Data reporting norms for 40Ar/39Ar geochronology

Data reported in ⁴⁰Ar/³⁹Ar geochronology studies are commonly insufficient to allow computation of ages. This deficiency renders it difficult to compare ages based on different standards or constants, and often hinders critical evaluation of the results. Herein are presented an enumeration of the data that should be reported in all ⁴⁰Ar/³⁹Ar studies, including a discussion in support of these requirements. The minimum required data are identified and distinguished from parameters that are useful but may be derived from them by calculation. Finally, recommendations are made for metadata needed to document age calculations (e.g., from age spectrum or isochron analyses).     

Deep crustal structure and rheology of the Gascoyne volcanic margin,western Australia

Interpretation of deep seismic reflection data across the Gascoyne Margin reveals six distinct seismic facies units related to the tectono-magmatic breakup history. On the outer Exmouth Plateau four large scale units are identified: (1) an extensively block-faulted upper crust; (2) a middle-crustal unit of discontinuous, undulatory reflectors; (3) a reflection-free deep crustal unit; and (4) a lower-crustal band of low-frequency, high-amplitude reflectors. Two additional units are found near the continent-ocean boundary (COB); (5) seaward-dipping reflectors (SDR); and (6) landward-dipping reflectors in the lower crust below the SDR. The lower-crustal high-reflectivity band, located near the top of a high-velocity unit (V_p > 7 kms^–1), is interpreted as magmatic underplating. There is a spatial correlation between the underplated area and the presence of extensive upper-crustal block-faulting and intrusive rocks in the shallow crust. The undulatory middle-crustal reflector unit is also only identified in the outer plateau area, and is interpreted as a zone in which the upper-crustal faults terminate. The inner parts of the margin consist of a deep basin showing little upper-crustal faulting and no evidence of middle crustal deformation or underplating. Theoretical modeling of the effect of rifting and magmatic underplating on crustal strength profiles suggests that the brittle-ductile transition may migrate at least 5 km upwards during several million years after the underplating event. Based on the seismic interpretation and crustal strength modeling we propose that the seismic structure of the outer Exmouth Plateau is severely modified by a transient change in the crustal rheological structure associated with magmatic underplating.     

Challenges in developing China's marine protected area system

Since the 1980s, there have been continuous increases in the coverage of marine protected areas (MPAs) in China, and a total of 158 MPAs have been declared. The MPA system in China is characterized by (1) decentralised designation and management with reduced control from the central government; (2) a dominance of de jure fully protected MPAs that are often implemented as de facto multiple-use areas; and (3) a lack of objective evaluation processes. To improve China's MPA system requires an appropriate integration of fully protected and multiple-use MPAs, and an approach that balances the advantages of top-down and bottom-up approaches.     

Parametric rolling behaviour of azimuthing propulsion-driven ships

The study investigates the experimental and numerical analysis of the occurrence of auto-parametric rolling for large, high-speed pod-driven ships in waves. Considering unique design and performance targets, the aim here is to exploit susceptibility to auto-parametric rolling behaviour and to identify probable design and operational precautions. In order to achieve this aim, an existing non-linear time-domain software to simulate capsizing and other critical manoeuvring behaviours of slow- to medium-speed conventional and podded ships in waves is being enhanced for fast pod-driven vessels and then compared against the dedicated model test conducted in long-crested regular and random waves for a large, pod-driven containership model. This paper includes the presentation of current numerical modifications for pod-driven ships and the verification analysis.     

Effects of cadmium, zinc and nitrogen status on non-protein thiols in the macroalgae Enteromorpha spp. from the Scheldt Estuary (SW Netherlands, Belgium) and Thermaikos Gulf (N Aegean Sea, Greece)

Enteromorpha prolifera (Scheldt Estuary) and E. linza (Thermaikos Gulf) were incubated at three salinities with 100 and 200microgL(-1)Cd and Zn. The objective was to measure effects of Cd, Zn and nitrogen (N) status on the pools of metal-binding non-protein thiols: glutathione and phytochelatins, (gamma-glutamyl-cysteinyl)(n)-glycine (PC). In E. linza, ammonium pools were higher, but amino acid pools, total N and protein contents were lower than in E. prolifera. Reduced glutathione (GSH) pools were positively correlated with free glutamate and protein contents. In E. linza GSH pools increased and the ratio of reduced to oxidized glutathione (GSH:(GSH+0.5GSSG)), an indicator of oxidative stress, decreased with Cd contents, indicating Cd-induced glutathione oxidation. Total glutathione pools (reduced plus oxidized) ranged from 16nmolSgdwt(-1) in controls (at 0.5micromolCdgdwt(-1)) to 179nmolSgdwt(-1) (at 1.9micromolCdgdwt(-1)) at the highest cadmium dosage. Cadmium stimulated PC synthesis in E. prolifera which suggests that in N-rich algae, glutathione pools were high enough for PC synthesis. In both species GSH and protein increased with Zn contents, whereas GSH:(GSH+0.5GSSG) decreased, which would indicate Zn-induced oxidative stress; in E. linza, at the highest salinity the glutathione redox ratio decreased from 0.61 (at 2.9micromolZngdwt(-1)) to 0.26 (at 4.9nmolSgdwt(-1)) (at 0.5molCdgdwt(-1)). PCs were not synthesized in response to Zn, which may have resulted in Zn-induced GSH oxidation. The presence of both oxidative effects (Cd, Zn) and detoxification (Cd) could be identified by observing the responses of glutathione and PC pools to metal stress.     

Covariance among North Sea ecosystem state indicators during the past50 years — Contrasts between coastal and open waters

Regime shift and principal component analysis of a spatially disaggregated database capturing time-series of climatic, nutrient and plankton variables in the North Sea revealed considerable covariance between groups of ecosystem indicators. Plankton and climate time-series span the period 1958–2003, those of nutrients start in 1980. In both regions, the period from 1989 to 2001 identified in principal component 1 had warmer surface waters, higher Atlantic inflow and stronger winds, than the periods before or after. However, it was preceded by a regime shift in both open (PC2) and coastal (PC3) waters during 1977 towards more hours of sunlight and higher water temperature, which lasted until 1997. The relative influence of nutrient availability and climatic forcing differed between open and coastal North Sea regions. Inter-annual variability in phytoplankton dynamics of the open North Sea was primarily regulated by climatic forcing, specifically by sea surface temperature, Atlantic inflow and co-varying wind stress and NAO. Coastal phytoplankton variability, however, was regulated by insolation and sea surface temperature, as well as Si availability, but not by N or P. Regime shifts in principal components of hydrographic and climatic variables (explaining 55 and 61% of the variance in coastal and open water variables) were detected using Rodionov's sequential t-test. These shifts in hydroclimatic variables which occurred around 1977, 1989, 1997 and 2001, were synchronized in open and coastal waters, and were tracked by open water chlorophyll and copepods, but not by coastal plankton. North–central–south or open-coastal spatial breakdowns of the North Sea explained similar amounts of variability in most ecosystem indicators with the exception of diatom abundance and chlorophyll concentration, which were clearly better explained using the open-coastal configuration.     

An integrated geophysical study of Vestbakken Volcanic Province, western Barents Sea continental margin, and adjacent oceanic crust

This paper describes results from a geophysical study in the Vestbakken Volcanic Province, located on the central parts of the western Barents Sea continental margin, and adjacent oceanic crust in the Norwegian-Greenland Sea. The results are derived mainly from interpretation and modeling of multichannel seismic, ocean bottom seismometer and land station data along a regional seismic profile. The resulting model shows oceanic crust in the western parts of the profile. This crust is buried by a thick Cenozoic sedimentary package. Low velocities in the bottom of this package indicate overpressure. The igneous oceanic crust shows an average thickness of 7.2 km with the thinnest crust (5–6 km) in the southwest and the thickest crust (8–9 km) close to the continent-ocean boundary (COB). The thick oceanic crust is probably related to high mantle temperatures formed by brittle weakening and shear heating along a shear system prior to continental breakup. The COB is interpreted in the central parts of the profile where the velocity structure and Bouguer anomalies change significantly. East of the COB Moho depths increase while the vertical velocity gradient decreases. Below the assumed center for Early Eocene volcanic activity the model shows increased velocities in the crust. These increased crustal velocities are interpreted to represent Early Eocene mafic feeder dykes. East of the zone of volcanoes velocities in the crust decrease and sedimentary velocities are observed at depths of more than 10 km. The amount of crustal intrusions is much lower in this area than farther west. East of the Kn?legga Fault crystalline basement velocities are brought close to the seabed. This fault marks the eastern limit of thick Cenozoic and Mesozoic packages on central parts of the western Barents Sea continental margin.     

Enhanced geochemical gradients in a marine shallow-water hydrothermal system: Unusual arsenic speciation in horizontal and vertical pore water profiles

The shallow marine hydrothermal vents near Ambitle Island in eastern Papua New Guinea discharge hot, slightly acidic, As-rich, chemically reduced fluid into cool, slightly alkaline, oxygenated seawater. Gradients in temperature, pH, and total As (As^T), among others, are established as the two aqueous phases mix. The hydrothermal fluid contained 900 μg/L As^T, almost exclusively present as the reduced As^III, while local seawater measured between 1.2 and 2.4 μg/L As, with approximately equal levels of As^III and As^V. Of particular interest in this study was As speciation and abundance in pore waters as a function of sediment depth and as a function of distance from the area of focused venting. With increasing distance, As^T concentration in the pore water decreased rapidly, but remained elevated up to 300 m from the area of focused venting when compared to a non-hydrothermal control site. As a function of depth (to 100 cm) As^T concentration in the pore water profiles was elevated and generally increased with depth. Surprisingly, aqueous As^V far exceeded aqueous As^III at almost all distances and depths investigated, while at the control site the As^III concentration exceeded that of As^V. In the Tutum Bay hydrothermal system, chemical disequilibria among As species provide potential metabolic energy for arsenite oxidizing microorganisms where hydrothermal fluid mixes with seawater near the vent orifice, and for arsenate reducing microorganisms with increasing distance and depth from the hydrothermal point source.     

Clitellate worms (Annelida) in lateglacial and Holocene sedimentary DNA records from the Polar Urals and northern Norway

While there are extensive macro‐ and microfossil records of a range of plants and animals from the Quaternary, earthworms and their close relatives amongst annelids are not preserved as fossils and therefore the knowledge of their past distributions is limited. This lack of fossils means that clitellate worms (Annelida) are currently underused in palaeoecological research, even though they can provide valuable information about terrestrial and aquatic environmental conditions. Their DNA might be preserved in sediments, which offers an alternative method for detection. Here we analyse lacustrine sediments from lakes in the Polar Urals, Arctic Russia, covering the period 24 000–1300 cal. a BP, and NE Norway, covering 10 700–3300 cal. a BP, using a universal mammal 16S rDNA marker. While mammals were recorded using the marker (reindeer was detected twice in the Polar Urals core at 23 000 and 14 000 cal. a BP, and four times in the Norwegian core at 11 000 cal. a BP and between 3600–3300 cal. a BP), worm extracellular DNA ‘bycatch’ was rather high. In this paper we present the first reported worm detection from ancient DNA. Our results demonstrate that both aquatic and terrestrial clitellates can be identified in late‐Quaternary lacustrine sediments, and the ecological information retrievable from this group warrants further research with a more targeted approach.     

Increased levels of petroleum hydrocarbons in the surface sediments of Swedish coastal waters

Petroleum hydrocarbons in the sediments of the Bothnian Bay, Baltic proper, Öresund, Kattegatt and Skagerrak were analysed in a survey of oil pollution along the Swedish coast in 1974 and 1975. Sixty-one of these sediment stations were revisited in 1982 and analysed with the methods used in the first survey. The mean content of petroleum hydrocarbons (paraffin-naphthene fraction) in the sediment surface showed a statistically significant increase from 199 to 252 μg g^?1 dry wt. The main increase had taken place in the coastal areas. Within 0–20 km distance of urbanized areas (>20 000 inhabitants) petroleum hydrocarbons had increased from 371 to 447 μg g^?1. Sediment levels increased from 76 to 117 μg g^?1, 20–50 km from urbanized areas. The increase in these areas was equivalent to 0.119 g m^?2 yr^?1.