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971.
972.
In order to understand the complex multi-parameter system of destruction of organic material on the surface of Mars, step-by-step laboratory simulations of processes occurring on the surface of Mars are necessary. This paper describes the measured effects of two parameters, a CO2 atmosphere and low temperature, on the destruction rate of amino acids when irradiated with Mars-like ultraviolet light (UV). The results show that the presence of a 7 mbar CO2 atmosphere does not affect the destruction rate of glycine, and that cooling the sample to 210 K (average Mars temperature) lowers the destruction rate by a factor of 7. The decrease in the destruction rate of glycine by cooling the sample is thought to be predominantly caused by the slower reaction kinetics. When these results are scaled to Martian lighting conditions, cold thin films of glycine are assumed to have half-lives of 250 h under noontime peak illumination. It has been hypothesised that the absence of detectable native organic material in the Martian regolith points to the presence of oxidising agents. Some of these agents might form via the interaction of UV with compounds in the atmosphere. Water, although a trace component of Mars’ atmosphere, is suggested to be a significant source of oxidising species. However, gaseous CO2 or adsorbed H2O layers do not influence the photodestruction of amino acids significantly in the absence of reactive soil. Other mechanisms such as chemical processes in the Martian regolith need to be effective for rapid organic destruction. 相似文献
973.
974.
975.
Mathematical modelling of overland flow is a critical task in simulating transport of water, sediment and other pollutants from land surfaces to receiving waters. In this paper, an overland flow routing method is developed based on the Saint‐Venant equations using a discretized hillslope system for areas with high roughness and steep slope. Under these conditions, the momentum equation reduces to a unique relationship between the flow depth and discharge. A hillslope is treated as a system divided into several subplanes. A set of first‐order non‐linear differential equations for subsequent subplanes are solved analytically using Chezy's formula in lieu of the momentum equation. Comparison of the analytical solution of the first‐order non‐linear ordinary differential equations and a numerical solution using the Runge‐Kutta method shows a relative error of 0·3%. Using runoff data reported in the literature, comparison between the new approach and a numerical solution of the full Saint‐Venant equations showed a close agreement. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
976.
977.
Yaping Shao Shaofeng Liu Jan H. Schween Susanne Crewell 《Boundary-Layer Meteorology》2013,148(2):333-356
A model is developed for the large-eddy simulation (LES) of heterogeneous atmosphere and land-surface processes. This couples a LES model with a land-surface scheme. New developments are made to the land-surface scheme to ensure the adequate representation of atmosphere–land-surface transfers on the large-eddy scale. These include, (1) a multi-layer canopy scheme; (2) a method for flux estimates consistent with the large-eddy subgrid closure; and (3) an appropriate soil-layer configuration. The model is then applied to a heterogeneous region with 60-m horizontal resolution and the results are compared with ground-based and airborne measurements. The simulated sensible and latent heat fluxes are found to agree well with the eddy-correlation measurements. Good agreement is also found in the modelled and observed net radiation, ground heat flux, soil temperature and moisture. Based on the model results, we study the patterns of the sensible and latent heat fluxes, how such patterns come into existence, and how large eddies propagate and destroy land-surface signals in the atmosphere. Near the surface, the flux and land-use patterns are found to be closely correlated. In the lower boundary layer, small eddies bearing land-surface signals organize and develop into larger eddies, which carry the signals to considerably higher levels. As a result, the instantaneous flux patterns appear to be unrelated to the land-use patterns, but on average, the correlation between them is significant and persistent up to about 650 m. For a given land-surface type, the scatter of the fluxes amounts to several hundred W $\text{ m }^{-2}$ , due to (1) large-eddy randomness; (2) rapid large-eddy and surface feedback; and (3) local advection related to surface heterogeneity. 相似文献
978.
Anirban Garai Eric Pardyjak Gert-Jan Steeneveld Jan Kleissl 《Boundary-Layer Meteorology》2013,148(1):51-72
Previous laboratory and atmospheric experiments have shown that turbulence influences the surface temperature in a convective boundary layer. The main objective of this study is to examine land-atmosphere coupled heat transport mechanism for different stability conditions. High frequency infrared imagery and sonic anemometer measurements were obtained during the boundary layer late afternoon and sunset turbulence (BLLAST) experimental campaign. Temporal turbulence data in the surface-layer are then analyzed jointly with spatial surface-temperature imagery. The surface-temperature structures (identified using surface-temperature fluctuations) are strongly linked to atmospheric turbulence as manifested in several findings. The surface-temperature coherent structures move at an advection speed similar to the upper surface-layer or mixed-layer wind speed, with a decreasing trend with increase in stability. Also, with increasing instability the streamwise surface-temperature structure size decreases and the structures become more circular. The sequencing of surface- and air-temperature patterns is further examined through conditional averaging. Surface heating causes the initiation of warm ejection events followed by cold sweep events that result in surface cooling. The ejection events occur about 25 % of the time, but account for 60–70 % of the total sensible heat flux and cause fluctuations of up to 30 % in the ground heat flux. Cross-correlation analysis between air and surface temperature confirms the validity of a scalar footprint model. 相似文献
979.
Roman Sk��la Petr Ondru? Franti?ek Veselovsky Ivana C��sa?ov�� Jan Hlou?ek 《Mineralogy and Petrology》2011,103(1-4):169-175
The new mineral agricolaite, a potassium uranyl carbonate with ideal formula K4(UO2)(CO3)3, occurs in vugs of ankerite gangue in gneisses in the abandoned Giftkiesstollen adit at Jáchymov, Czech Republic. The name is after Georgius Agricola (1494?C1555), German scholar and scientist. Agricolaite occurs as isolated equant irregular translucent grains to 0.3?mm with yellow color, pale yellow streak, and vitreous luster. It is brittle with uneven fracture and displays neither cleavage nor parting. Agricolaite is non-fluorescent. Mohs hardness is ~4. It is associated with aragonite, brochantite, posnjakite, malachite, rutherfordine, and ??pseudo-voglite??. Experimental density is higher than 3.3?g.cm?3, Dcalc is 3.531?g.?cm?3. The mineral is monoclinic, space group C2/c, with a 10.2380(2), b 9.1930(2), c 12.2110(3) ?, ?? 95.108(2)°, V 1144.71(4) ?3, Z?=?4. The strongest lines in the powder X-ray diffraction pattern are d(I)(hkl): 6.061(55)(002), 5.087(57)(200), 3.740(100)(202), 3.393(43)(113), 2.281(52)(402). Average composition based on ten electron microprobe analyses corresponds to (in wt.%) UO3 48.53, K2O 31.49, CO2(calc) 22.04 which gives the empirical formula K3.98(UO2)1.01(CO3)3.00. The crystal structure was solved from single-crystal X-ray diffraction data and refined to R 1?=?0.0184 on the basis of the 1,308 unique reflections with F o?>?4??F o. The structure of agricolaite is identical to that of synthetic K4(UO2)(CO3)3 and consists of separate UO2(CO3)3 groups organized into layers parallel to (100) and two crystallographically non-equivalent sites occupied by K+ cations. Both the mineral and its name were approved by the IMA-CNMNC. 相似文献
980.
Groundwater levels in basalt aquifers around the world have been declining for many years. Understanding water pathways is needed for solutions like artificial drainage. Water supply in the Palouse Basin, Washington and Idaho, USA, primarily relies on basalt aquifers. This study presents a combination of modeling and field observations to understand the spatial distribution of recharge pathways in the overlying Pleistocene sediments. A spatially distributed model was used to quantify potential recharge rates. The model shows clearly that recharge predominantly occurs through non-argilic soils and soils that are not underlain by fine-grained sediments, i.e. the upper area of the watershed. A field survey was conducted to determine recharge pathways from this area. It revealed 83 ?perennial springs. Drillings near springs showed connection of coarse-grained layers within the fine-grained Sediments of Bovill to these springs. Such layers, with streambed-like features, act as paleo-channels. Water from one of these coarse-grained layers had a similar electrical conductivity (200? ??S? cm?C1) to water from a downstream perennial spring, also suggesting the existence of a lateral conduit for deep percolation water. 相似文献