The presolar grain inventory of fine‐grained chondrule rims in the Mighei‐type (CM) chondrites

We investigated the inventory of presolar silicate, oxide, and silicon carbide (SiC) grains of fine‐grained chondrule rims in six Mighei‐type (CM) carbonaceous chondrites (Banten, Jbilet Winselwan, Maribo, Murchison, Murray and Yamato 791198), and the CM‐related carbonaceous chondrite Sutter's Mill. Sixteen O‐anomalous grains (nine silicates, six oxides) were detected, corresponding to a combined matrix‐normalized abundance of ~18 ppm, together with 21 presolar SiC grains (~42 ppm). Twelve of the O‐rich grains are enriched in ¹⁷O, and could originate from low‐mass asymptotic giant branch stars. One grain is enriched in ¹⁷O and significantly depleted in ¹⁸O, indicative of additional cool bottom processing or hot bottom burning in its stellar parent, and three grains are of likely core‐collapse supernova origin showing enhanced ¹⁸O/¹⁶O ratios relative to the solar system ratio. We find a presolar silicate/oxide ratio of 1.5, significantly lower than the ratios typically observed for chondritic meteorites. This may indicate a higher degree of aqueous alteration in the studied meteorites, or hint at a heterogeneous distribution of presolar silicates and oxides in the solar nebula. Nevertheless, the low O‐anomalous grain abundance is consistent with aqueous alteration occurring in the protosolar nebula and/or on the respective parent bodies. Six O‐rich presolar grains were studied by Auger Electron Spectroscopy, revealing two Fe‐rich silicates, one forsterite‐like Mg‐rich silicate, two Al‐oxides with spinel‐like compositions, and one Fe‐(Mg‐)oxide. Scanning electron and transmission electron microscopic investigation of a relatively large silicate grain (490 nm × 735 nm) revealed that it was crystalline åkermanite (Ca₂Mg[Si₂O₇]) or a an åkermanite‐diopside (MgCaSi₂O₆) intergrowth.     

A standard format for reporting PILPS experiments

In model inter-comparisons one major obstacle is the format of the reported data. To facilitate the analysis of the results from the different models they should all be reported in the same format. This requires that the format is flexible enough to be easily implemented into the different land surface schemes. It should also be fault tolerant and allow a few consistence checks to avoid erroneous data to be submitted. The present note describes such a format developed for the PILPS project. After discussing the aim of this new format we present the routines which are used to write and read data. Finally two applications are described which allow the user to perform a number of consistency checks on the data.     

Gravity reduction with three-dimensional atmospheric pressure data for precise ground gravity measurements

The redistribution of air masses induces gravity variations (atmospheric pressure effect) up to about 20 μgal. These variations are disturbing signals in gravity records and they must be removed very carefully for detecting weak gravity signals. In the past, different methods have been developed for modelling of the atmospheric pressure effect. These methods use local or two-dimensional (2D) surface atmospheric pressure data and a standard height-dependent air density distribution. The atmospheric pressure effect is consisting of the elastic deformation and attraction term. The deformation term can be well modelled with 2D surface atmospheric pressure data, for instance with the Green's function method. For modelling of the attraction term, three-dimensional (3D) data are required. Results with 2D data are insufficient.From European Centre for Medium-Range Weather Forecasts (ECMWF) 3D atmospheric pressure data are now available. The ECMWF data used here are characterised by a spacing of Δ and Δλ = 0.5°, 60 pressure levels up to a height of 60 km and an interval of 6 h. These data are used for modelling of the atmospheric attraction term. Two attraction models have been developed based on the point mass attraction of air segments and the gravity potential of the air masses. The modelling shows a surface pressure-independent part of gravity variations induced by mass redistribution of the atmosphere in the order of some μgal. This part can only be determined by using 3D atmospheric pressure data. It has been calculated for the Vienna Superconducting Gravimeter site.From this follows that the gravity reduction can be improved by applying the 3D atmospheric attraction model for analysing long-periodic tidal waves including the polar tide. The same improvement is expected for reduction of long-term absolute gravity measurements or comparison of gravity measurements at different seasonal times. By using 3D atmospheric pressure data, the gravity correction can be improved up to some μgal.     

Carry-over effects of the membrane interface probe

The membrane interface probe (MIP) is widely used to characterize the subsurface distribution of volatile organic compounds (VOCs). One problem that arises during MIP application is that disproportionately high MIP signals are obtained after passing source zones which contain mobile or residual phases. This serious problem occurs because of a carry-over effect, in particular caused by compound-specific retention times in the conventional unheated transfer line, commonly used during such an investigation. The objective of this study was to perform a qualitative methodical field evaluation of the carry-over effect of a conventional MIP system with a conventional unheated transfer line. This was achieved by coupling a mobile mass spectrometer to the MIP device. Results obtained were then further compared with those achieved using a laser induced fluorescence (LIF) system. Because of this coupling, time- and depth-dependent signals for different substances became known. Field evaluation data obtained showed complex superpositions of compounds with MIP system results. As a result of this superposition, MIP signals from the saturated zone beneath the source zone (zone with free and/or residual phase) are blurred and are therefore not representative of particular depths. However, utilizing multidirectional probing alongside conventional MIP probing (forwards and backwards), it was possible to detect the upper and lower phase boundary of the source zone. These MIP results correlated excellently with the LIF results. An important conclusion that can be drawn from the field investigation is that coupling a mobile mass spectrometer to the MIP system enables advanced MIP signal interpretation to be successfully achieved.     

The role of long‐term human impact on avulsion and fan development

This study aims to understand (mainly qualitatively) the long‐term role of human impact on avulsion processes and the development of fluvial (mega‐) fans in semi‐arid environments. In this paper we refer to human impact as the direct influences of actions on the river's hydraulics (i.e. flow regulation, flow diversion and channel engineering). In five case‐studies drawn from the Khuzestan plains in southwest Iran we have analysed the setup and triggering conditions of specific avulsions that occurred in the past (timescale of millennia) and identified the role of human interference in their causation. Our analysis is based on the integration of historical, archaeological, geomorphological and geological data. Through this study we demonstrate that avulsions in the Khuzestan plains are the result of long‐term and complex interplay between multiple human‐induced and natural causes. In similar ways human‐induced actions may play important roles during different phases of avulsion development. The ‘success‘ of an avulsion in the post‐triggering phase may be defined by human‐induced setup causes as well as morphodynamic processes. We suggest that present‐day flood events may be partly inherited from long‐term human alterations of the natural processes. These finding could have implications for any fluvial system (e.g. distributive fluvial systems, deltas) where avulsion plays a major role in their development and research tends to emphasize on natural mechanisms. Copyright © 2016 John Wiley & Sons, Ltd.     

A study of presolar material in hydrated lithic clasts from metal-rich carbonaceous chondrites

We report on the investigation of presolar grain inventories of hydrated lithic clasts in three metal-rich carbonaceous chondrites from the CR clan, Acfer 182 (CH3), Isheyevo (CH3/CB_b3), and Lewis Cliff (LEW) 85332 (C3-un), as well as the carbon- and nitrogen-isotopic compositions of the fine-grained clast material. Eleven presolar silicate grains as well as nine presolar silicon carbide (SiC) grains were identified in the clasts. Presolar silicate abundances range from 4 to 22 parts per million (ppm), significantly lower than in pristine meteorites and interplanetary dust particles (IDP), and comparable to recent findings for CM2s and CR2 interchondrule matrix. SiC concentrations lie between 9 and 23 ppm, and are comparable to the values for CI, CM, and CR chondrites. The results of our investigation suggest similar alteration pathways for the clast material, the interchondrule matrix of the CR2 chondrites, and the fine-grained fraction of CM2 chondrites. Fine-grained matter of all three meteorites contains moderate to high ¹⁵N-enrichments (~50‰ ≤ δ¹⁵N ≤ ~1600‰) compared to the terrestrial value, indicating the presence of primitive organic material. We observed no correlation between ¹⁵N-enrichments and presolar dust concentrations in the clasts. This is in contrast to the findings from a suite of primitive IDPs, which display in several cases enhanced bulk ¹⁵N/¹⁴N ratios and high presolar grain abundances of several hundred or even thousand ppm. The bulk ¹⁵N/¹⁴N ratios of the clasts are comparable to the range for primitive IDPs, suggesting a nitrogen carrier less susceptible to destruction by aqueous alteration than silicate stardust.     

The chronology of a large ice-dammed lake and the Barents–Kara Ice Sheet advances, Northern Russia

Beach and shoreface sediments deposited in the more than 800-km long ice-dammed Lake Komi in northern European Russia have been investigated and dated. The lake flooded the lowland areas between the Barents–Kara Ice Sheet in the north and the continental drainage divide in the south. Shoreline facies have been dated by 18 optical stimulated luminescence (OSL) dates, most of which are closely grouped in the range 80–100 ka, with a mean of 88±3 ka. This implies that that the Barents–Kara Ice Sheet had its Late Pleistocene maximum extension during the Early Weichselian, probably in the cold interval (Rederstall) between the Brørup and Odderade interstadials of western Europe, correlated with marine isotope stage 5b. This is in strong contrast to the Scandinavian and North American ice sheets, which had their maxima in isotope stage 2, about 20 ka. Field and air photo interpretations suggest that Lake Komi was dammed by the ice advance, which formed the Harbei–Harmon–Sopkay Moraines. These has earlier been correlated with the Markhida moraine across the Pechora River Valley and its western extension. However, OSL dates on fluvial sediments below the Markhida moraine have yielded ages as young as 60 ka. This suggests that the Russian mainland was inundated by two major ice sheet advances from the Barents–Kara seas after the last interglacial: one during the Early Weichselian (about 90 ka) that dammed Lake Komi and one during the Middle Weichselian (about 60 ka). Normal fluvial drainage prevailed during the Late Weichselian, when the ice front was located offshore.