The structure and dynamics of 2-dimensional fluids in swelling clays

The interlayer pores of swelling 2:1 clays provide an ideal 2-dimensional environment in which to study confined fluids. In this paper we discuss our understanding of the structure and dynamics of interlayer fluid species in expanded clays, based primarily on the outcome of recent molecular modelling and neutron scattering studies. Counterion solvation is compared with that measured in bulk solutions, and at a local level the cation-oxygen coordination is found to be remarkably similar in these two environments. However, for the monovalent ions the contribution to the first coordination shell from the clay surfaces increases with counterion radius. This gives rise to inner-sphere (surface) complexes in the case of potassium and caesium. In this context, the location of the negative clay surface charge (i.e. arising from octahedral or tetrahedral substitution) is also found to be of major importance. Divalent cations, such as calcium, eagerly solvate to form outer-sphere complexes. These complexes are able to pin adjacent clay layers together, and thereby prevent colloidal swelling. Confined water molecules form hydrogen bonds to each other and to the clays' surfaces. In this way their local environment relaxes to close to the bulk water structure within two molecular layers of the clay surface. Finally, we discuss the way in which the simple organic molecules methane, methanol and ethylene glycol behave in the interlayer region of hydrated clays. Quasi-elastic neutron scattering of isotopically labelled interlayer CH₃OD and (CH₂OD)₂ in deuterated clay allows us to measure the diffusion of the CH₃- and CH₂-groups in both clay and liquid environments. We find that in both the one-layer methanol solvates and the two-layer glycol solvates the diffusion of the most mobile organic molecules is close to that in the bulk solution.     

T -distributed Random Fields: A Parametric Model for Heavy-tailedWell-log Data1

Histograms of observations from spatial phenomena are often found to be more heavy-tailed than Gaussian distributions, which makes the Gaussian random field model unsuited. A T-distributed random field model with heavy-tailed marginal probability density functions is defined. The model is a generalization of the familiar Student-T distribution, and it may be given a Bayesian interpretation. The increased variability appears cross-realizations, contrary to in-realizations, since all realizations are Gaussian-like with varying variance between realizations. The T-distributed random field model is analytically tractable and the conditional model is developed, which provides algorithms for conditional simulation and prediction, so-called T-kriging. The model compares favourably with most previously defined random field models. The Gaussian random field model appears as a special, limiting case of the T-distributed random field model. The model is particularly useful whenever multiple, sparsely sampled realizations of the random field are available, and is clearly favourable to the Gaussian model in this case. The properties of the T-distributed random field model is demonstrated on well log observations from the Gullfaks field in the North Sea. The predictions correspond to traditional kriging predictions, while the associated prediction variances are more representative, as they are layer specific and include uncertainty caused by using variance estimates.     

On the origin of rock fragment mulches on Vertisols: A case study from the Ethiopian highlands

Many Vertisols in Tigray, Ethiopia, typically carry a discontinuous rock fragment (RF, size 0.5–> 40 · 10^− 2 m) cover with 10 to 100 RFs m^− 2. Such RF mulches are of agricultural and environmental significance because they influence the water balance in the underlying soils and the crop yield. Natural RF concentrations are mostly considered as eolian or hydraulic lag deposits, or as the result of lateral transport over the soil surface from a rock outcrop, upslope. In cultivated areas RF mulches can develop by tillage.This paper presents the case of a natural RF mulch whose lithology indicates that the RFs are up-squeezed by the local Vertisol. The study site is located in the pass of Enda Maryam, Tigray, Northern Ethiopia (39°8′ E and 13°36′ N). A circular area of 10 m diameter, about 200 m away from the water divide in the valley has been cleared annually between 01/1999 and 05/2003. During this period, 625 RFs, 17 being > 7.5 · 10^− 2 m in size, totalling a mass of nearly 62 kg, have been collected. After correction for measurement procedures, the rate of RF up-warping by the Vertisol at Enda Maryam is assessed at 5 RFs m^− 2 in 3 years. At this rate of appearance, the formation of current RF concentrations on top of active valley Vertisols is only a matter of 10^1–2 years, provided the availability of RFs below the soil surface.Although important underground displacements were measured in the Vertisol between 01/1999 and 05/2002, the supposed link between up-squeezing of RFs and plastic deformations of ‘chimney’, ‘diapir’ or ‘intrusion’-like type in the Vertisol could not be evidenced. Instead, RFs are clearly concentrated on the soil surface as well as in depth, along the existing vertical desiccation cracks, often > 1 m deep which display polygonal configurations at the soil surface. Further, bundles of slickensides containing some RFs, have been mapped at the base of the Vertisol. The slickenside configuration suggests that the RF-bearing substrate is being scraped off.While the underground displacement of RFs along active slickensides seems normal, the process of RFs ascending in ‘upright’ position in the edge of desiccation cracks needs explanation. The closure of a desiccation crack is a peristaltic-like movement, following ascent or descent of the capillary fringe. It is hypothesized that this movement gradually pushes the RF to the surface or to another place or level in the soil profile where the crack closes in last instance.The apparent young age of the valley Vertisol mulches in Ethiopia might indicate the very recent formation of yearly recurrent desiccation cracks of Vertisols in the area. Available information confirms that most valleys in the study area used to be perennially marshy. Under these conditions no movements of RFs in the soil profile are expected to occur. Gullying, leading to pronounced seasonal desiccation of the Vertisols, started in several cases not more than 50 years ago.     

韧性剪切变形对岩石地球化学行为的制约——以北阿尔金巴什考供韧性剪切带为例

韧性剪切变形对岩石地球化学行为的制约一直是地质学家们探讨的课题。本文以构成北阿尔金红柳沟——拉配泉俯冲碰撞杂岩带与北阿尔金地块边界的巴什考供斜向逆冲型韧性剪切带为例，通过对韧性剪切带内花岗岩变形前后不同变形强度构造岩的地球化学组成进行对比，确定等比线斜率，探讨韧性变形对岩石体积和成分变异的影响。计算结果表明，在糜棱岩化过程中，糜棱岩化花岗岩体积亏损21％，花岗质糜棱岩体积亏损31％。质量平衡计算结果和等比线图表明，韧；陛剪切作用导致SiO2，流失量最大，A12O3、K2O及Ba、Rb、Sr等都有不同程度的丢失，显示出较强的活动性，MnO、P2O5、Sc位于等比线上或附近，表现出相对的稳定性。岩石中活动组分的变异是流体渗滤作用引起的，不活动组分的变异是体．积亏损造成的。     

Structure sismique du socle paléozoı̈que du bassin des Doukkala,Môle côtier,Maroc occidental. Indication en faveur de l'existence d'une phase éo-varisqueSeismic structure of the Doukkala basin,Palaeozoic basement,western Morocco: a hint for an Eovariscan fold-and-thrust belt

Seismic profiles and well data from the Doukkala basin unravel the structure of the Palaeozoic basement and suggest that this coastal zone of western Morocco was affected by a compressive phase during the Frasnian. This resulted in the formation of upright, plurikilometric folds associated with reverse faults (North Doukkala), and of asymmetrical folds associated with mostly west verging ramps (South Doukkala). Folding involved all pre-Upper Frasnian formations and caused partial or total hiatus of Upper Frasnian–Strunian strata. This event can be correlated with the orogenic phase reported from more internal domains of the Morocco Hercynian belt, where it is referred to as the ‘Bretonne’ or ‘Eovariscan’ phase. To cite this article: H. Echarfaoui et al., C. R. Geoscience 334 (2002) 13–20     

Improved NMO correction with a specific application to shallow-seismic data

The application of traditional NMO‐correction techniques in the processing of seismic data may result in severe distortion. This distortion is observed as a decrease in frequency content (NMO stretch) or even a total loss of data for steep velocity gradients. It is shown that the specific nature of the observed distortion is introduced by the particular implementation of the traditional NMO‐correction technique. It is also shown that other techniques that have been proposed in the literature suffer from similar artefacts. An alternative approach is suggested, based on the correction of tapered blocks of seismic data, followed by a coherence filter to compensate for the specific artefacts thus introduced. Correction of seismic amplitudes (e.g. geometrical spreading and attenuation) is implemented as an integral part of the NMO‐correction method thus allowing for both dynamic and kinematic reconstruction of interfering events. From the application of this method to synthetic and field data, it is concluded that the proposed technique may be particularly useful in the processing of shallow seismic (shear‐wave) data. Although not illustrated in this paper, it is emphasized that application of the proposed method is by no means restricted to shear waves; application to P‐wave data will prove equally useful, although the stretch effects involved may not be as severe as in the examples given in this paper.     

新时期我国区域经济地理学发展问题初探

我国新时期的区域经济地理学在取得全面发展的同时，在理论体系，研究方法和实践领域等方面还需要进一步的发展，文章根据学习和实践区域经济地理学的体会，初步提出基础理论和应用理论，思维方法和技术方法等方面发展见解，并指出区域创新系统和国际经济技术合作等学科应注意拓展的重要实践领域，最后提出我国区域经济地理学科发展的建议。     

华南地区凉果加工业与凉果资源的匹配关系分析——以广东省新兴县为例

文章以广东省新兴县为例，从凉果资源分布与加工能力的匹配关系角度对华南地区凉果资源的分布，凉果加工业的分布与布局，凉果市场分布与竞争力，凉果加工业与资源的匹配关系等进行了分析，并针对华南地区凉果加工业面临的主要问题提供了一些建议。