Generation of Hydrogen Gas as a Result of Drilling Within the Saturated Zone

Hydrogen gas was discovered within the steel casing above standing water in a percussion-drilled borehole on the Hanlord Site in south-central Washington state. In situ measurements of the borehole fluids indicated anoxic, low-Eh (<-400 mV) conditions. Ground water sampled from adjacent wells in the same formation indicated that the ground water was oxygenated. H₂ was generated during percussion drilling, due to the decomposition of borehole waters as a result of aqueous reactions with drilled sediment and steel from the drilling tools or casing. The generation of H₂ within percussion-drilled boreholes that extend below the water table may be more common than previously realized. The ambient concentration of H₂ produced during drilling was limited by microbial activity within the casing-resident fluids. H₂ was generated abiotically in the laboratory, whereby sterilized borehole slurry samples produced 100 times more H₂ than unsterilizcd samples. It appears that H₂ is metabolized by microorganisms and concentrations might be significantly greater if not for microbial metabolism.     

Prediction of thermal conductivity in reservoir rocks using fabric theory

An accurate prediction of the thermal conductivity of reservoir rocks in the subsurface is extremely important for a quantitative analysis of basin thermal history and hydrocarbon maturation. A model for calculating the thermal conductivity of reservoir rocks as a function of mineral composition, porosity, fluid type, and temperature has been developed based on fabric theory and experimental data. The study indicates that thermal conductivities of reservoir rocks are dependent on the volume fraction of components (minerals, porosity, and fluids), the temperature, and the fraction of series elements (FSE) which represents the way that the mineral components aggregate. The sensitivity test of the fabric model shows that quartz is the most sensitive mineral for the thermal conductivity of clastic rocks. The study results indicate that the FSE value is very critical. Different lithologies have different optimum FSE values because of different textures and sedimentary structures. The optimum FSE values are defined as those which result in the least error in the model computation of the thermal conductivity of the rocks. These values are 0.444 for water-saturated clay rocks, 0.498 for water-saturated sandstones, and 0.337 for water-saturated carbonates. Compared with the geometric mean model, the fabric model yields better results for the thermal conductivity, largely because the model parameters can be adjusted to satisfy different lithologies and to minimize the mean errors. The fabric model provides a good approach for estimating paleothermal conductivity in complex rock systems based on the mineral composition and pore fluid saturation of the rocks.     

Frictional heat generation and seismic radiation in a foam rubber model of earthquakes

Results from a study of stick-slip particle motion at the interface between two stressed foam rubber blocks indicate that normal vibrations and interface separation are an important part of the stick-slip process in foam rubber. The dimension of the dynamic slip pulse is small compared to the dimension of the model (approximately 10 cm vs. 200 cm) consistent with the abrupt-locking slip pulse model ofBrune (1970, 1976), andHeaton (1990). A comparison of frictional heat generation between stable-sliding and stick-slip foam rubber models indicates a linear relation between the temperature increase on the fault surface (for a given distance of slip) and the driving shear force for the stable-sliding model, while for the stick-slip model there is essentially no variation in frictional heat generation with an increase in shear stress. We performed experiments to investigate the ratio of normal motion to shear motion at different levels of normal stress in the stick-slip foam rubber model. Preliminary result indicate that the normal component of the particle motion increases more rapidly with increasing normal stress than the shear component. The phenomenon of interface separation and normal vibrations may thus explain some of the most frustrating problems in earthquake mechanics, e.g., the heat flow paradox, the long-term weakness of major active faults, and anomalousP-wave radiation.     

Gravel transport and morphological change in braided sunwapta river,Alberta, Canada

The relation between morphological change and patterns of variation in bedload transport rate in braided streams was observed by repeated, daily topographic surveys over a 25 day study period in a 60 m reach of the proglacial Sunwapta River, Alberta, Canada. There are two major periods of morphological change, each lasting several days and each involving the complete destruction and reconstruction of bar complexes. Bar complex destruction was caused by redirection of the flow and by downstream extension of the confluence scour zone upstream. Reconstruction involved accretion of unit bars on bar head, flank and tail and in one case was initiated by disection of a large, lobate unit bar. High rates of sediment movement, measured from net scour and fill of the cross-sections, coincided with these morphological changes. Sediment was supplied from both bed and bank erosion, and patterns and distances of transfer were highly variable. Rates of transport estimated by matching upstream erosional volumes with downstream deposition were much greater than those estimated from either a step-length approach or a sediment budget. Measurements of scour and fill and observations of morphological change indicate that step lengths (virtual transport distances) were typically 40–100m during a diurnal discharge cycle. Shorter step lengths occurred when transfer was confined to a single anabranch and longer steps involved channel changes at the scale of the entire reach. Sediment budgeting was used to describe the spatial patterns of sediment transport associated with the morphological changes and to estimate minimum daily reach-averaged transport rates. Mean bedload transport rates correlate with discharge, but with considerable scatter. The largest deviations from the mean relation can be tied to phases of channel incision, bank erosion, scour hole migration, bar deposition and channel filling apparently controlled by changes and fluctuations in sediment supply from upstream, independent of discharge. These are interpreted as field evidence of ‘autopulses’ or ‘macropulses’ in bedload transport, previously observed only in laboratory models of braided streams.     

Coal resources,production, and quality in the Eastern kentucky coal field: Perspectives on the future of steam coal production

The Eastern Kentucky coal field, along with adjacent portions of Virginia and southern West Virginia, is part of the greatest production concentration of high-heating-value, low-sulfur coal in the United States, accounting for over 27% of the 1993 U.S. production of coal of all ranks. Eastern Kentucky's production is spread among many coal beds but is particularly concentrated in a limited number of highquality coals, notably the Pond Creek coal bed and its correlatives, and the Fire Clay coal bed and its correlatives. Both coals are relatively low ash and low sulfur through the areas of the heaviest concentration of mining activity. We discuss production trends, resources, and the quality of in-place and clean coal for those and other major coals in the region.     

The role of bioindicators in estuarine management

Estuarine organisms can be considered three ways as bioindicators—first, as indicators of a defined set of environmental conditions, second, as indicators of contaminant loads on the system, and third, as indicators of the overall health of the system. By their very nature, estuarine organisms are eurytolerant and this, along with the various stratagems that have evolved to cope with the problems of life in estuaries results in a confusing picture for the estuarine manager. The recommended bioindicators for estuarine conditions are plankton; for contaminant loads, a range of species with different feeding types; and for system status, a eurytolerant species, such as the musselMytilus edulis for laboratory monitoring or a “target” species such as the clamMacoma balthica for field monitoring. However, it would be unwise to rely on a single indicator, and the recommendation is that the final choice, and preferably choices, be tailored to the desired goal.     

Diver-operated piston corer for nearshore use

A diver-operated piston corer suitable for collecting cores of >3 m length from fine-grained nearshore sediment has been developed. The corer uses a platform that rests on the sediment surface supporting both the operators and a derrick that maintains the piston at the sediment-water interface. The core is insected into and recovered from the sediment manually. The technique offers several advantages; low cost, minimal disruption of the sediment-water interface, little compaction of the sediment, the ability to collect longer length cores than is possible with gravity corers, and the ability to be deployed from relatively small boats. Dissolved ammonium and inorganic carbon data are presented from a 3.3-m core collected by this technique from Tomales Bay, California.