Laboratory kinetics of C2H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.     

CORROSION RESISTANCE OF INTERFERENCE FILM ON STAINLESS STEEL

IwrRODUcrlONStainlessstalhasbeenusedwidelyasbuildingrnateria1,especiallyasdecoratingrnate-rialinbuildings.Ordinarystainlesssteehasonlyonemonot0noussilverywhitCcolourwhichsomeimesdoesnotrnatchwithitSsurmundingenvironment.lnordert0improveitSdereratingperfonnaneeandexpanditsuse,muchresearchhasbeenconductedsincethe4O'st0trytoformabright,uniform,highcorrosi0nandwearresistantco1ourfilmonastainlesssteesurface.Duringtheeariystage,anirnmersionedhodwasused,i.e.inimrs-ingthestainlesssteelinahots0luti…     

Late Weichselian glacial maximum on Andøya, North Norway

Morphological, seismic and lithostratigraphic investigations of a moraine deposit at Bleik (the Bleik moraine), northern Andøya, show short-distance transported till overlying long-distance transported predominantly glaciofluvial ice-marginal deposits. Consolidated glaciomarine sediments from a core at present sea-level, c . 400 m distally to the moraine complex, contain 31 species of foraminifera, among which Cassidulina reniforme, Islandiella helenae and Trifarina fluens dominate, and fragments of the molluscs Mya truncata and Astarte sp. and the echinoid Strongylocentrotus sp. Amino acid analyses of the foraminifera Cibicides lobatulus and the mollusc Mya truncata indicate ages between 22,000 and 16,000 BP. Radiocarbon dating of fragments of Mya truncata from the upper part of the core gave an age of 17,940 ± 245 BP, while a dating of unidentified shell fragments from the lower part gave an infinite age (>40,000 BP). The sediment was probably disturbed by icebergs beyond the end moraine zone, and the radiocarbon and amino acid dating of Mya truncata therefore represent a maximum age for this process. This new evidence indicates two phases with a higher relative sea-level than at present at Bleik, c . 18,000 and >40,000 BP. The Bleik moraine probably represents the early Late Weichselian glacial maximum ( c . 22,000 BP), while the underlying deglaciation deposit and associated beach-ridge (Bruvollen) is of pre-Late Weichselian age. Moraine ridges 3–4 km to the south of Bleik probably indicate advances of local glaciers between 22,000 and 18,000 BP.     

Spectroscopy of comet P/Schaumasse

Column density profiles for CN, C₃, C₂ and NH have been determined from a long-slit CCD spectrum of periodic comet P/Schaumasse (1992x). Comparisons of these profiles with Haser models indicate that the ratios of the CN, C₃ and C₂ production rates are typical for a short-period comet. Although the scale lengths for NH and its parent species are uncertain, the results indicate that the production rate for NH is much greater than for either C₂ or CN.     

measurement of noise power spectrum in photon counting PMT's and the effect of the observed (1/f) noise on astronomical photometry

In astronomical photometry, the sensitivity of observations is limited by the dark counts of the photomultiplier tube. In the present work, the effect of dark count noise in photon counting systems is investigated by theory and experimental measurements. Dark counts are considered to be originating from two sources, namely: dc fluctuations and random pulses.Experimental measurements were carried out to determine noise effects in different operating regions of noise dominance. The results provide strong evidence that: in normal operating mode, where the effect of random pulses is dominant, dark counts do not follow Poisson statistics. The observed noise shows strong (1/f) power spectrum, where the observed noise power is found to increase with time of observation.The results are important in photon counting systems operating under dark count limited mode. The conclusions drawn can be useful in obtaining more accurate error estimates and in assessing astronomical photometric observations and data reduction techniques.