Si,Al ordering in leucite by high-resolution 27Al MAS NMR spectroscopy

High-resolution ²⁷Al MAS NMR spectra of natural leucite recorded at H ₀=11.7T contain three resolvable resonances at ²⁷Al δ _i = 69.2, 64.7, and 61.0±0.5 ppm. These three resonances are assigned to the three inequivalent framework positions of leucite: T3, T2, and T1, respectively. Fitting the observed spectra yields a Si,Al distribution for leucite in which approximately one-half of the Al is in T1 and one-quarter in each of T2 and T3. This Si,Al distribution differs substantially from those obtained by previous workers using ²⁹Si NMR spectroscopy and X-ray diffraction. New ²⁹Si NMR spectra and revision of previously reported ²⁹Si NMR peak assignments, however, make the ²⁷Al and ²⁹Si NMR results consistent. The ²⁷Al δ _i correlate linearly with the mean T-O-T′ bond angles of the average structure, which allows the peak assignments to be made. However, this correlation lies distinctly toward higher frequency and larger bond angles than correlations for Si,Al ordered aluminosilicates, suggesting that the mean T(Al)-O-T′(Si) bond angle for each site in leucite is smaller than the mean bond angle of the average structure, which is averaged over T(Al)-O-T′(Si) and T(Si)-OT′(Si,Al) angles.     

On the evolution of interacting,magnetized, galactic plasmas

The advent of three-dimensional, electromagnetic, and fully relativistic particle simulations allows a detailed study of a magnetized, rotating plasma, galaxy model. When two such models are simulated, an interaction yielding results resembling observational data from double radio sources, including the emission of synchrotron radiation, are obtained. Simulation derived morphologies, radiation intensities, frequency spectra, and isophote patterns are directly compared to observations. The constituent plasma parameters associated with the source Cygnus A are found to ben _e =1.8×10^?3 cm^?3,T=2.8 keV,B=20–30 gamma, with a small population of electrons accelerated to GeV energies by a rotation induced electric field. The results of these simulations, involving a computational resource of five CDC 7600 and five Cray-1 computers, strongly supports an inhomogeneous version of the Klein world model.     

Marine cements in mid-Tertiary cool-water shelf limestones of New Zealand and southern Australia

Large areas of southern Australia and New Zealand are covered by mid‐Tertiary limestones formed in cool‐water, shelf environments. The generally destructive character of sea‐floor diagenesis in such settings precludes ubiquitous inorganic precipitation of carbonates, yet these limestones include occasional units with marine cements: (1) within rare in situ biomounds; (2) within some stacked, cross‐bedded sand bodies; (3) at the top of metre‐scale, subtidal, carbonate cycles; and (4) most commonly, associated with certain unconformities. The marine cements are dominated by isopachous rinds of fibrous to bladed spar, interstitial homogeneous micrite and interstitial micropeloidal micrite, often precipitated sequentially in that order. Internal sedimentation of microbioclastic micrite may occur at any stage. The paradox of marine‐cemented limestone units in an overall destructive cool‐water diagenetic regime may be explained by the precipitation of cement as intermediate Mg‐calcite from marine waters undersaturated with respect to aragonite. In some of the marine‐cemented limestones, aragonite biomoulds may include marine cement/sediment internally, suggesting that dissolution of aragonite can at times be wholly marine and not always involve meteoric influences. We suggest that marine cementation occurred preferentially, but not exclusively, during periods of relatively lowered sea level, probably glacio‐eustatically driven in the mid‐Tertiary. At times of reduced sea level, there was a relative increase in both the temperature and the carbonate saturation state of the shelf waters, and the locus of carbonate sedimentation shifted towards formerly deeper shelf sites, which now experienced increased swell wave and/or tidal energy levels, fostering sediment abrasion and reworking, reduced sedimentation rates and freer exchange of sediment pore‐waters. Energy levels were probably also enhanced by increased upwelling of cold, deep waters onto the Southern Ocean margins of the Australasian carbonate platforms, where water‐mass mixing, warming and loss of CO₂ locally maintained critical levels of carbonate saturation for sea‐floor cement precipitation and promoted the phosphate‐glauconite mineralization associated with some of the marine‐cemented limestone units.     

Climate change and mental health: an exploratory case study from Rigolet, Nunatsiavut, Canada

As the impacts from anthropogenic climate change are increasing globally, people are experiencing dramatic shifts in weather, temperature, wildlife and vegetation patterns, and water and food quality and availability. These changes impact human health and well-being, and resultantly, climate change has been identified as the biggest global health threat of the 21st Century. Recently, research is beginning to indicate that changes in climate, and the subsequent disruption to the social, economic, and environmental determinants of health, may cause increased incidences and prevalence of mental health issues, emotional responses, and large-scale sociopsychological changes. Through a multi-year, community-led, exploratory case study conducted in Rigolet, Nunatsiavut, Labrador, Canada, this research qualitatively explores the impacts of climate change on mental health and well-being in an Inuit context. Drawing from 67 in-depth interviews conducted between January 2010 and October 2010 with community members and local and regional health professionals, participants reported that changes in weather, snow and ice stability and extent, and wildlife and vegetation patterns attributed to climate change were negatively impacting mental health and well-being due to disruptions in land-based activities and a loss of place-based solace and cultural identity. Participants reported that changes in climate and environment increased family stress, enhanced the possibility of increased drug and alcohol usage, amplified previous traumas and mental health stressors, and were implicated in increased potential for suicide ideation. While a preliminary case study, these exploratory findings indicate that climate change is becoming an additional mental health stressor for resource-dependent communities and provide a baseline for further research.     

Uranium-lead isotope systematics of Mars inferred from the basaltic shergottite QUE 94201

Uranium-lead ratios (commonly represented as ²³⁸U/²⁰⁴Pb = μ) calculated for the sources of martian basalts preserve a record of petrogenetic processes that were active during early planetary differentiation and formation of martian geochemical reservoirs. To better define the range of μ values represented by the source regions of martian basalts, we completed U-Pb elemental and isotopic analyses on whole rock, mineral and leachate fractions from the martian meteorite Queen Alexandra Range 94201 (QUE 94201). The whole rock and silicate mineral fractions have unradiogenic Pb isotopic compositions that define a narrow range (²⁰⁶Pb/²⁰⁴Pb = 11.16-11.61). In contrast, the Pb isotopic compositions of weak HCl leachates are more variable and radiogenic. The intersection of the QUE 94201 data array with terrestrial Pb in ²⁰⁶Pb/²⁰⁴Pb-²⁰⁷Pb/²⁰⁴Pb-²⁰⁸Pb/²⁰⁴Pb compositional space is consistent with varying amounts of terrestrial contamination in these fractions. We calculate that only 1-7% contamination is present in the purified silicate mineral and whole rock fractions, whereas the HCl leachates contain up to 86% terrestrial Pb. This terrestrial Pb contamination generated a ²⁰⁶Pb-²⁰⁷Pb array in the QUE fractions that appears to represent an ancient age, which contrasts with a much younger crystallization age of 327 ± 10 Ma derived from Rb-Sr and Sm-Nd isochrons (Borg L. E., Nyquist L. E., Taylor L. A., Wiesmann H. and Shih C. -Y. (1997) Constraints on Martian differentiation processes from Rb-Sr and Sm-Nd isotopic analyses of the basaltic shergottite QUE 94201. Geochim. Cosmochim. Acta61, 4915-4931). Despite the contamination, and accepting 327 ± 10 Ma as the crystallization age, we use the U-Pb data to determine the initial ²⁰⁶Pb/²⁰⁴Pb of QUE 94201 to be 11.086 ± 0.008 and to calculate the μ value of its mantle source to be 1.82 ± 0.01. The μ value calculated for the QUE 94201 source is the lowest determined for any martian basalt source, and, when compared to the highest values determined for martian basalt sources, indicates that μ values in martian source reservoirs vary by at least a factor of two. Additionally, the range of source μ values indicates that the μ value of bulk silicate Mars is approximately three. The amount of variation in the μ values of the mantle sources (μ ∼ 2-4) is greater than can be explained by igneous processes involving silicate phases alone. We suggest the possibility that a small amount of sulfide crystallization may generate greater extents of U-Pb fractionation during formation of the mantle sources of martian basalts.     

Petrology of a portion of the Eastern Peninsular Ranges mylonite zone,Southern California

Peraluminous and metaluminous plutonic rocks of the Peninsular Ranges batholith near Borrego Springs in southern California were mylonitized in the large shear zone known as the eastern Peninsular Ranges mylonite zone (EPRMZ). Accompanying mylonitization in this portion of the EPRMZ was metamorphism at intermediate-low-pressure amphibolite-facies conditions. Deformation in the zone overlapped in time with Cretaceous intrusion of the batholith. In the San Ysidro Mountain — Pinyon Ridge area, four north-south trending zones of differing intensity of deformation have been defined; from east to west the degree and style of deformation gradually change from undeformed or weakly deformed rocks to strongly mylonitized rocks. Electron microprobe analysis shows that recrystallized hornblende, biotite, and plagioclase are variable in composition, probably reflecting a range of metamorphic conditions accompanying deformation. Comparison of mineral compositions with those from mafic schists of Vermont suggests conditions ranged from andalusite-staurolite through sillimanite-muscovite grades as defined for pelitic rocks. Stability of muscovite+quartz in mylonite assemblages and lack of remelting of granitic rocks indicate that temperature did not exceed about 650° C during mylonitization and lithostatic pressure did not exceed about 5 kbar. Over time, any given rock volume experienced a range of temperature, lithostatic pressure, and perhaps fluid pressure and differential stress. Mineral reactions in the zone involved hydration, requiring introduction of water. The possibility of large-scale migration of K and Fe is suggested by whole-rock chemical data. Brittle and ductile deformation features are closely associated in one part of the EPRMZ. The combined evidence suggests the presence of a pore fluid with fluid pressure close to lithostatic pressure. Short periods of low fluid pressure and possible high differential stress cannot be ruled out.     

An example of slip instability resulting from displacement-varying strength

A rock cylinder, containing a clay-filled sawcut making an angle of 30° to the sample axis, was deformed at constant confining and pore pressures and constant remote shortening rate. The sawcut surfaces contained a series of regularly spaced ridges and grooves oriented perpendicular to the direction of shear. The interaction of these grooved surfaces resulted in a sliding strength which varied periodically with displacement. By varying the effective machine stiffness through the use of an electronic feedback circuit, a range of stable and unstable slip behavior was achieved. In this way, we examined fault slip behavior which was dominated by displacement-dependent strength.     

Finite difference modeling of contaminant transport using analytic element flow solutions

The two-dimensional implementation of the analytic element method (AEM) is commonly used to simulate steady-state saturated groundwater flow phenomena at regional and local scales. However, unlike alternative groundwater flow simulation methods, AEM results are not ordinarily used as the basis for simulation of reactive solute transport. The use of AEM-simulated flow fields is impeded by the discrepancy between a continuous representation of flow and a typically discrete representation of transport, and requires translation of the flow solution to a discrete analog. This paper presents a variety of methods for analytically calculating conservative discrete water fluxes and integrated components of the dispersion tensor across cell interfaces. An Eulerian finite difference method based on these AEM-derived parameters is implemented for use in simulation of 2D (vertically averaged) solute transport. This implementation is first benchmarked against existing methods that use standard finite difference flow solutions, then used to investigate the effects of an inaccurate discrete water balance. It is shown that improper translation of AEM fluxes leads to significant water balance errors and inaccurate simulation of contaminant transport.