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171.
M. I. Holloway F. Bussy T. W. Vennemann 《Contributions to Mineralogy and Petrology》2008,155(1):111-121
Migmatites produced by low-pressure anatexis of basic dykes are found in a contact metamorphic aureole around a pyroxenite–gabbro
intrusion (PX2), on Fuerteventura. Dykes outside and inside the aureole record interaction with meteoric water, with low or
negative δ18O whole-rock values (+0.2 to −3.4‰), decreasing towards the contact. Recrystallised plagioclase, diopside, biotite and oxides,
from within the aureole, show a similar evolution with lowest δ18O values (−2.8, −4.2, −4.4 and −7.6‰, respectively) in the migmatite zone, close to the intrusion. Relict clinopyroxene phenocrysts
preserved in all dykes, retain typically magmatic δ18O values up to the anatectic zone, where the values are lower and more heterogeneous. Low δ18O values, decreasing towards the intrusion, can be ascribed to the advection of meteoric water during magma emplacement, with
increasing fluid/rock ratios (higher dyke intensities towards the intrusion acting as fluid-pathways) and higher temperatures
promoting increasing exchange during recrystallisation.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
172.
A.N. Krot M. Chaussidon H. Yurimoto N. Sakamoto K. Nagashima I.D. Hutcheon G.J. MacPherson 《Geochimica et cosmochimica acta》2008,72(10):2534-2555
In situ oxygen isotopic measurements of primary and secondary minerals in Type C CAIs from the Allende CV3 chondrite reveal that the pattern of relative enrichments and depletions of 16O in the primary minerals within each individual CAI are similar to the patterns observed in Types A and B CAIs from the same meteorite. Spinel is consistently the most 16O-rich (Δ17O = −25‰ to −15‰), followed by Al,Ti-dioside (Δ17O = −20‰ to −5‰) and anorthite (Δ17O = −15‰ to 0‰). Melilite is the most 16O-depleted primary mineral (Δ17O = −5‰ to −3‰). We conclude that the original melting event that formed Type C CAIs occurred in a 16O-rich (Δ17O −20‰) nebular gas and they subsequently experienced oxygen isotopic exchange in a 16O-poor reservoir. At least three of these (ABC, TS26F1 and 93) experienced remelting at the time and place where chondrules were forming, trapping and partially assimilating 16O-poor chondrule fragments. The observation that the pyroxene is 16O-rich relative to the feldspar, even though the feldspar preceded it in the igneous crystallization sequence, disproves the class of CAI isotopic exchange models in which partial melting of a 16O-rich solid in a 16O-poor gas is followed by slow crystallization in that gas. For the typical (not associated with chondrule materials) Type C CAIs as well for as the Types A and B CAIs, the exchange that produced internal isotopic heterogeneity within each CAI must have occurred largely in the solid state. The secondary phases grossular, monticellite and forsterite commonly have similar oxygen isotopic compositions to the melilite and anorthite they replace, but in one case (CAI 160) grossular is 16O-enriched (Δ17O = −10‰ to −6‰) relative to melilite (Δ17O = −5‰ to −3‰), meaning that the melilite and anorthite must have exchanged its oxygen subsequent to secondary alteration. This isotopic exchange in melilite and anorthite likely occurred on the CV parent asteroid, possibly during fluid-assisted thermal metamorphism. 相似文献
173.
We have determined the metallographic cooling rates for 13 IVA irons using the most recent and most accurate metallographic cooling rate model. Group IVA irons have cooling rates that vary from 6600 °C/Myr at the low-Ni end of the group to 100 °C/Myr at the high-Ni end of the group. This large cooling rate range is totally incompatible with cooling in a mantled core which should have a uniform cooling rate. Thermal and fractional crystallization models have been used to describe the cooling and solidification of the IVA asteroid. The thermal model indicates that a metallic body of 150 ± 50 km in radius with less than 1 km of silicate on the outside of the body has a range of cooling rates that match the metallographic cooling rates in IVA irons in the temperature range 700-400 °C where the Widmanstätten pattern formed. The fractional crystallization model for Ni with initial S contents between 3 and 9 wt% is consistent with the measured variation of cooling rate with bulk Ni and the thermal model. New models for impacts in the early solar system and the evolution of the primordial asteroid belt allow us to propose that the IVA irons crystallized and cooled in a metallic body that was derived from a differentiated protoplanet during a grazing impact. Other large magmatic iron groups, IIAB, IIIAB, and IVB, also show significant cooling rate ranges and are very likely to share a similar history. 相似文献
174.
Kathryn A. Matthews Andréa G. Grottoli James E. Palardy 《Geochimica et cosmochimica acta》2008,72(18):4537-4550
Skeletal cadmium-to-calcium (Cd/Ca) ratios in hermatypic stony corals have been used to reconstruct changes in upwelling over time, yet there has not been a systematic evaluation of this tracer’s natural variability within and among coral species, between depths and across environmental conditions. Here, coral skeletal Cd/Ca ratios were measured in multiple colonies of Pavona clavus, Pavona gigantea and Porites lobata reared at two depths (1 and 7 m) during both upwelling and nonupwelling intervals in the Gulf of Panama (Pacific). Overall, skeletal Cd/Ca ratios were significantly higher during upwelling than during nonupwelling, in shallow than in deep corals, and in both species of Pavona than in P. lobata. P. lobata skeletal Cd/Ca ratios were uniformly low compared to those in the other species, with no significant differences between upwelling and nonupwelling values. Among colonies of the same species, skeletal Cd/Ca ratios were always higher in all shallow P. gigantea colonies during upwelling compared to nonupwelling, though the magnitude of the increase varied among colonies. For P. lobata, P. clavus and deep P. gigantea, changes in skeletal Cd/Ca ratios were not consistent among all colonies, with some colonies having lower ratios during upwelling than during nonupwelling. No statistically significant relationships were found between skeletal Cd/Ca ratios and maximum linear skeletal extension, δ13C or δ18O, suggesting that at seasonal resolution the Cd/Ca signal was decoupled from growth rate, coral metabolism, and ocean temperature and salinity, respectively. These results led to the following conclusions, (1) coral skeletal Cd/Ca ratios are independent of skeletal extension, coral metabolism and ambient temperature/salinity, (2) shallow P. gigantea is the most reliable species for paleoupwelling reconstruction and (3) the average Cd/Ca record of several colonies, rather than of a single coral, is needed to reliably reconstruct paleoupwelling events. 相似文献
175.
We have collected ∼500 stream waters and associated bed-load sediments over an ∼400 km2 region of Eastern Canada and analyzed these samples for Fe, Mn, and the rare earth elements (REE + Y). In addition to analyzing the stream sediments by total digestion (multi-acid dissolution with metaborate fusion), we also leached the sediments with 0.25 M hydroxylamine hydrochloride (in 0.05 M HCl), to determine the REE + Y associated with amorphous Fe- and Mn-oxyhydroxide phases. We are thus able to partition the REE into “dissolved” (<0.45 μm), labile (hydroxylamine) and detrital sediment fractions to investigate REE fractionation, and in particular, with respect to the development of Ce and Eu anomalies in oxygenated surface environments. Surface waters are typically LREE depleted ([La/Sm]NASC ranges from 0.16 to 5.84, average = 0.604, n = 410; where the REE are normalized to the North America Shale Composite), have strongly negative Ce anomalies ([Ce/Ce∗]NASC ranges from 0.02 to 1.25, average = 0.277, n = 354), and commonly have positive Eu anomalies ([Eu/Eu∗]NASC ranges from 0.295 to 1.77, average = 0.764, n = 84). In contrast, the total sediment have flatter REE + Y patterns relative to NASC ([La/Sm]NASC ranges from 0.352 to 1.12, average = 0.778, n = 451) and are slightly middle REE enriched ([Gd/Yb]NASC ranges from 0.55 to 3.75, average = 1.42). Most total sediments have negative Ce and Eu anomalies ([Ce/Ce∗]NASC ranges from 0.097 to 2.12, average = 0.799 and [Eu/Eu∗]NASC ranges from 0.39 to 1.43, average = 0.802). The partial extraction sediments are commonly less LREE depleted than the total sediments ([La/Sm]NASC ranges from 0.24 to 3.31, average = 0.901, n = 4537), more MREE enriched ([Gd/Yb]NASC ranges from 0.765 to 6.28, average = 1.97) and Ce and Eu anomalies (negative and positive) are more pronounced.The partial extraction recovered, on average ∼20% of the Fe in the total sediment, ∼80% of the Mn, and 21-29% of the REEs (Ce = 19% and Y = 32%). Comparison between REEs in water, partial extraction and total sediment analyses indicates that REEs + Y in the stream sediments have two primary sources, the host lithologies (i.e., mechanical dispersion) and hydromorphically transported (the labile fraction). Furthermore, Eu appears to be more mobile than the other REE, whereas Ce is preferentially removed from solution and accumulates in the stream sediments in a less labile form than the other REEs + Y. Despite poor statistical correlations between the REEs + Y and Mn in either the total sediment or partial extractions, based on apparent distribution coefficients and the pH of the stream waters, we suggest that either sediment organic matter and/or possibly δ-MnO2/FeOOH are likely the predominant sinks for Ce, and to a lesser extent the other REE, in the stream sediments. 相似文献
176.
James D. Prikryl 《Geochimica et cosmochimica acta》2008,72(18):4508-4520
The dissolution and growth of uranophane [Ca(UO2)2(SiO3OH)2·5H2O] have been examined in Ca- and Si-rich test solutions at low temperatures (20.5 ± 2.0 °C) and near-neutral pH (∼6.0). Uranium-bearing experimental solutions undersaturated and supersaturated with uranophane were prepared in matrices of ∼10−2 M CaCl2 and ∼10−3 M SiO2(aq). The experimental solutions were reacted with synthetic uranophane and analyzed periodically over 10 weeks. Interpretation of the aqueous solution data permitted extraction of a solubility constant for the uranophane dissolution reaction and standard state Gibbs free energy of formation for uranophane ( kJ mol−1). 相似文献
177.
The petroleum resource potential is considered for the Atlantic, West Pacific, and East Pacific types of deepwater continental margins. The most considerable energy resources are concentrated at the Atlantic-type passive margins in the zone transitional to the ocean. The less studied continental slope of backarc seas of the generally active margins of the West Pacific type is currently not so rich in discoveries as the Atlantic-type margin, but is not devoid of certain expectations. In some of their parameters, the margins bounded by continental slopes may be regarded as analogs of classical passive margins. At the margins of the East Pacific type, the petroleum potential is solely confined to transform segments. In the shelf-continental-slope basins of the rift and pull-apart nature, petroleum fields occur largely in the upper fan complex, and to a lesser extent in the lower graben (rift) complex. In light of world experience, the shelf-continental-slope basins of the Arctic and Pacific margins of Russia are evaluated as highly promising. 相似文献
178.
If a magma is a hybrid of two (or more) isotopically distinctend-members, at least one of which is partially crystalline,separation of melt and crystals after hybridization will leadto the development of isotopic heterogeneities in the magmaas long as some of the pre-existing crystalline material (antecrysts)retains any of its original isotopic composition. This holdstrue whether the hybridization event is magma mixing as traditionallyconstrued, bulk assimilation, or melt assimilation. Once a magma-scaleisotopic heterogeneity is formed by crystal–melt separation,it is essentially permanent, persisting regardless of subsequentcrystallization, mixing, or equilibration events. The magnitudeof the isotopic variability resulting from crystal–meltseparation can be as large as that resulting from differentialcontamination, multiple isotopically distinct sources, or insitu isotopic evolution. In one model, a redistribution of one-thirdof the antecryst cargo yielded a crystal-enriched sample with87Sr/86Sr of 0·7058, whereas the complementary crystal-poorsample has 87Sr/86Sr of 0·7068. In other models, crystal-richsamples are enriched in radiogenic Sr. Isotopic heterogeneitiescan be either continuous (controlled by the modal distributionof crystals and melt) or discontinuous (when there is completeseparation of crystals and liquid). The first case may be exemplifiedby some isotopically zoned large-volume rhyolites, formed bythe eruptive inversion of a modally zoned magma chamber. Inthe latter case, the isotopic composition of any (for example)interstitial liquid will be distinct from the isotopic compositionof the bulk crystal fraction. The separation of such an interstitialliquid may explain the presence of isotopically distinct late-stageaplites in plutons. Crystal–melt separation provides anadditional option for the interpretation of isotopically zonedor heterogeneous magmas. This option is particularly attractivefor systems whose chemical variation is otherwise explicableby fractionation-dominated processes. Non-isotopic chemicalheterogeneities can also develop in this fashion. KEY WORDS: isotopic heterogeneity; zoning; hybrid magma; crystal separation; Sr isotopes; aplite; rhyolite 相似文献
179.
In distribution areas of the Pekul’neiveem and Chirynai formations customary distinguishable in the Koryak Upland, complicated tectonostratigraphic units are composed of alternating thrust sheets of different lithologic composition and age, which are juxtaposed because of widespread thrust faulting, as is proved by the radiolarian analysis. Nineteen radiolarian assemblages of different age are first established here in the Lower Jurassic-Hauterivian succession of siliceous-volcanogenic sediments. In the Lower Jurassic interval, the lower and upper Hettangian, lower and upper Sinemurian, and Pliensbachian beds are recognized. Paleontological characterization is also presented for the Aalenian (or Toarcian?-Aalenian), upper Bajocian, lower and upper Bathonian, and Callovian beds of the Middle Jurassic. Within the Upper Jurassic, the Oxfordian-early Kimmeridgian, late Kimmeridgian-early Tithonian, Tithonian, and late Tithonian-early Berriasian radiolarian assemblages are distinguished. The late Berriasian-early Valanginian, middle-late Valanginian, and Hauterivian radiolarian assemblages are first recognized or compositionally revised. Radiolarians and lithofacies data are used to correlate the tectonostratigraphic units and individualize the jasper-alkali basaltic (lower Hettangian), chert-terrigenous (Hettangian-Sinemurian), jasper-cherty (Pliensbachian-Aalenian), jasper (Bajocian-Hauterivian), jasper-basaltic (upper Bajocian-Valanginian), Fe-Ti basaltic (upper Bajocian-Bathonian), tuffitejasper-basaltic (Bathonian-Hauterivian), and terrigenous-volcanogenic (Bajocian-Valanginian) sequences. The correlation results are extrapolated into other continental areas flanking the Pacific, i.e., to the western Kamchatka, northern and northwestern coastal areas of the Sea of Okhotsk, where the analogous radiolarian assemblages are characteristic of comparable allochthonous units of terrigenous-siliceous-volcanogenic sediments. 相似文献
180.
M. P. Chekhovskaya I. A. Basov A. G. Matul T. A. Khusid S. A. Gorbarenko 《Stratigraphy and Geological Correlation》2008,16(3):328-342
Taxonomic composition and distribution of planktonic foraminifers are studied in section of Core GC-11 that penetrated through Upper Quaternary sediments of the Bowers Ridge western slope, the southern Bering Sea. As is shown, structure of foraminiferal assemblage and productivity have varied substantially during the last 32000 calendar years in response to changes in surface water temperatures and water mass circulation in the northern part of the Pacific, the Bering Sea included. The productivity was maximal during deglaciation epoch, being notably lower in the Holocene and minimal at the glaciation time. 相似文献