Assessment of marine debris on the Belgian Continental Shelf

A comprehensive assessment of marine litter in three environmental compartments of Belgian coastal waters was performed. Abundance, weight and composition of marine debris, including microplastics, was assessed by performing beach, sea surface and seafloor monitoring campaigns during two consecutive years. Plastic items were the dominant type of macrodebris recorded: over 95% of debris present in the three sampled marine compartments were plastic. In general, concentrations of macrodebris were quite high. Especially the number of beached debris reached very high levels: on average 6429 ± 6767 items per 100 m were recorded. Microplastic concentrations were determined to assess overall abundance in the different marine compartments of the Belgian Continental Shelf. In terms of weight, macrodebris still dominates the pollution of beaches, but in the water column and in the seafloor microplastics appear to be of higher importance: here, microplastic weight is approximately 100 times and 400 times higher, respectively, than macrodebris weight.     

The unique environment of the most acidified permanently meromictic lake in the Czech Republic

Changes in the water properties and biological characteristics of the highly acidic Hromnice Lake (Western Bohemia) were investigated. This 110-year-old lake, formed as a consequence of the mining of pyritic shales, is permanently meromictic. Two chemoclines separate an extremely acidic (pH ～ 2.6) mixolimnion from a metal-rich anoxic monimolimnion. The absence of spring mixolimnetic turnover due to ice melting and very slow heat propagation through the chemocline with a 6-month delay were observed. Extreme mixolimnetic oxygen maxima (up to 31 mg l^?1) in phosphorus-rich lake (PO₄^3? up to 1.6 mg l^?1) well correlated with outbursts of phytoplankton. Phytoplankton consist of several acido-tolerant species of the genera Coccomyxa, Lepocinclis, Chlamydomonas and Chromulina. Surface phytoplankton biomass expressed as chlorophyll-a varies from 2 to 140 μg l^?1. Multicellular zooplankton are almost absent with the exception of Cephalodella acidophila, a small rotifer occurring in low numbers. Large red larvae of the midge Chironomus gr. plumosus were found at the bottom close to the shore, with larvulae in the open water. Developmental stages (protonemata) of a moss, resembling filamentous algae, dwell in the otherwise plant-free littoral zone.     

Convective mixing influenced by the capillary transition zone

Convective mixing of dissolved carbon dioxide (CO₂) with formation brine has been shown to be a significant factor for the rate of dissolution of CO₂ and thus for determining the viability of geological CO₂ storage sites. In most previous convection investigations, a no-flow boundary condition was used to represent the interface between an upper region with CO₂ and brine and the single-phase brine region beneath. However, due to interfacial tension between the phases, the water phase is partly mobile in the upper region and advection may occur. Based on linear stability analysis and numerical simulations, we show that advection across the interface leads to considerable destabilization of the system. In particular, the time of onset of instability is reduced by a factor of two and the rate of dissolution is enhanced by a factor of two for three of four formations we consider, and by 40 % for the fourth formation. It is found that exponential decay of the relative permeability away from the interface provides a useful approximation to the real system. In addition, the exponential decay also simplifies the linear stability analysis. Interestingly, formations with large absolute permeability and small porosity have the largest impact from the transition zone, despite the fact that the relative permeability decays quickly above the interface in these formations. This is because the length-scale of instability is smallest in these formations.     

Constraining genesis and geotectonic setting of metavolcanic complexes: a multidisciplinary study of the Devonian Vrbno Group (Hrubý Jeseník Mts., Czech Republic)

The low-grade metavolcanic/volcanosedimentary complex of the Devonian Vrbno Group (Silesicum, NE Bohemian Massif, Czech Republic) occurs in two ~NE–SW trending belts, separated by tectonic slices of Cadomian metagranitic paraautochton. (1) The basic–intermediate lavas of the calc-alkaline Western Volcanic Belt came from a moderately depleted mantle $ \left( {\varepsilon_{\text{Nd}}^{370} \sim + 3} \right) $ . Rare rhyolites (374.0 ± 1.7 Ma: 2σ, LA–ICP–MS U–Pb Zrn) were derived most likely from immature crust or by extensive fractionation of primary basaltic melts. The rock association is interpreted as a vestige of a deeply dissected continental arc. (2) The Eastern Volcanic Belt consists mainly of (nearly) contemporaneous (371.0 ± 1.4 Ma) felsic alkaline lavas with high HFSE contents, as well as high Ga/Al and Fe/Mg ratios, typical of within-plate igneous setting. The petrology and Nd–Sr isotopic data point to a high-T anatexis of a young metagranitic crust, resembling the Cadomian (Brunovistulian) basement, in a back-arc setting. The attenuated Brunovistulian lithosphere could have partially melted by the heat provided by the upwelling asthenosphere and/or underplating basic magma. (3) Finally, the region was penetrated by numerous subalkaline, MORB/EMORB-like dolerite sheets—a hallmark of the considerable crustal thinning.     

A New Method for Low‐Temperature Decomposition of Chromites and Dichromium Trioxide using Bromic Acid Evaluated by Chromium Isotope Measurements

In recent years, routine application of the stable isotope determination of chromium (Cr) in environmental and health protection research has led to the search for simpler chromite decomposition techniques. As the range of Cr isotope abundance ratios in nature is very narrow, conventional chromite decomposition techniques are no longer suitable, due to the relatively high risk of contamination during laboratory procedures. We have developed a protocol for the decomposition of chromites based on oxidation by bromic acid at room temperature. The procedure takes 15 d and requires two doses of bromic acid during the reaction period (day 1 and 8), due to the limited stability of the reagent. Chromium extracted by alkaline oxidative fusion and by bromic acid decomposition yielded statistically indistinguishable δ⁵³Cr values, measured by multi‐collector inductively coupled plasma‐mass spectrometry following addition of a ⁵⁰Cr‐⁵⁴Cr double‐spike.     

Spatial analysis of the mining and transport of rock minerals (aggregates) in the context of regional development

Rock minerals such as dimension and crushed stones and sands and gravels (aggregates) are indispensable materials for the building and construction industries. The growth in demand for these resources causes intensification of mining operations (and their consequent environmental impacts) and transport problems in regions abundant in rock minerals. The balanced management of these resources by regional policy-makers is difficult as it requires, among other things, comprehensive and up-to-date information on the spatial distribution and temporal changes of available reserves, demand, production, and transport. This information can be provided by means of spatial and temporal analyses through geographic information systems (GIS). In this research, the focus is on the following aspects of rock mineral (aggregates) resources and mining management in the context of regional spatial planning in the example region of Lower Silesia in Poland: the spatial and temporal changes in distribution and intensity of mining, the availability of economic reserves in active mines, the magnitude and distribution of road transport flows of aggregates, the potential of railways as an alternative means of transport, and the valorisation of undeveloped aggregates deposits to assess their suitability for future use. For the purposes of this study, cartographic models have been developed using GIS to facilitate analyses of these mineral resources, mining, and transport. The results of these analyses provide current and comprehensive information on the state of aggregates mineral resources, production and transport in the Lower Silesia region. They also give an insight into availability of rock mineral resources for the future. Knowledge of these processes is important for spatial development planning, especially physical infrastructure, conducted by national, regional, and local governments.     

The algal community at an ecocline of a cold sulphidic spring (Sovra artesian borehole,Slovenia)

The physicochemical parameters of the sulphide spring water from a 500?m deep artesian borehole in Sovra Valley (Slovenia) are stable, with very little variation: temperature, 9.2 ± 0.0 °C; pH 7.70 ± 0.11; specific electrical conductivity, 777 ± 8 μS/cm; and dissolved oxygen, 0.19 ± 0.11 mg/l. The water from the borehole is hard, rich in sulphates, and has a notable concentration of sulphide, while it is low in chlorides. Communities of phototrophs were analysed at the oxygenic ecocline at the outflow from the borehole, and from further downstream. Caloneis tenuis, Frustulla vulgaris, Gomphonema sp., Navicula radiosa, Oscillatoria sp., and Tribonema vulgare successfully thrive exclusively at the outflow from the borehole under sub-optimum conditions for the majority of phototrophs. Downstream from the borehole, where the hydrogen sulphide degasses, autotrophic biofilms were dominated by different diatoms. The Bray–Curtis similarity index confirms the distinctive phototrophic communities along the oxygenic ecocline downstream from the sulphidic spring. The sulphidic ecocline downstream from the spring is indicative of the composition of phototrophic communities, as some species appear only downstream from the spring. An ecocline downstream from the borehole of the sulphidic spring was reflected also in the bacterial indicator groups. This study brings novel insights to the limited knowledge in the field of oxygenic phototrophy related to sulphidic springs.     

Physically based dynamic run-out modelling for quantitative debris flow risk assessment: a case study in Tresenda,northern Italy

Quantitative landslide risk assessment requires information about the temporal, spatial and intensity probability of hazardous processes both regarding their initiation as well as their run-out. This is followed by an estimation of the physical consequences inflicted by the hazard, preferentially quantified in monetary values. For that purpose, deterministic hazard modelling has to be coupled with information about the value of the elements at risk and their vulnerability. Dynamic run-out models for debris flows are able to determine physical outputs (extension, depths, velocities, impact pressures) and to determine the zones where the elements at risk can suffer an impact. These results can then be applied for vulnerability and risk calculations. Debris flow risk has been assessed in the area of Tresenda in the Valtellina Valley (Lombardy Region, northern Italy). Three quantitative hazard scenarios for different return periods were prepared using available rainfall and geotechnical data. The numerical model FLO-2D was applied for the simulation of the debris flow propagation. The modelled hazard scenarios were consequently overlaid with the elements at risk, represented as building footprints. The expected physical damage to the buildings was estimated using vulnerability functions based on flow depth and impact pressure. A qualitative correlation between physical vulnerability and human losses was also proposed. To assess the uncertainties inherent in the analysis, six risk curves were obtained based on the maximum, average and minimum values and direct economic losses to the buildings were estimated, in the range of 0.25–7.7 million €, depending on the hazard scenario and vulnerability curve used.     

Introducing top-down methods in assessing compliance with the Kyoto Protocol

Abstract

The Kyoto Protocol has an ambitious reporting and review system to assess Parties' compliance with their emission commitments. It is based on a ‘bottom-up’ approach; that is, each Party is required to submit detailed inventories of emissions and removals. This requires considerable resources and may still not detect all important cases of non-compliance. We consider the case for introducing ‘top-down’ methods; that is, independent inverse modelling methods that calculate probable emissions using measured concentrations of gases in the atmosphere and meteorological models. We argue that the top-down methods are at present too inaccurate, too cumbersome, and politically too problematic to serve as independent alternatives to the reported emission inventories for assessing compliance, although they could be useful in monitoring the global success of the protocol. We conclude that these top-down approaches may supplement the traditional emission inventories, in particular those dealing with fluorinated gases, thereby providing input for improving the emission inventory methods.     

A Review of Coastal Fog Microphysics During C-FOG

Boundary-Layer Meteorology - Our goal is to provide an overview of the microphysical measurements made during the C-FOG (Toward Improving Coastal Fog Prediction) field project. In addition, we...