Primary minerals of Zn-Pb mining and metallurgical dumps and their environmental behavior at Plombières,Belgium

The primary phases and minerals of the Plombières dumps include typical smelting furnace products such as metallic Fe, Pb, Cu, Zn, Fe-Zn alloys, carbides, phosphides, sulfides of Fe, Zn, Pb, Cu, Mn (alabandite), and FeAs. Spinels, mainly of Fe and Al, are common constituents of the primary assemblage; substitution by Zn, V, Cr, Ti, Mg, and Ca occurs. Primary phases also include the most common Zn-rich fayalite, Zn-rich Ca-Fe silicates, melilite, corundum, and apatite. Most of the Zn is incorporated in iron silicates, ZnO and ZnS. Lead occurs mainly as PbS, metallic lead, and is also present in coal residues. Cadmium is found mainly in metallic zinc and its alloys and in ZnO. The dumps also contain mining wastes composed of pyrite, melnikovite, and iron oxides produced by natural weathering of Zn-Pb ores. Melnikovite and iron oxides are rich in As, Pb, and Zn and possess an increased content of Tl. Leaching tests carried out on the surfaces of polished sections indicate that acid rain (solutions I and II) will mobilize mainly Zn and Cd and, to a much smaller extent, Pb and Sb. Leaching of metals by sulfate-chloride fluids present in the pore network of dumps (solutions III, IV, and V) depends on the pH, which in the dumps is controlled by the proportion of carbonates to sulfides. The more acid fluids leach both sulfides and silicates.     

Composition of hydrous melts in equilibrium with quartz eclogites

Summary Compositions of the hydrous melts in equilibrium with garnet, omphacitic clinopyroxene and quartz have been investigated experimentally at 28.5 and 35 kbar. They are represented by silica-rich liquids (> 70% SiO₂) with low MgO, FeO and CaO contents. The removal of ca 10–15% of the magma of this composition may be sufficient to convert quartz eclogite formed after subduction of altered MORB into a quartz-free bimineralic eclogite assemblage, which is a common type of xenoliths in kimberlites.At 28.5 kbar the solidus temperature is between 700 and 750° C in the system quartz eclogite—water, and the high pressure amphibole-out boundary lies at ca 25 kbar in accord with the previous studies.

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Die Zusammensetzung wasserhältiger Schmelzen im Gleichgewicht mit Quarz-Eklogiten

Zusammenfassung Um Prozesse zu simulieren, die bei der Subduktion von Ozeanbodenbasalten durch partielle Anatexis im Stabilitätsfeld von Eklogiten ablaufen, wurde die Zusammensetzung wasserhältiger Schmelzen in Gleichgewicht mit Granat, Omphacit und Quarz bei 28.5 und 35 Kbar experimentell untersucht. Diese Schmelzen sind reich an SiO₂ (> 70 Gew%) und arm an Mg0, Fe0 and CaO. Die Extraktion von ca. 10–15% derartiger Schmelzen würde genügen, um quarzführende Eklogite, die durch die Subduktion von alteriertem MORB Material entstanden sind, in quarzfreie bimineralische Eklogite umzuwandeln wie sie häufig als Xenolithe in Kimberliten beobachtet werden.Im System Quarz-Eklogit-Wasser liegt die Solidustemperatur bei 28.5 Kbar zwischen 700 und 750°C. Die obere Stabilitätsgrenze von Amphibol liegt in diesem Temperaturbereich bei ca. 25 Kbar.

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A new, instantaneous aeolian sand trap design for field use

A new aeolian sediment trap is described which can give up to 1 Hz measurement frequency in field conditions. The trap adopts a circular, horizontal trap design with a load cell connection to give continuous, unobtrusive trap measurement of sediment flux. Simultaneous velocity recording is carried out using an anemometer. Trap construction costs are approximately £200. Initial results in field conditions using a direct comparison of wind velocity data, sampled at an equivalent frequency, have given a first-order relationship between sediment flux and velocity. The trap enables simultaneous sampling of wind velocity and sediment flux at a sufficiently short interval to enable investigation of sediment transport dynamics under a variety of field conditions.     

Ice wastage and landscape evolution along the southern margin of the Laurentide Ice Sheet, north-central Wisconsin

The Chippewa and Wisconsin Valley Lobes of the Laurentide Ice Sheet reached their maximum extent in north-central Wisconsin about 20 000 years ago. Their terminal positions are marked by a broad area of hummocky topography, containing many ice-walled-lake plains, which is bounded on the up-ice and down-ice sides by ice-contact ridges and outwash fans. The distribution of these ice-disintegration landforms shows that a wide zone of stagnant, debris-covered, debris-rich ice separated from the active margins of both lobes as they wasted northward during deglaciation. Accumulation of thick, uncollapsed sediment in ice-walled lakes high in the ice-cored landscape indicates a period of stability. In contrast, hummocky disintegration topography indicates unstable conditions. Thus, we interpret two phases of late-glacial landscape evolution. During the first phase, ice buried beneath thick supraglacial sediment was stable. Supraglacial lakes formed on the ice surface and some melted their way to solid ground and formed ice-walled lakes. During the second phase, buried ice began to melt rapidly, hummocky topography formed by topographic inversion, and supraglacial and ice-walled lakes drained. We suggest that ice wastage was controlled primarily by climatic conditions and supraglacial-debris thickness. Late-glacial permafrost in northern Wisconsin likely delayed wastage of buried ice until after about 13 000 years ago, when climate warmed and permafrost thawed.     

Characterisation of brown coal humic acids and modified humic acids using pyrolysis gcms and other techniques

It has been proposed that Victorian brown coal can be considered as a two-component structure — a lignocellulosic “host”, containing various amounts of weakly bound or entrapped “guest” material together with very small amounts of inorganic and/or mineral matter. The latter predominantly consists of wax esters and/or terpenoid material. In this paper we describe attempts to gain structural information regarding the more complex, “host” component of the coal. Our initial model compound has been humic acid that can be readily obtained from the coal by alkaline extraction. It has been found that “pure” humic acid, free from material associated with the “guest” components of the coal, can be obtained by a highly selective, low-yielding alkaline extraction. This humic acid has been studied by nmr spectroscopy and pyrolysis gas chromatography-mass spectroscopy (py-gc/ms). The products arising from py-gc/ms have been compared with those obtained from similar pyrolysis of whole coals. Alkylation of humic acids using alkyl halides in the presence of base has been successfully carried out and reactivity of the resulting materials compared with those of the parent coal and humic acid.     

Leucoxene fish as a micro-kinematic indicator

Asymmetric aggregates of fine-grained leucoxene and quartz are reported from siliceous L-S tectonites deformed by progressive simple shear. The leucoxene fish, morphologically similar to mica fish, consistently yield shear senses in agreement with other kinematic criteria. We interpret the leucoxene as a pre- or early syntectonic alteration product of detrital heavy-minerals in a siliciclastic protolith. The leucoxene fish behave as passive markers, and they record kinematics by modification of pre-existing aggregates rather than syndeformational mineral growth. For siliceous metasedimentary rocks otherwise lacking in micro-kinematic indicators, leucoxene fish may provide an alternative to quartz c-axis analysis.     

Neogene volcanism and Holocene earthquakes in the Tanlu fault zone, eastern China

In this paper, we study the relationship between Neogene volcanism and Holocene earthquakes in the Tanlu fault, eastern China. We find that fault segments through which Neogene and Quaternary magma have extruded do not show Holocene slip because they are covered by unfaulted basalts. In contrast, fault branches that are away from the Quaternary volcanic centers display Quaternary faulting and are responsible for earthquakes as recorded both historically and geomorphologically. Therefore, magma intrusion appears to modify fault activity in two different ways: (1) within the faults, the cooling magma serves as a cohesion or barrier, welding the faults so that they become stronger in resisting slip; (2) beneath the faults, the upwelling magma promotes slip of faults above the magma body, and hence generation of earthquakes. Physically, the first case results from contraction of the cooling magma, which causes a relative increase in fault-normal stress so that the fault failure resistance is enhanced. The second case results from the upward dynamic force and the heat brought in by the magma body, both of which cause the effective fault-normal stress to decrease so that the fault failure resistance is reduced. That could explain why earthquakes occur on faults bypassing the volcanic centers as typified in the Yishu fault zone and in the regions where heat flows are relatively high as shown in the Bohai Bay area.     

Late Quaternary Upper Mississippi River alluvial episodes and their significance to the Lower Mississippi River system

The period in the Upper Mississippi Valley (UMV) from about 25 000 years B.P. until the time of strong human influence on the landscape beginning about 150–200 years ago can be characterized by three distinctly different alluvial episodes. The first episode is dominated by the direct and indirect effects of Late Wisconsin glacial ice in the basin headwaters. This period, which lasted until about 14 000 years B.P., was generally a time of progressive valley aggradation by a braided river system transporting large quantities of bedload sediment. An island braided system evolved during the second episode, which extended from about 14 000 to 9000 years B.P. The second episode is associated with major environmental changes of deglaciation when occurrences of major floods and sustained flows of low sediment concentration from drainage of proglacial lakes produced major downcutting. By the time of the beginning of the third episode about 9000 years B.P., most vegetation communities had established their approximate average Holocene locations. The change of climate and establishment of good vegetation cover caused upland landscapes of the UMV to become relatively stable during the Holocene in comparison to their relative instability during the Late Wisconsin. However, Holocene remobilization of Late Wisconsin age sediment stored in tributary valleys resulted in a return to long-term upper Mississippi River aggradation. The dominance of Holocene deposition over transportation reflects the abundance of sandy bedload sediment introduced from tributaries and the situation that energy conditions for floods and the hydraulic gradient of the upper Mississippi River are much less for the Holocene than they were for the Late Wisconsin and deglaciation periods.Outburst floods from glacial lakes appear to have been common in the UMV during the Late Wisconsin and especially during deglaciation. Magnitudes for the Late Wisconsin floods are generally poorly understood, but an estimate of 10 000–15 000 m³ s⁻¹ was determined for one of the largest events in the northern UMV based on heights of paleo-foreset beds in a flood unit deposited in the Savanna Terrace. For comparison, the great flood of 1993 on the upper Mississippi River was about 12 000 m³ s⁻¹ at Keokuk, Iowa, near the Des Moines River confluence where it represented the 500-year event in relation to modem flood series. Exceptionally large outburst floods derived from the rapid drainage of pro-glacial Lake Michigan and adjacent smaller proglacial lakes between about 16 000 and 15 500 years B.P. are a likely cause of the final diversion of the Mississippi River through the Bell City-Oran Gap at the upstream end of the Lower Mississippi Valley (LMV). The largest outburst flood from northern extremities of the UMV appears to have occurred between about 11700 and 10 800 years B.P. when the southern outlet of Lake Agassiz was incised. Based on the probable maximum capacity of the Agassiz flood channel 600 km downstream near the junction of the Wisconsin and Mississippi Rivers, the Agassiz flood discharge apparently did not exceed 30 000 m³ s⁻¹. However, if the Agassiz flood channel here is expanded to include an incised component, then the flood discharge maximum could have been as large as 100,000 to 125 000 m³ s⁻¹. The larger flood is presently viewed as unlikely, however, because field evidence suggests that the incised component of the cross-section probably developed after the main Agassiz flood event. Nevertheless, the large Agassiz flood between about 11 700 and 10 800 years B.P. produced major erosional downcutting and removal of Late Wisconsin sediment in the UMV. This flood also appears to be mainly responsible for the final diversion of the Mississippi River through Thebes Gap in extreme southwestern Illinois and the formation of the Charleston alluvial fan at the head of the LMV.After about 9000 years B.P. prairie-forest ecotones with associated steep seasonal climatic boundaries were established across the northern and southern regions of the UMV. The general presence of these steep climatically sensitive boundaries throughout the Holocene, in concert with the natural tendency for grasslands to be especially sensitive to climatic change, may partially explain why widespread synchroneity of Holocene alluvial episodes is recognized across the upper Mississippi River and Missouri River drainage systems. Comparison of estimated beginning ages of Holocene flood episodes and alluvial chronologies for upper Mississippi River and Missouri River systems with beginning ages for LMV meander belts and delta lobes shows a relatively strong correlation. At present, dating controls are not sufficiently adequate and confidence intervals associated with the identified ages representing system changes are too large to establish firm causal connections. Although the limitations of the existing data are numerous, the implicit causal connections suggested from existing information suggest that further exploration would be beneficial to improving the understanding of how upper valley hydrological and geomorphic events are influencing hydrological and geomorphic activity in the LMV. Since nearly 80% of the Mississippi River drainage system lies upstream of the confluence of the Mississippi and Ohio Rivers, there is a strong basis for supporting the idea that UMV fluvial activity should be having a strong influence on LMV fluvial activity. If this assertion is correct, then the traditional assignment of strong to dominant control by eustatic sea level variations for explaining channel avulsions, delta lobes, and meander belts in the LMV needs re-examination. A stronger role for upper valley fluvial activity as a factor influencing lower valley fluvial activity does not disregard the role of eustatic sea level, tectonic processes or other factors. Rather, upper valley fluvial episodes or specific events such as extreme floods may commonly serve as a “triggering mechanism” that causes a threshold of instability to be exceeded in a system that was poised for change due to sea level rise, tectonic uplift, or other environmental factors. In other situations, the upper valley fluvial activity may exert a more dominant control over many LMV fluvial processes and landforms as frequently was the case during times of glacial climatic conditions.     

A traverse through the western Kunlun (Xinjiang,China): tentative geodynamic implications for the Paleozoic and Mesozoic

The northern part of the western Kunlun (southern margin of the Tarim basin) represents a Sinian rifted margin. To the south of this margin, the Sinian to Paleozoic Proto-Tethys Ocean formed. South-directed subduction of this ocean, beneath the continental southern Kunlun block during the Paleozoic, resulted in the collision between the northern and southern Kunlun blocks during the Devonian. The northern part of the Paleo-Tethys Ocean, located to the south of the southern Kunlun, was subducted to the north beneath the southern Kunlun during the Late Paleozoic to Early Mesozoic. This caused the formation of a subduction-accretion complex, including a sizeable accretionary wedge to the south of the southern Kunlun. A microcontinent (or oceanic plateau?), which we refer to as “Uygur terrane,” collided with the subduction complex during the Late Triassic. Both elements together represent the Kara-Kunlun. Final closure of the Paleo-Tethys Ocean took place during the Early Jurassic when the next southerly located continental block collided with the Kara-Kunlun area. From at least the Late Paleozoic to the Early Jurassic, the Tarim basin must be considered a back-arc region. The Kengxiwar lineament, which “connects” the Karakorum fault in the west and the Ruogiang-Xingxingxia/Altyn-Tagh fault zone in the east, shows signs of a polyphase strike-slip fault along which dextral and sinistral shearing occurred.