Arguments for ionic nature of the Carpathian electric conductivity anomaly

This publication is a contribution to discussion on the geometry and petrography of the rock complex responsible for the Carpathian conductivity anomaly. We analysed arguments showing that this anomaly is caused by induction in the sedimentary basin, and make a critical review of various data to find out whether the good conductivity is connected with a rock complex containing graphite or mineralized water. We conclude that a more likely mechanism is the ionic one, i.e., the existence of fluids, although a final decision can only be made on the basis of deep drillings.     

Data reporting norms for 40Ar/39Ar geochronology

Data reported in ⁴⁰Ar/³⁹Ar geochronology studies are commonly insufficient to allow computation of ages. This deficiency renders it difficult to compare ages based on different standards or constants, and often hinders critical evaluation of the results. Herein are presented an enumeration of the data that should be reported in all ⁴⁰Ar/³⁹Ar studies, including a discussion in support of these requirements. The minimum required data are identified and distinguished from parameters that are useful but may be derived from them by calculation. Finally, recommendations are made for metadata needed to document age calculations (e.g., from age spectrum or isochron analyses).     

Evaluation of cosmogenic 3He and 21Ne production rates in olivine and pyroxene from two Pleistocene basalt flows,western Grand Canyon,AZ, USA

Combining cosmogenic ³He and ²¹Ne (³He_c and ²¹Ne_c) measurements on both pyroxene and olivine from the Pleistocene Bar Ten flows (85–107 ka) greatly increases our ability to evaluate the accuracy of ³He_c and ²¹Ne_c production rates and, therefore, ³He_c and ²¹Ne_c surface exposure ages. Comparison of ³He_c and ²¹Ne_c age-pairs yielded by experimentally determined production rates and composition-based model calculations indicates that the former give more accurate surface exposure ages than the latter in this study. However, experimental production rates should be adjusted to the composition of the minerals being analyzed to obtain the best agreement between ³He_c and ²¹Ne_c ages for any given sample. ²¹Ne_c/³He_c values are 0.400 ± 0.029 and 0.204 ± 0.014 for olivine and pyroxene, respectively, in Bar Ten lava flows, in agreement with previously published values, and indicate that ²¹Ne_c/³He_c in olivine and pyroxene is not affected by erosion and remains constant with latitude, elevation, and time (up to 10 Myr). Samples with ²¹Ne_c/³He_c that do not agree with these values may indicate the presence of non-cosmogenic helium and/or neon. The neon three-isotope diagram can also indicate whether or not all excess neon in mineral separates comes from cosmogenic sources. An error-weighted regression for olivine defines a spallation line [y = (1.033 ± 0.031)x + (0.09876 ± 0.00033)], which is indistinguishable from that for pyroxene (Schäfer et al., 1999). We have derived a production rate of 25 ± 8 at/g/yr for ²¹Ne_c in clinopyroxene (En_43–44) based on the ⁴⁰Ar/³⁹Ar age of the upper Bar Ten flow. Our study indicates that the production rate of ²¹Ne_c in olivine may be slightly higher than previously determined. Cosmogenic ³He and ²¹Ne remain extremely useful, particularly when paired, in determining accurate eruption ages of young olivine- and pyroxene-rich basaltic lava flows.     

Age and nature of eclogites in the Huwan shear zone,and the multi-stage evolution of the Qinling-Dabie-Sulu orogen,central China

In situ LA-ICPMS U-Pb, trace element, and Hf isotope data in zircon demonstrate a Carboniferous age for eclogite-facies metamorphism in Siluro-Devonian protoliths in the Huwan shear zone, Dabie Mountains, Central China. This age contrasts with the more prevailing Triassic age for high- to ultrahigh pressure (HP to UHP) metamorphism in the Qinling-Dabie-Sulu orogen. Metamorphic zircon in two eclogite samples from Sujiahe is characterized by low Th/U ratios, small negative Eu anomalies, flat HREE patterns, and low ¹⁷⁶Lu/¹⁷⁷Hf ratios. These geochemical signatures suggest that the zircon crystallized in the presence of garnet and in the absence of plagioclase feldspar. Furthermore, temperatures of ~ 655 and ~ 638 °C, calculated using the Ti content of zircon, are consistent with their formation during eclogite-facies metamorphism. The weighted mean ²⁰⁶Pb/²³⁸U age of 309 ± 4 Ma (2δ) for this zircon improves previous age estimates for eclogite-facies metamorphism in the Huwan shear zone, ranging from 420 to 220 Ma. Metamorphic zircon from one eclogite sample from Hujiawan, most likely formed during prograde metamorphism, yields an equivalent age estimate of 312 ± 11 Ma. Magmatic zircon cores in the three samples yield ages for the magmatic protoliths of the eclogites ranging from 420 ± 7 to 406 ± 5 Ma, and post-dating the middle Paleozoic collision of the North China and the Qinling terrain. The zircon crystals in the three eclogite samples display a large variation of ε_Hf (t) values of ? 4.9 to 21.3. The metamorphic zircon overgrowths show the same range of ε_Hf (t) values as those of the inherited magmatic crystal interiors. This suggests that the metamorphic zircon overgrowths may have formed by dissolution-reprecipitation of pre-existing magmatic zircon thereby preserving their original Hf isotopic composition. The high ε_Hf (t) values suggest that the protoliths were derived from depleted mantle sources, most likely Paleotethyan oceanic crust; while the low ε_Hf (t) values are attributed to crustal contamination. Some eclogites in the Huwan shear zone have a distinctive signature of continental crust most probably derived from the Yangtze Craton. The coexistence of Paleozoic oceanic crust and Neoproterozoic continental crust with similar metamorphic ages in the Huwan shear zone implies that Paleozoic Paleotethyan oceanic crust was produced within a marginal basin of the northern Yangtze Craton. The opening of the Paleo-Tethyan ocean was slightly younger than the collision of the North China Craton and the Qinling terrain during the Late Paleozoic in the Qinling-Dabie-Sulu orogen. Subduction of the Paleo-Tethyan oceanic crust and associated continental basement resulted in the 309 ± 2 Ma (2σ) eclogite-facies metamorphism in the Huwan shear zone. The subsequent Triassic continent-continent collision led to the final coalescence of the Yangtze and Sino-Korean cratons. Amalgamation of the Yangtze and North China cratons was, therefore, a multistage process extending over at least 200 Ma.     

Volatile-induced transport of HFSE, REE, Th and U in arc magmas: evidence from zirconolite-bearing vesicles in potassic lavas of Lewotolo volcano (Indonesia)

Potassium-rich calc-alkaline lavas of Lewotolo volcano, situated in the East Sunda Arc, Indonesia, contain the rare mineral zirconolite (CaZrTi₂O₇). Samples in which tiny grains of this mineral (3–25 μm in size) were found span the entire range of lava compositions (47–62 wt% SiO₂). To the best of our knowledge, this is the first record of primary zirconolite in juvenile arc volcanics. The mineral forms part of a vesicle-filling assemblage consisting of a network of quenched feldspar crystals and an SiO₂ phase, probably cristobalite. High contents of Th, U and REE (up to 9.3, 4.3 and 15.6 wt% oxide respectively) and very high Fe contents (up to 13.5 wt% Fe₂O₃) distinguish these zirconolites from those of other rock types. The extraction of volatile-rich phases with changing compositions in successive stages is considered to be responsible for the zirconolite formation. We hypothesise that a fluid capable of transporting HFSE, REE, Th and U was extracted from the magma and (partly) crystallised within voids which had formed earlier upon saturation of an aqueous fluid. Assuming that zirconolite compositions largely reflect trace metal contents of the coexisting fluid phase, significant amounts of `immobile' elements must have been transported on a macroscopic scale. Our findings thus point to a late-stage transfer of HFSE, REE, Th and U between different domains in a cooling magma body. Such a volatile-induced redistribution of trace elements at shallow levels of high-K volcanic systems may be significant for conventional geochemical modelling of magma evolution and for Th–U disequilibrium studies. Received: 3 November 1999 / Accepted: 29 February 2000     

The Ordovician chondrite from Brunflo, central Sweden: III. Geochemistry of terrestrial alteration

The fossil H chondrite Brunflo, found in a slab of Ordovician limestone from central Sweden, is pervasively altered to an assemblage dominated by calcite and barite. The meteorite is surrounded by a 15–20 cm wide zone of lighter colors than the unaffected limestone due to dissolution of hematite. Here we present detailed geochemical analyses of two meteorite samples, 14 limestone samples at distances from 0 to 29 cm along two profiles from the meteorite, and a reference sample of Brunflo limestone. Element concentrations in Brunflo and surrounding bleached limestone have been strongly disturbed during two stages of alteration (early oxygenated and deep burial). In the meteorite, the Ni/Co ratio has changed from an initial value of 20 to 0.8 and redox sensitive elements like V, As, Mo, Re and U are strongly enriched. The sulfur isotope composition of barite from Brunflo (δ³⁴S=+35‰) indicates initial loss of meteoritic sulfide, followed by later accumulation of sea water sulfate as barite. During deep burial under more reducing conditions, reduction processes supported by an externally derived reductant possibly derived from alum shale underlying the limestone, were largely responsible for the observed redox phenomena. In spite of massive redistribution of many elements, concentrations of Pt, Ir and Au remain at chondritic levels. The geochemistry and mineralogy of alteration determined for Brunflo are similar to those in “reduction spots” in red beds, where accumulation of a similar suite of elements (except Mo, Re) occurred as a result of isolated reduction activity.     

In situ bioremediation of 1,2-dichloroethane under anaerobic conditions

Historic spillages of chlorinated hydrocarbons at a vinyl chloride plant in the Rotterdam–Botlek area in The Netherlands has lead to deep-seated pollution of the underlying aquifer. The principal pollutant is 1,2-dichloroethane (1,2-DCA). As a temporary measure, the contamination is being contained using a pump and treat system. In the long term, in-situ bioremediation has been proposed using a biologically active zone where pollutants would be dechlorinated by microorganisms that simultaneously degrade other carbon sources. In order to investigate the suitability of this new technology, a programme of laboratory tests was carried out. The laboratory programme involved a series of anaerobic soil column tests, where the selection and delivery of different carbon substrates that stimulated 1,2-DCA dechlorination were investigated. The soil columns were prepared using soil and groundwater samples from boreholes. Groundwater was flushed through the columns under anaerobic conditions. A comparison was made between the transformation of 1,2-DCA without a carbon substrate and in the presence of sugars (molasses) and alcohol (methanol) respectively. In addition, different modes of delivery were investigated. In the case of molasses, the material was injected into the column as a plug to simulate grout injection in the field, whereas methanol was delivered as a constant flow dissolved in the influent. Both carbon substrates resulted in the biotransformation of 1,2-DCA. However, fermentation of molasses produced secondary effects that led to a drop in pH and an excessive production of carbon dioxide, which temporarily blocked the flow of groundwater.     

Contribution of Local Seismic Networks To The Regional Velocity Model of The Bohemian Massif

The routine location of regional seismic events using data from the Czech National Seismological Network (CNSN) is based on Pn, Pg, Sn, Sg phases. A simple velocity model derived from Kárník's (1953) interpretation of an earthquake in Northern Hungary in 1951 has hitherto been used. At present, numerous local seismic networks record and locate local events, which are occasionally recorded at regional distances as well. Due to the relatively small dimensions of local networks, hypocenters (and origin times) determined by a local network might be considered as nearly exact from the point of view of regional-scale CNSN. The comparison of common locations performed by CNSN and by a local network enables us to estimate the accuracy of CNSN locations, as well as to optimize a simple velocity model. The joint interpretation of the CNSN bulletin and the catalogues of four local seismic networks WEBNET, OSTRAVA, KLADNO and LUBIN produced a new ID velocity model. The most frequent epicentral error in this model is less than 5 km, and most foci lie up to 15 km from the true position. The performed analysis indicates bimodal distribution of Sn residuals.