Watershed-scale vegetation,water quantity,and water quality responses to wildfire in the southern Appalachian mountain region,United States

Wildfires are landscape scale disturbances that can significantly affect hydrologic processes such as runoff generation and sediment and nutrient transport to streams. In Fall 2016, multiple large drought-related wildfires burned forests across the southern Appalachian Mountains. Immediately after the fires, we identified and instrumented eight 28.4–344 ha watersheds (four burned and four unburned) to measure vegetation, soil, water quantity, and water quality responses over the following two years. Within burned watersheds, plots varied in burn severity with up to 100% tree mortality and soil O-horizon loss. Watershed scale high burn severity extent ranged from 5% to 65% of total watershed area. Water quantity and quality responses among burned watersheds were closely related to the high burn severity extent. Total water yield (Q) was up to 39% greater in burned watersheds than unburned reference watersheds. Total suspended solids (TSS) concentration during storm events were up to 168 times greater in samples collected from the most severely burned watershed than from a corresponding unburned reference watershed, suggesting that there was elevated risk of localized erosion and sedimentation of streams. NO₃-N concentration, export, and concentration dependence on streamflow were greater in burned watersheds and increased with increasing high burn severity extent. Mean NO₃-N concentration in the most severely burned watershed increased from 0.087 mg L⁻¹ in the first year to 0.363 mg L⁻¹ (+317%) in the second year. These results suggest that the 2016 wildfires degraded forest condition, increased Q, and had negative effects on water quality particularly during storm events.     

Trends in phosphatase activity along a successional gradient of tidal freshwater marshes on the Cooper River South Carolina

Phosphatase activity was measured in sediments from tidal freshwater habitats adjacent to the Cooper River in South Carolina representing different stages of ecological succession. It was found that sediment (0–5 cm) acid phosphatase activity, alkaline phosphatase activity and phosphodiesterase activity increased with increasing successional stage and phytomass. Acid phosphatase activity in creased from 7.5±1.2 (±1 SD) in subtidal sediment from a shallow open water habitat without vegetation to 61.2±4.9 μmol g⁻¹ hr⁻¹ (μmol of p-nitrophenol released per gram of dry sediment per hour) in intertidal sediments colonized by emergent macrophytes, while alkaline phosphatase activity increased from 2.1±0.1 to 19.01±1.5 μmol g⁻¹ hr⁻¹. Phosphodiesterase activity increased from 1.8±0.1 to 20.2±2.0 μmol g⁻¹ hr⁻¹ along the same gradient. Acid phosphatase activity was highly correlated (R²=0.92, P<0.001) with the organic matter content of the sediment. A study of phosphatase kinetics showed that V_max of all phosphatases also increased along the successional gradient. Trends in phosphatase activity and V_max correlated positively with plant biomass and negatively with concentrations of soluble reactive phosphorus in porewater, sediment extractable phosphorus, and total phosphourus. The porewater N∶P atom ratio decreased along the succession gradient from 25.3 in an early stage, open water community to 13.0 in a community dominated by emergent vegetation. The data also show that the distribution of the forms of phosphorus changed with successional stage. The change in distribution and the increased biological demand for phosphorus that paralleled succession were mediated by the activity of phosphatase enzymes.     

A middle–late Ediacaran volcano‐sedimentary record from the eastern Arabian‐Nubian shield

The Ediacaran Jibalah Group comprises volcano‐sedimentary successions that filled small fault‐bound basins along the NW–SE‐trending Najd fault system in the eastern Arabian‐Nubian Shield. Like several other Jibalah basins, the Antaq basin contains exquisitely preserved sedimentary structures and felsic tuffs, and hence is an excellent candidate for calibrating late Ediacaran Earth history. Shallow‐marine strata from the upper Jibalah Group (Muraykhah Formation) contain a diversity of load structures and intimately related textured organic (microbial) surfaces, along with a fragment of a structure closely resembling an Ediacaran frond fossil and a possible specimen of Aspidella. Interspersed carbonate beds through the Muraykhah Formation record a positive δ¹³C shift from ?6 to 0‰. U‐Pb zircon geochronology indicates a maximum depositional age of ~570 Ma for the upper Jibalah Group, consistent with previous age estimates. Although this age overlaps with that of the upper Huqf Supergroup in nearby Oman, these sequences were deposited in contrasting tectonic settings on opposite sides of the final suture of the East African Orogen.     

Is public awareness and perceived threat of climate change associated with governmental mitigation targets?

Social scientists and science communicators are concerned about the apparent discrepancy between the scientific consensus on climate change (Anderegg et al. Proc Natl Acad Sci 107:12107–12109, 2010; Doran and Zimmerman EOS Trans Am Geophys Union 90:22–3, 2009) and the general public’s views (Knight Environ Sociol 2:101–113, 2016; Lee et al. Nat Clim Chang 5:1014–1020, 2015). It is reasoned that increased public awareness and perceived threat of climate change may pressure governments to enact policy to counteract climate change (e.g. setting stringent carbon emissions targets). Despite a logical link between public awareness and government-set emissions targets, this relationship remains untested. We examined the relationship between public awareness about and perceived threat of climate change and governmental emissions targets across 71 countries and 1 region. We found a positive association between the proportions of a country’s population that are aware of climate change and the unconditional emissions reduction targets set by that country in the Paris Agreement (Rogelj et al. Nature 534:631–639, 2016). However, the proportion of people in a country who perceive climate change as a personal threat was not associated with higher emissions reduction targets. Our results suggest that public awareness may be an important part of garnering the public support required for policies designed to mitigate climate change to succeed.     

Two metallogenic maps for North America

Part of the interior of the North American continent is covered by relatively undisturbed sedimentary rocks not available to the entrance of ore-bearing fluids from depths, but a wide belt along the Pacific Coast, a narrower belt along the Atlantic Coast, and most of the north-east quadrant of the continent have been mineralized. If we plot all the known ore deposits in these latter areas, we find considerable differences in the densities of occurrences but no well defined patterns except a crowding along most of the area near the Pacific Coast. If, on the other hand, we plot only the major occurrences, we can see some linear patterns transverse to the edges of the continent.Transverse ore deposit patterns in an ENE direction are conspicuous in western United States and northern Mexico and in Ontario and Quebec of Canada but are almost unknown in British Columbia and Alaska. East-west patterns (within 5 degrees of a 90degree azimuth) are much more rare: one in southern British Columbia, one in Quebec and Ontario, one in Missouri, and one in Tennessee. No north-south patterns of any great length can be recognized.In addition to these rich ridges there are many inhomogeneities in the distribution of the major ore deposits, and these I think are due to subcrustal inhomogeneities in the distribution of metals, presumably in the upper mantle and probably of a late stage in the formation of the earth. I will attempt to show that the large ore deposits of North America form belts bounded approximately by parallels of latitude, separated by gaps in which no large deposits occur. Without undue distortions I have been able to draw outlines to include all the approximately 250 major ore deposits, except in the area north of latitude 60 where recorded occurrences are at present too sparse and too widely distributed.The localization of ore deposits in North America is thus the result of linear zones, probably deep crustal or sub-crustal fracture zones, crossing latitudinal belts of anomalous concentrations of metals probably of pre-crustal age.I have no explanations for the processes that formed either the transverse patterns or the latitudinal belts. They are not prominent and will be judged by many to be nonexistent. The lack of an explanation must not, however, be used to deny their existence— an attitude that surely limits the progress of metallogenic theory. Correlations with similar studies on other continents will be most useful.

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Zusammenfassung Ein Teil des Inneren des Nordamerikanischen Kontinents ist mit relativ ungestörten Sedimentgesteinen bedeckt, die ein Eindringen von Erz-bringenden Lösungen aus der Tiefe verhinderten. Dagegen sind ein breiter Streifen entlang der Pazifikküste, ein schmalerer Streifen entlang der Atlantikküste und der größte Teil des Nordostquadranten des Kontinentes mineralisiert. Wenn wir alle bekannten Erzlagerstätten in diese Gebiete eintragen, so finden wir auffällige Unterschiede in der Verteilung der Punkte, aber kein regelmäßiges Muster, ausgenommen das Gebiet nahe der Pazifikküste. Wenn wir dagegen nur die größeren Vorkommen auftragen, so ergeben sich lineare Anordnungen, die quer auf die Ecken des Kontinentes zulaufen.Quer verlaufende Muster in ENE-Richtung sind auffallend in den westlichen Vereinigten Staaten, in Nord-Mexico, in Ontario und Quebec; diese Richtung ist jedoch in British Columbia und in Alaska unbekannt.E-W-Muster mit±5° Schwankungen sind sehr viel seltener. Eines finden wir im südlichen British Columbia, eines in Quebec und Ontario, eines in Missouri und Tennessee, N-S-streichende Lineationen sind unbekannt.Über die Anordnung in reichen Zonen hinaus finden wir viele Inhomogenitäten in der Verteilung der wichtigsten Erzlagerstätten; diese sind meiner Meinung nach von subkrustalen Inhomogenitäten in der Verteilung der Metalle bestimmt. Vielleicht spielt hier eine frühe Verteilung im oberen Mantel zur Zeit der Entstehung der Erde eine Rolle. Ich will versuchen zu zeigen, daß die großen Erzlagerstätten an Zonen gebunden sind, die annähernd parallel zu den Breitengraden verlaufen und durch erzfreie Zonen getrennt sind. Ohne Schwierigkeiten lassen sich Umgrenzungen mit dieser Orientierung aufzeigen, die alle 250 größeren Erzlagerstätten umfassen, ausgenommen im Gebiet nördlich des 60. Breitengrades, wo die Dichte der Lagerstätten zu gering ist.Die Anordnung der Erzlagerstätten Nordamerikas ist auf lineare Zonen zurückzuführen, die wahrscheinlich auf Bruchstrukturen der Unterkruste oder des oberen Mantels begründet sind. Die Konzentration der Metalle in Querstrukturen zu den Breitenkreisen ist vermutlich eine Auflage, die vor der Bildung der Kruste entstanden ist. Ich habe keine Erklärung für die Prozesse, die zu dieser Metallkonzentration geführt haben. Viele mögen eine derartig vorgegebene Anordnung ablehnen; man sollte jedoch bedenken, daß das Fehlen einer Erklärung noch nicht zur Ablehnung auffälliger Phänomene berechtigt. Es sollten auch andere Kontinente daraufhin untersucht werden.

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Résumé Une partie de l'intérieur du continent Nord Américain est couverte par des roches sédimentaires peu dérangées et défavorables à l'accès de fluides minéralisants venus de la profondeur. Par contre une large ceinture le long de la côte pacifique, un ceinture plus étroit de long de la côte atlantique, et la majeure partie du quadrant Nord-Est du continent ont été minéralisées. Si l'on reporte sur carte tous les dépôts connus dans ces domaines, on trouve des différences considérables dans les »densités d'occurrences« mais aucun réseau bien défini, à l'exception d'un fort peuplement dans presque tout le domaine proche du Pacifique. Si, d'autre part, on ne reporte que les occurrences majeures, on voit apparaître des lignes directrices transversales sur les bordures du continent.De telles transversales dirigées ENE apparaissent dans l'Ouest des Etats-Unis, le Nord du Mexique, l'Ontario et le Québec (Canada) mais sont presque inconnues en Colombie britannique et en Alaska.Des directions Est-Ouest (avec une variation de 5) sont beaucoup plus rares: une dans le Sud de la Colombie britannique, une dans le Québec et l'Ontario, une dans le Missouri et une dans le Tennessee. Aucune direction Nord-Sud de grande longueur ne peut être reconnue.En plus de ces »arêtes riches« existent beaucoup d'inhomogénéités dans la distribution des gisements importants, et celles-ci sont dues, à mon avis, à des hétérogénéités souscrustales de la distribution des métaux, probablement au niveau du manteau supérieur et remontant à une étape tardive de la formation de la Terre. Je désire essayer de montrer que les grands gisements métallifères de l'Amérique du Nord s'intègrent dans des ceintures approximativement limitées par des parallèles de latitude et séparées par des intervalles dépourvus de grands dépôts. Ainsi, sans distorsions abusives, j'ai pu tracer des enveloppes englobant environ 250 gisements majeurs, sauf dans une aire située au Nord du parallèle 60 Nord, où les occurrences jusqu'ici enregistrées sont encore trop rares et disséminées.La localisation des gisements métallifères de l'Amérique du Nord est donc due à des zones linéaires, probablement des zones de fractures crustales profondes ou sous-crustales, croisant des ceintures latitudinales de concentrations anormales de métaux, elles-mêmes probablement précrustales.Je n'offre pas d'explication pour les processus qui ont formé les ceintures latitudinales et les transversales. Les unes et les autres ne sont pas fortement apparentes, et beaucoup estimeront qu'elles n'existent pas. Cette absence d'explication ne doit cependant pas être utilisée pour nier leur existence, attitude qui limiterait certainement les progrès des théories métallogéniques. Des comparaisons avec des ètudes similaires sur d'autres continents seraient certainement très utiles.

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Marine and limnic radiocarbon reservoir corrections for studies of late- and postglacial environments in Georgia Basin and Puget Lowland, British Columbia, Canada and Washington, USA

Models of late-glacial environmental change in coastal areas are commonly based on radiocarbon ages on marine shell and basal lake sediments, both of which may be compromised by reservoir effects. The magnitude of the oceanic reservoir age in the inland waters of the Georgia Basin and Puget Lowland of northwestern North America is inferred from radiocarbon ages on shell-wood pairs in Saanich Inlet and previously published estimates. The weighted mean oceanic reservoir correction in the early and mid Holocene is −720±90 yr, slightly smaller than, but not significantly different from, the modern value. The correction in late-glacial time is −950±50 yr. Valley-head sites yield higher reservoir values (−1200±130 yr) immediately after deglaciation. The magnitude of the gyttja reservoir effect is inferred from pairs of bulk gyttja and plant macrofossil ages from four lakes in the region. Incorporation of old carbon into basal gyttja yields ages from bulk samples that are initially about 600 yr too old. The reservoir age declines to less than 100 yr after the first millennium of lake development. When these corrections are accounted for, dates of deglaciation and late-glacial sea-level change in the study area are pushed forward in time by more than 500 yr.     

Late Quaternary sapropel sediments in the eastern Mediterranean Sea: Faunal variations and chronology

Distinctive planktonic foraminiferal assemblages which characterize particular late Quaternary sapropel layers in deep basin sediments from the eastern Mediterranean Sea have been identified using cluster analysis. Three distinct clusters allow for identification and intercore correlation of the nine sapropels deposited during the last 250,000 yr. Cluster 1, representing sapropel layers S1 and S9, exhibits low abundances of Neogloboquadrina dutertrei and high abundances of Globigerinoides ruber; Cluster 2, which groups S3, S5, and S7, contains high abundances of G. ruber, N. dutertrei, and Globigerina bulloides, and Cluster 3, which includes samples from S4, S6, and S8, is marked by extremely abundant N. dutertrei and G. bulloides, and rare G. ruber. Analysis of sedimentation rates in 14 cores reveals the following approximate ages for the sapropel layers: S2 = 52,000 yr B.P.; S3 = 81,000–78,000 yr B.P.; S4 = 100,000–98,000 yr B.P.; and S5 = 125,000–116,000 yr B.P. As previously suggested, sedimentation rates on the Mediterranean Ridge were determined to be relatively constant during the last 127,000 yr. In contrast, basin sedimentation rates have fluctuated markedly from lower rates during interglacial stage 5 to higher rates during the last glacial episode. These glacial/interglacial differences are most pronounced in the northern Ionian Basin, because of increased terrigenous sediment deposition during glacial episodes. Unusually high biogenic sedimentation rates occurred in an arc south of Crete during the deposition of sapropel S5, probably due to higher productivity in this region.     

A comparative study of the modelling of cement hydration and cement-rock laboratory experiments

The use of cement and concrete as fracture grouting or as tunnel seals in a geological disposal facility for radioactive wastes creates potential issues concerning chemical reactivity. From a long-term safety perspective, it is desirable to be able model these interactions and changes quantitatively. The ‘Long-term Cement Studies’ (LCS) project was formulated with an emphasis on in situ field experiments with more realistic boundary conditions and longer time scales compared with former experiments. As part of the project programme, a modelling inter-comparison has been conducted, involving the modelling of two experiments describing cement hydration on one hand and cement-rock reaction on the other, with teams representing the NDA (UK), Posiva (Finland), and JAEA (Japan).This modelling exercise showed that the dominant reaction pathways in the two experiments are fairly well understood and are consistent between the different modelling teams, although significant differences existed amongst the precise parameterisation (e.g. reactive surface areas, dependences of rate upon pH, types of secondary minerals), and in some instances, processes (e.g. partition of alkali elements between solids and liquid during cement hydration; kinetic models of cement hydration). It was not conclusive if certain processes such as surface complexation (preferred by some modellers, but not by others) played a role in the cement-rock experiment or not. These processes appear to be more relevant at early times in the experiment and the evolution at longer timescales was not affected. The observed permeability profile with time could not be matched. The fact that no secondary minerals could be observed and that the precipitated mass calculated during the simulations is minor might suggest that the permeability reduction does not have a chemical origin, although a small amount of precipitates at pore throats could have a large impact on permeability.The modelling exercises showed that there is an interest in keeping the numerical models as simple as possible and trying to obtain a reasonable fit with a minimum of processes, minerals and parameters. However, up-scaling processes and model parameterisation to the timescales appropriate to repository safety assessment are of considerable concern. Future modelling exercises of this type should focus on a suitable natural or industrial analogue that might aid assessing mineral-fluid reactions at these longer timescales.     

Characteristics and mitigation of the snow avalanche hazard in Kaghan Valley,Pakistan Himalaya

Snow avalanche hazards in mountainous areas of developing countries have received scant attention in the scientific literature. The purpose of this paper is to describe this hazard and mitigative measures in Kaghan Valley, Pakistan Himalaya, and to review alternatives for future reduction of this hazard. Snow avalanches have long posed a hazard and risk to indigenous populations of the Himalaya and Trans-Himalaya mountains. Land use intensification due to population growth, new transportation routes, military activity and tourism is raising levels of risk. The history of land use in the study area is such that investigations of avalanche hazard must rely on different theoretical bases and data than in most industrialised countries. Despite the intensive use of valley-bottom land which is affected by avalanches, a number of simple measures are currently employed by the indigenous population to mitigate the hazard. Out-migration during the winter months is the most important one. During the intensive use period of summer avalanche-transported snow provides numerous resources for the population. In Kaghan the avalanche hazard is increasing primarily as a result of poorly located new buildings and other construction projects. The large scale of avalanche activity there rules out any significant improvement or protection of the currently difficult winter access. Instead, future mitigation of the hazard should focus on protecting the small number of winter inhabitants and minimising property damage.