bohemian Massif) in the Mítov area of the Czech Republic. A black shale formation that is crosscut by these andesitic basalts is 565 Ma old. Carbon disulfide extracts of two powdered samples of SB contain 0.2 and 0.3 ppm of C₆₀, respectively, as determined by high-pressure liquid chromatography. The peak assignment based on retention time is fully supported by high-resolution electron ionization mass spectrometry (EI-MS). No C₇₀ was detected, nor was C₆₀ found in two other SB samples from this locality. Other investigated carbonaceous samples from Bohemia (coals and anthracites of Upper Paleozoic age and anthraxolite, graphitoids, and graphite of Upper Proterozoic age) did not contain fullerenes at concentrations above the detection limit of 0.01 ppm. The absence of C₆₀ in these samples was confirmed by EI-MS. The proposed mechanism of fullerene formation involves a primary algal phase, generation of a hydrocarbonaceous mixture in the course of thermal evolution of the sedimentary series, and their high-temperature transformation related to the extrusion of basalt. An important feature for fullerene conservation was the enclosure of fullerenes in SB with a structure similar to glasslike carbon, where the fullerene was protected against oxidation.     

Use of phytoplankton species indicators to track the origin of phytoplankton blooms in Willapa Bay, Washington

We focus on the question of whether high phytoplankton production events observed in a United States Pacific Northwest estuary consist of estuarine species blooms fueled by oceanic nutrient input or reflect offshore oceanic blooms that have advected into the estuary. Our approach is to use certain phytoplankton species as indicators associated with water mass origin, either estuarine or oceanic, to help resolve this question in Willapa Bay, Washington. We used species analysis and primary production data from 10 selected dates in May–September of 1998 and 1999, representing periods of high through low productivity. Out of 108 phytoplankton species identified from Willapa Bay, nine were selected and tested as indicators of oceanic species, six as estuarine, and two as surf zone. Our test results demonstrated the oceanic and estuarine species to be satifactory indicators of source waters. The prevalence of these species indicators in our samples revealed that the highest primary production and the appearance ofPseudo-nitzschia spp. were associated with oceanic intrusions of phytoplankton biomass into Willapa Bay. While the largest blooms were oceanic in origin, numerous medium-sized production events were from either oceanic, surf zone, or estuarine sources, indicating a complex situation.