The effects of parent body processes on amino acids in carbonaceous chondrites

Abstract– To investigate the effect of parent body processes on the abundance, distribution, and enantiomeric composition of amino acids in carbonaceous chondrites, the water extracts from nine different powdered CI, CM, and CR carbonaceous chondrites were analyzed for amino acids by ultra performance liquid chromatography‐fluorescence detection and time‐of‐flight mass spectrometry (UPLC‐FD/ToF‐MS). Four aqueously altered type 1 carbonaceous chondrites including Orgueil (CI1), Meteorite Hills (MET) 01070 (CM1), Scott Glacier (SCO) 06043 (CM1), and Grosvenor Mountains (GRO) 95577 (CR1) were analyzed using this technique for the first time. Analyses of these meteorites revealed low levels of two‐ to five‐carbon acyclic amino alkanoic acids with concentrations ranging from approximately 1 to 2,700 parts‐per‐billion (ppb). The type 1 carbonaceous chondrites have a distinct distribution of the five‐carbon (C₅) amino acids with much higher relative abundances of the γ‐ and δ‐amino acids compared to the type 2 and type 3 carbonaceous chondrites, which are dominated by α‐amino acids. Much higher amino acid abundances were found in the CM2 chondrites Murchison, Lonewolf Nunataks (LON) 94102, and Lewis Cliffs (LEW) 90500, the CR2 Elephant Moraine (EET) 92042, and the CR3 Queen Alexandra Range (QUE) 99177. For example, α‐aminoisobutyric acid (α‐AIB) and isovaline were approximately 100 to 1000 times more abundant in the type 2 and 3 chondrites compared to the more aqueously altered type 1 chondrites. Most of the chiral amino acids identified in these meteorites were racemic, indicating an extraterrestrial abiotic origin. However, nonracemic isovaline was observed in the aqueously altered carbonaceous chondrites Murchison, Orgueil, SCO 06043, and GRO 95577 with l ‐isovaline excesses ranging from approximately 11 to 19%, whereas the most pristine, unaltered carbonaceous chondrites analyzed in this study had no detectable l ‐isovaline excesses. These results are consistent with the theory that aqueous alteration played an important role in amplification of small initial left handed isovaline excesses on the parent bodies.     

A shallow subsurface controlled release facility in Bozeman, Montana, USA, for testing near surface CO2 detection techniques and transport models

A controlled field pilot has been developed in Bozeman, Montana, USA, to study near surface CO₂ transport and detection technologies. A slotted horizontal well divided into six zones was installed in the shallow subsurface. The scale and CO₂ release rates were chosen to be relevant to developing monitoring strategies for geological carbon storage. The field site was characterized before injection, and CO₂ transport and concentrations in saturated soil and the vadose zone were modeled. Controlled releases of CO₂ from the horizontal well were performed in the summers of 2007 and 2008, and collaborators from six national labs, three universities, and the U.S. Geological Survey investigated movement of CO₂ through the soil, water, plants, and air with a wide range of near surface detection techniques. An overview of these results will be presented.     

Head–tail Galaxies: beacons of high-density regions in clusters

Using radio data at 1.4 GHz from the Australia Telescope Compact Array (ATCA), we identify five head–tail (HT) galaxies in the central region of the Horologium–Reticulum Supercluster (HRS). Physical parameters of the HT galaxies were determined along with substructure in the HRS to probe the relationship between environment and radio properties. Using a density enhancement technique applied to 582 spectroscopic measurements in the  2°× 2°  region about A3125/A3128, we find all five HT galaxies reside in regions of extremely high density (>100 galaxies Mpc⁻³). In fact, the environments surrounding HT galaxies are statistically denser than those environments surrounding non-HT galaxies and among the densest environments in a cluster. Additionally, the HT galaxies are found in regions of enhanced X-ray emission and we show that the enhanced density continues out to substructure groups of 10 members. We propose that it is the high densities that allow ram pressure to bend the HT galaxies as opposed to previously proposed mechanisms relying on exceptionally high peculiar velocities.     

Noble gases and nitrogen in Martian meteorites Dar al Gani 476, Sayh al Uhaymir 005 and Lewis Cliff 88516: EFA and extra neon

Meteorite “finds” from the terrestrial hot deserts have become a major contributor to the inventory of Martian meteorites. In order to understand their nitrogen and noble gas components, we have carried out stepped heating experiments on samples from two Martian meteorites collected from hot deserts. We measured interior and surface bulk samples, glassy and non-glassy portions of Dar al Gani 476 and Sayh al Uhaymir 005. We have also analyzed noble gases released from the Antarctic shergottite Lewis Cliff 88516 by crushing and stepped heating. For the hot desert meteorites significant terrestrial Ar, Kr, Xe contamination is observed, with an elementally fractionated air (EFA) component dominating the low temperature releases. The extremely low Ar/Kr/Xe ratios of EFA may be the result of multiple episodes of trapping/loss during terrestrial alteration involving aqueous fluids. We suggest fractionation processes similar to those in hot deserts to have acted on Mars, with acidic weathering on the latter possibly even more effective in producing elementally fractionated components. Addition from fission xenon is apparent in DaG 476 and SaU 005. The Ar-Kr-Xe patterns for LEW 88516 show trends as typically observed in shergottites - including evidence for a crush-released component similar to that observed in EETA 79001. A trapped Ne component most prominent in the surface sample of DaG 476 may represent air contamination. It is accompanied by little trapped Ar (²⁰Ne/³⁶Ar > 50) and literature data suggest its presence also in some Antarctic finds. Data for LEW 88516 and literature data, on the other hand, suggest the presence of two trapped Ne components of Martian origin characterized by different ²⁰Ne/²²Ne, possibly related to the atmosphere and the interior. Caution is recommended in interpreting nitrogen and noble gas isotopic signatures of Martian meteorites from hot deserts in terms of extraterrestrial sources and processes. Nevertheless our results provide hope that vice-versa, via noble gases and nitrogen in meteorites and other relevant samples from terrestrial deserts, Martian secondary processes can be studied.     

Deep groundwater mediates streamflow response to climate warming in the Oregon Cascades

Recent studies predict that projected climate change will lead to significant reductions in summer streamflow in the mountainous regions of the Western US. Hydrologic modeling directed at quantifying these potential changes has focused on the magnitude and timing of spring snowmelt as the key control on the spatial–temporal pattern of summer streamflow. We illustrate how spatial differences in groundwater dynamics can also play a significant role in determining streamflow responses to warming. We examine two contrasting watersheds, one located in the Western Cascades and the other in the High Cascades mountains of Oregon. We use both empirical analysis of streamflow data and physically based, spatially distributed modeling to disentangle the relative importance of multiple and interacting controls. In particular, we explore the extent to which differences in snow accumulation and melt and drainage characteristics (deep ground water vs. shallow subsurface) mediate the effect of climate change. Results show that within the Cascade Range, local variations in bedrock geology and concomitant differences in volume and seasonal fluxes of subsurface water will likely result in significant spatial variability in responses to climate forcing. Specifically, watersheds dominated by High Cascade geology will show greater absolute reductions in summer streamflow with predicted temperature increases.     

Recombinant workfare, across the Americas: Transnationalizing “fast” social policy

The paper presents a genealogy of the Bloomberg administration’s Opportunity NYC program, launched in 2007 as part of New York City’s explicitly experimental anti-poverty strategy. Opportunity NYC was modeled on “conditional cash transfer” programs, currently operating in more than thirty countries across the Global South, drawing direct inspiration from Mexico’s widely touted Oportunidades program. This striking case of South-North policy emulation calls attention to some distinctive features of what is characterized here as a transnationalizing “fast-policy” regime, based on technocratic forms of program evaluation and development, dense expert networks, and orchestrated communities of practice, within which a range of policy intermediaries—particularly those connected with multilateral agencies—are assuming significant new roles. What appears to be a pragmatic form of policy learning in fact operates in the context of narrow ideological parameters, within which there is a concerted technocratic “push” toward favored solutions.     

Sulphur isotopes in carbonatites and associated silicate rocks from the Superior Province, Canada

Thirty-five S isotope analyses obtained from six carbonatite complexes from the Superior Province, Canadian Shield, ranging in age from 1,897 Ma to 1,093 Ma, have δ³⁴S_CDT values of between ?4.5‰ and +3.4‰. Pyrrhotite, chalcopyrite and pyrite mineral separates were used. Each complex possesses its own distinct range and mean S isotope composition. The range for Schryburt Lake is: ?4.5‰ to ?3.4‰ ( mean?=??3.9‰), for Big Beaver House: ?3.6‰ to ?1.5‰ (mean?=??2.2‰), for Cargill: ?1.5‰–+0.5‰ (mean?=??0.7‰), for Spanish River: ?0.1‰–+0.1‰ (mean?=?0.0‰), and for Firesand River: +1.3‰–+3.4‰ (mean?=?+1.7‰). A single sample from Carb Lake yielded a δ³⁴S_CDT value of +2.8‰. Differences in isotope compositions can be related to isotope effects brought about during melt generation and emplacment, such as variations in fo₂ and temperature. The different S and C isotope data for most complexes, however, suggest that the parental melts could have been generated from a heterogeneous mantle source, although process-driven changes cannot be completely ruled out.     

Simulating low flows over a heterogeneous landscape in southeastern Poland

This paper presents a scheme describing low flow formation processes in areas with different environmental conditions, including the impact of the selection and explanatory power of predictors for a probabilistic model based on the Logit model. The research was carried out using 29 daily streamflow gauges located in the Lublin region of southeastern Poland for the hydrological period 1976–2018. Analysis resulted in two distinct low flow schemes. In the lowland rivers, low flows occur during the warm season and are related to evaporation exceeding precipitation. In the upland rivers, hydrogeological factors related to water levels in the local Cretaceous aquifers determine the occurrence of low flows. This differentiation affects the quality of the predictive models. For lowland rivers, models based on the climatic water balance with a monthly shift have a better fit, while these models used for upland rivers are characterized by an approximately 10% decrease in accuracy. For upland rivers, the combined C_tH_t models without shifts produce the best model fit. The generalized precision of the Logit models is around 80%–90%.     

Wetland soil moisture complicates the use of Sporormiella to trace past herbivore populations

Spores of the dung‐fungi Sporormiella provide a proxy for assessing past changes in herbivore abundance, and for temporally linking these with shifts in vegetation communities (pollen) and fire frequency (charcoal). Although the proxy is now widely used, potential influences of local environmental conditions are poorly understood. Here we assess the reliability of Sporormiella as a proxy of herbivores by presenting five new spore records from the South Island of New Zealand; a land where the herbivore extinction/introduction chronology is well established, and where extinctions occurred independently of major climate change. We show that Sporormiella spores from relatively dry soils provide a good proxy for herbivore extinctions and introductions. However, spore abundances from saturated soil sites appear to fluctuate in close correlation with changes in local hydrology (represented by wetland herb pollen, testate amoebae and moisture sensitive mosses). Our results suggest Sporormiella records derived from wetlands require cautious interpretation, and that proxies for hydrological conditions should also be considered when interpreting such records. Copyright © 2011 John Wiley & Sons, Ltd.     

Assessing stand water use in four coastal wetland forests using sapflow techniques: annual estimates,errors and associated uncertainties

Forests comprise approximately 37% of the terrestrial land surface and influence global water cycling. However, very little attention has been directed towards understanding environmental impacts on stand water use (S) or in identifying rates of S from specific forested wetlands. Here, we use sapflow techniques to address two separate but linked objectives: (1) determine S in four, hydrologically distinctive South Carolina (USA) wetland forests from 2009–2010 and (2) describe potential error, uncertainty and stand‐level variation associated with these assessments. Sapflow measurements were made from a number of tree species for approximately 2–8 months over 2 years to initiate the model, which was applied to canopy trees (DBH > 10–20 cm). We determined that S in three healthy forested wetlands varied from 1.97–3.97 mm day^?1 or 355–687 mm year^?1 when scaled. In contrast, saltwater intrusion impacted individual tree physiology and size class distributions on a fourth site, which decreased S to 0.61–1.13 mm day^?1 or 110–196 mm year^?1. The primary sources of error in estimations using sapflow probes would relate to calibration of probes and standardization relative to no flow periods and accounting for accurate sapflow attenuation with radial depth into the sapwood by species and site. Such inherent variation in water use among wetland forest stands makes small differences in S (<200 mm year^?1) difficult to detect statistically through modelling, even though small differences may be important to local water cycling. These data also represent some of the first assessments of S from temperate, coastal forested wetlands along the Atlantic coast of the USA. Copyright © 2014 John Wiley & Sons, Ltd.